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Krüger A. L Nicolodelli G Villas-Boas P. R Watanabe A Milori D. M. B. P 《Plasma Chemistry and Plasma Processing》2020,40(6):1417-1427
Plasma Chemistry and Plasma Processing - Laser-induced breakdown spectroscopy (LIBS) has been considered a promising tool for agricultural analysis in the recent years due to its advantages over... 相似文献
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D. W. Taylor V. Villas-Boas Q. Lu M. F. Rossignol F. P. Missell D. Givord S. Hirosawa 《Journal of magnetism and magnetic materials》1994,130(1-3):225-236
We studied the coercivity in magnets of composition R17Fe83−χBχ (R = Nd, Pr and χ = 8, 30), using measurements of the coercive field Hc, its angular dependence, and the magnetic viscosity coefficient Sv, for temperatures between 4.2 and 500 K. The results are discussed in relation to a model which does not specifically consider the detailed mechanisms involved in magnetization reversal, but which provides information about the magnetic properties in the activation volume v where magnetization reversal is initiated. It is concluded that the ordering temperature in v tends to be slightly smaller than in the bulk and that the room temperature anisotropy in v is not strongly reduced with respect to the bulk value. Finally, a direct evaluation of the dipolar interactions is in good agreement with results obtained from Hc(T). 相似文献
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Harrison S Fraser K Lane G Hughes D Villas-Boas S Rasmussen S 《Analytical and bioanalytical chemistry》2011,401(9):2955-2963
The main water-soluble carbohydrates in temperate forage grasses are polymeric fructans. Fructans consist of fructose chains
of various chain lengths attached to sucrose as a core molecule. In grasses, fructans are a complex mixture of a large number
of isomeric oligomers with a degree of polymerisation ranging from 3 to >100. Accurate monitoring and unambiguous peak identification
requires chromatographic separation coupled to mass spectrometry. The mass range of ion trap mass spectrometers is limited,
and we show here how monitoring selected multiply charged ions can be used for the detection and quantification of individual
isomers and oligomers of high mass, particularly those of high degree of polymerization (DP > 20) in complex plant extracts.
Previously reported methods using linear ion traps with low mass resolution have been shown to be useful for the detection
of fructans with a DP up to 49. Here, we report a method using high-resolution mass spectrometry (MS) using an Exactive Orbitrap
MS which greatly improves the signal-to-noise ratio and allows the detection of fructans up to DP = 100. High-sugar (HS) Lolium perenne cultivars with high concentrations of these fructans have been shown to be of benefit to the pastoral agricultural industry
because they improve rumen nitrogen use efficiency and reduce nitrous oxide emissions from pastures. We demonstrate with our
method that these HS grasses not only contain increased amounts of fructans in leaf blades but also accumulate fructans with
much higher DP compared to cultivars with normal sugar levels. 相似文献
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J.G. Mendoza-Alvarez M.P. Pires S.M. Landi A.S. Lopes P.L. Souza J.M. Villas-Boas N. Studart 《Physica E: Low-dimensional Systems and Nanostructures》2006,32(1-2):85
We report photoluminescence (PL) spectra of InP/InxGa1-xAs/InAs/InP dot-in-a-well structures grown by MOVPE, with different compositions of the ternary layer. Measurements with atomic force microscopy showed that the largest quantum dot (QD) height is obtained when the InAs QDs are grown on the InxGa1-xAs layer with a mismatch of 1000 ppm, and the height decreases as the mismatch departs from this value. PL spectra of the QDs showed an asymmetric band, which involves transitions between dot energy levels and can be deconvoluted into two peaks. The highest energy PL peak of this band was observed for the sample with the QDs grown on top of the lattice-matched InxGa1-xAs layer and it shifted to lower energies for strained samples as the degree of mismatch increased. Theoretical calculations of the energy levels of the entire structure were used to interpret the obtained PL spectra and determine the possible detection tunability range. 相似文献
5.
R.K. Murakami H.R. Rechenberg A.C. Neiva F.P. Missell V. Villas-Boas 《Journal of magnetism and magnetic materials》2008,320(14):e65-e68
Effects of titanium carbide (TiC) addition on structural and magnetic properties of isotropic (Pr,Nd)–Fe-B nanocrystalline magnetic materials have been investigated. In this work, we investigate the effect of TiC addition on a (Pr,Nd)-poor and B-rich composition, as well as on a B-poor and (Nd,Pr)-rich composition. Rapidly solidified (Pr,Nd)–Fe–B alloys were prepared by melt-spinning. The compositions studied were (Pr1−xNdx)4Fe78B18 (x=0, 0.5, and 1) with addition of 3 at% TiC. Unlike the (PrxNd1−x)9.5Fe84.5B6 materials that present excellent values for coercive field and energy product, the (Pr,Nd)-poor and B-rich composition alloys with TiC addition present lower values. Rietveld analysis of X-ray data and Mössbauer spectroscopy revealed that samples are predominantly composed of Fe3B and -Fe. For the RE-rich compositions (PrxNd1−x)9.5Fe84.5B6 (x=0.1, 0.25, 0.5, 0.75, and 1) with the addition of 3 at% TiC, the highest coercive field and energy product (8.4 kOe and 14.4 MGOe, respectively) were obtained for the composition Pr9.5Fe84.5B6. 相似文献
6.
Angela D. Barra-Barrera Angela M. Pizzo Valquíria Villas-Boas 《Journal of magnetism and magnetic materials》2006
Ribbons of Pr5Fe77−xCrxB18 (x=0, 1, 2, 2.5, 3, 4, 5) were produced by melt spinning and then annealed to develop an enhanced-remanence nanocrystalline magnetic material. These nanocomposites with Cr present a coercive field at least 50% higher than the Cr-free ones, which makes them promising materials for bonded magnets. Four different types of annealing were used in order to develop the nanocrystalline state and to optimize the magnetic properties of these alloys. The first was a conventional annealing, where the ribbons were wrapped in a tantalum foil and annealed in an argon atmosphere, but not encapsulated. The second was a flash annealing, where the ribbons were annealed by passing a current through them. The third was a conventional annealing in an external magnetic field. Finally, the fourth was a conventional annealing, where the ribbons were wrapped in a tantalum foil and encapsulated in quartz tubes with argon gas and then annealed. The annealed samples were studied by magnetic measurements, X-ray diffraction, scanning and transmission electron microscopy and atomic force microscopy. The best magnetic properties are found for Pr5Fe74Cr3B18, annealed by the fourth method, which resulted in the lowest oxygen content in the annealed nanocrystalline material as confirmed by scanning electron microscopy. The value for the coercive field for this composition is at least 50% higher than for the material without Cr (≈560 vs. ≈320 kA/m) and 40% higher than for the Nd2Fe14B/Fe3B nanocomposite with Cr. Curie temperature measurements and X-ray diffraction data showed that the main phases present in all the samples are Pr2Fe14B, Fe3B and α-Fe, Pr2Fe14B being the majoritary phase. From Curie temperature measurements it was also found that Cr atoms preferentially dissolve in the Fe3B phase. 相似文献
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Alex J. Lee Melissa M. Cadelis Sang H. Kim Simon Swift Brent R. Copp Silas G. Villas-Boas 《Molecules (Basel, Switzerland)》2020,25(24)
We have isolated a filamentous fungus that actively secretes a pigmented exudate when growing on agar plates. The fungus was identified as being a strain of Epicoccum nigrum. The fungal exudate presented strong antifungal activity against both yeasts and filamentous fungi, and inhibited the germination of fungal spores. The chemical characterization of the exudate showed that the pigmented molecule presenting antifungal activity is the disalt of epipyrone A—a water-soluble polyene metabolite with a molecular mass of 612.29 and maximal UV–Vis absorbance at 428 nm. This antifungal compound showed excellent stability to different temperatures and neutral to alkaline pH. 相似文献
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We investigate the quantum-to-classical crossover of a dissipative cavity field by measuring the correlations between two noninteracting atoms coupled to the cavity mode. First, we note that there is a time window in which the mode shows a classical behavior, which depends on the cavity decay rate, the atom-field coupling strength, and the number of atoms. Then, considering the steady state of two atoms inside the cavity, we note that the entanglement between the atoms disappears while the mean number of photons of the cavity field (n) rises. However, the quantum discord reaches an asymptotic nonzero value even in the limit of n→∞, whether n is increased coherently or incoherently. Therefore, the cavity mode always preserves some quantum characteristics in the macroscopic limit, which is revealed by the quantum discord. 相似文献
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D.R. Cornejo T.R.F. Peixoto P.F.P. Fichtner V. Villas-Boas 《Journal of magnetism and magnetic materials》2010,322(7):827-831
Ribbons of nominal composition (Pr9.5Fe84.5B6)0.96Cr0.01(TiC)0.03 were produced by arc-melting and melt-spinning the alloys on a Cu wheel. X-ray diffraction reveals two main phases, one based upon α-Fe and the other upon Pr2Fe14B. The ribbons show exchange spring behavior with Hc=12.5 kOe and (BH)max=13.6 MGOe when these two phases are well coupled. Transmission electron microscopy revealed that the coupled behavior is observed when the microstructure consists predominantly of α-Fe grains (diameter ∼100 nm.) surrounded by hard material containing Pr2Fe14B. A first-order-reversal-curve (FORC) analysis was performed for both a well-coupled sample and a partially-coupled sample. The FORC diagrams show two strong peaks for both the partially-coupled sample and for the well-coupled material. In both cases, the localization of the FORC probability suggests demagnetizing interactions between particles. Switching field distributions were calculated and are consistent with the sample microstructure. 相似文献
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