Gold-Catalyzed Divergent Ring-Opening Rearrangement of Cyclopropenes Enabled by Dichotomous Gold−Carbenes

The gold-catalyzed ring-opening rearrangement of cyclopropenes affords an efficient route to either polysubstituted naphthols or aryl-substituted furans. Owing to the unique dichotomy of gold−carbenes, this protocol provides a switchable reaction selectivity between naphthols and furans enabled by the use of TFP−Au(MeCN)SbF₆ (tri(2-furyl) phosphine) or PNP(AuNTf₂)₂ (bis(diphenylphosphino)(isopropyl) amine) as catalysts respectively. It is proposed that the gold−carbene intermediate might be involved in the cyclopropene→naphthol rearrangement while the gold-carbocation is more likely to be involved in the cyclopropene→furan rearrangement.     

Mean first-passage time for random walks on undirected networks

In this paper, by using two different techniques we derive an explicit formula for the mean first-passage time (MFPT) between any pair of nodes on a general undirected network, which is expressed in terms of eigenvalues and eigenvectors of an associated matrix similar to the transition matrix. We then apply the formula to derive a lower bound for the MFPT to arrive at a given node with the starting point chosen from the stationary distribution over the set of nodes. We show that for a correlated scale-free network of size N with a degree distribution P(d) ∼ d ^−γ , the scaling of the lower bound is N ^1−1/γ . Also, we provide a simple derivation for an eigentime identity. Our work leads to a comprehensive understanding of recent results about random walks on complex networks, especially on scale-free networks.