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Khafizova L. O. Ibragimov A. G. Yalalova D. F. Borisova A. L. Khalilov L. M. Dzhemilev U. M. 《Russian Chemical Bulletin》2003,52(9):2012-2016
A method for the synthesis of secondary and tertiary alcohols was developed. The method is based on cycloalumination of olefins with trialkylalanes in the presence of Zr-containing catalysts followed by the CuCl-catalyzed in situ reaction of the corresponding aluminacyclopentanes with aldehydes or ketones. 相似文献
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Dzhemilev U. M. Ibragimov A. G. Khafizova L. O. Parfenova L. V. Yalalova D. F. Khalilov L. M. 《Russian Chemical Bulletin》2001,50(8):1465-1468
The reactions of 3-alkyl-1-ethylalumacyclopentanes with allyl halides in the presence of Ni(acac)2 as a catalyst were studied by dynamic NMR spectroscopy. Under the action of Ni complexes, alumacyclopentanes initially undergo intramolecular hydride transfer to give but-3-enyl(ethyl)aluminum hydrides and then react with the starting allyl halide, yielding but-3-enyl(ethyl)aluminum halides. Subsequent intramolecular carboalumination affords the corresponding 1,1-disubstituted cyclopropanes. 相似文献
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