全文获取类型
收费全文 | 1189篇 |
免费 | 27篇 |
国内免费 | 2篇 |
专业分类
化学 | 877篇 |
晶体学 | 5篇 |
力学 | 24篇 |
数学 | 53篇 |
物理学 | 259篇 |
出版年
2021年 | 9篇 |
2020年 | 11篇 |
2019年 | 21篇 |
2018年 | 9篇 |
2017年 | 9篇 |
2016年 | 25篇 |
2015年 | 19篇 |
2014年 | 25篇 |
2013年 | 66篇 |
2012年 | 59篇 |
2011年 | 62篇 |
2010年 | 31篇 |
2009年 | 28篇 |
2008年 | 67篇 |
2007年 | 58篇 |
2006年 | 62篇 |
2005年 | 59篇 |
2004年 | 46篇 |
2003年 | 56篇 |
2002年 | 30篇 |
2001年 | 39篇 |
2000年 | 22篇 |
1999年 | 15篇 |
1997年 | 10篇 |
1996年 | 5篇 |
1995年 | 8篇 |
1994年 | 17篇 |
1993年 | 6篇 |
1992年 | 24篇 |
1991年 | 17篇 |
1990年 | 23篇 |
1989年 | 15篇 |
1988年 | 15篇 |
1987年 | 16篇 |
1986年 | 22篇 |
1985年 | 31篇 |
1984年 | 13篇 |
1983年 | 13篇 |
1982年 | 12篇 |
1981年 | 13篇 |
1980年 | 15篇 |
1979年 | 12篇 |
1978年 | 10篇 |
1977年 | 13篇 |
1976年 | 10篇 |
1975年 | 12篇 |
1974年 | 7篇 |
1973年 | 10篇 |
1969年 | 5篇 |
1968年 | 5篇 |
排序方式: 共有1218条查询结果,搜索用时 31 毫秒
1.
Naoto Sato Taiki Hayashi Kazuma Tochigi Prof. Hiroaki Wada Prof. Atsushi Shimojima Prof. Kazuyuki Kuroda 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(33):7860-7865
Eight corners of a double-four ring cage-type germanoxane, containing a fluoride ion, were successfully silylated by the combination of chlorosilanes and silazanes. Three different silyl groups, trimethylsilyl, dimethylsilyl, and dimethylvinylsilyl, were attached on the corners of germanoxane cage. The solubility and reactivity of the cage modified with dimethylvinylsilyl groups were significantly increased, allowing for further reaction. Hydrosilylation reaction between dimethylvinylsilylated cage geramanoxanes and dimethylsilylated cage siloxanes afforded porous solids. Functionalization of the corners of germanoxanes with silyl groups should provide valuable building blocks in various functional materials. 相似文献
2.
Asymmetric Total Synthesis of (−)‐Englerin A through Catalytic Diastereo‐ and Enantioselective Carbonyl Ylide Cycloaddition 下载免费PDF全文
Dr. Taiki Hanari Dr. Naoyuki Shimada Dr. Yasunobu Kurosaki Dr. Neetipalli Thrimurtulu Dr. Hisanori Nambu Dr. Masahiro Anada Prof. Dr. Shunichi Hashimoto 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(33):11671-11676
An asymmetric total synthesis of the guaiane sesquiterpene (?)‐englerin A, a potent and selective inhibitor of the growth of renal cancer cell lines, was accomplished. The basis of the approach is a highly diastereo‐ and enantioselective carbonyl ylide cycloaddition with an ethyl vinyl ether dipolarophile under catalysis by dirhodium(II) tetrakis[N‐tetrachlorophthaloyl‐(S)‐tert‐leucinate], [Rh2(S‐TCPTTL)4], to construct the oxabicyclo[3.2.1]octane framework with concomitant introduction of the oxygen substituent at C9 on the exo‐face. Another notable feature of the synthesis is ruthenium tetraoxide‐catalyzed chemoselective oxidative conversion of C9 ethyl ether to C9 acetate. 相似文献
3.
4.
Directing/Protecting‐Group‐Free Synthesis of Tetraaryl‐Substituted Pyrazoles through Four Direct Arylations on an Unsubstituted Pyrazole Scaffold 下载免费PDF全文
Dr. Shinichiro Fuse Taiki Morita Dr. Kohei Johmoto Dr. Hidehiro Uekusa Dr. Hiroshi Tanaka 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(41):14370-14375
A directing/protecting‐group‐free synthesis of 1,3,4,5‐tetraaryl‐substituted pyrazoles was achieved through four transition metal‐catalyzed direct arylations. Various pyrazoles with four different aryl rings were obtained using readily available reagents from an unsubstituted pyrazole. Two aryl‐substituted pyrazoles showed intense violet fluorescence, high quantum yields (Φf=0.68, 0.64), and large Stokes shifts (19000, 15200 cm?1). 相似文献
5.
Synthesis of Disaccharide Nucleosides by the O‐Glycosylation of Natural Nucleosides with Thioglycoside Donors 下载免费PDF全文
Prof. Shin Aoki Taketo Fukumoto Taiki Itoh Masayuki Kurihara Shigeto Saito Shin‐ya Komabiki 《化学:亚洲杂志》2015,10(3):740-751
Disaccharide nucleosides constitute an important group of naturally‐occurring sugar derivatives. In this study, we report on the synthesis of disaccharide nucleosides by the direct O‐glycosylation of nucleoside acceptors, such as adenosine, guanosine, thymidine, and cytidine, with glycosyl donors. Among the glycosyl donors tested, thioglycosides were found to give the corresponding disaccharide nucleosides in moderate to high chemical yields with the above nucleoside acceptors using p‐toluenesulfenyl chloride (TolSCl) and silver triflate (AgOTf) as promoters. The interaction of these promoters with nucleoside acceptors was examined by 1H NMR spectroscopic experiments. 相似文献
6.
Michael Andreas Tandiary Masashi Asano Taiki Hattori Satoshi Takehira Yoichi Masui Makoto Onaka 《Tetrahedron letters》2017,58(20):1925-1928
The solid acid, tin hydroxide-embedded montmorillonite, catalyzes the unprecedented alkylation of various silicon enolates with primary, secondary and tertiary benzylic alcohols as well as secondary allylic alcohols. The acid catalysis of Sn-Mont was not only higher than that of the other ion-exchanged montmorillonites (M-Mont; M = H, Ti, Fe and Al), but also higher than that of the typical homogeneous acid catalysts such as BF3·OEt2, TMSOTf and TfOH. 相似文献
7.
0Introduction Anelectronicpackageisgenerallyconstructedwithanactivesiliconchip,mountisland,gold wires,leadframesandsoldersasshowninFig.1(a).Toprotectfromtheenvironment,thesilicon chipisusuallyencapsulatedinresin.SincethesematerialshavedifferentCTE(coeffic… 相似文献
8.
Yoshihisa Morita Hirokazu Ninomiya 《Journal of Dynamics and Differential Equations》2006,18(4):841-861
We deal with a reaction–diffusion equation u
t
= u
xx
+ f(u) which has two stable constant equilibria, u = 0, 1 and a monotone increasing traveling front solution u = φ(x + ct) (c > 0) connecting those equilibria. Suppose that u = a (0 < a < 1) is an unstable equilibrium and that the equation allows monotone increasing traveling front solutions u = ψ1(x + c
1
t) (c
1 < 0) and ψ2(x + c
2
t) (c
2 > 0) connecting u = 0 with u = a and u = a with u = 1, respectively. We call by an entire solution a classical solution which is defined for all
. We prove that there exists an entire solution such that for t≈ − ∞ it behaves as two fronts ψ1(x + c
1
t) and ψ2(x + c
2
t) on the left and right x-axes, respectively, while it converges to φ(x + ct) as t→∞. In addition, if c > − c
1, we show the existence of an entire solution which behaves as ψ1( − x + c
1
t) in
and φ(x + ct) in
for t≈ − ∞. 相似文献
9.
Makoto Watanabe Masanori Morita Makoto Sakurai Mioko Maeda 《Phosphorus, sulfur, and silicon and the related elements》2013,188(6-7):1823-1826
Preparations of small-ring and short-chain condensed phosphates were made by dry and wet processes, respectively. The crystallization of tetra- hexa-, and octaphosphates from the phosphate solution was not easy, and metal salts of these oligophosphates were amorphous and unstable at normal temperature. Guanidine tetraphosphate and ammonium hexaphosphate were crystalline and stable at normal temperature. 相似文献
10.
The phase behaviour of the binary systems 4′- n -tetradecyloxy-3′-nitrobiphenyl-4-carboxylic acid (ANBC-14)- n -alkane ( n -tetradecane or n -hexadecane) was investigated by differential scanning calorimetry, polarizing optical microscopy, and X-ray diffraction. The phase behaviour was a function of temperature ( T ) and the effective carbon number of the system ( n*), where n* involves carbon atoms both from the alkoxy group of ANBC-14 and from the n -alkane added. ANBC-14 shows no cubic phase, but the addition of n -alkane induced cubic phases when n*≧c. 15. An interesting point is that the type of cubic phase is Ia 3 d for 15≦n*≦17, while an Im 3 m type is formed for 18≦n*≦20. Furthermore, for n* = 22, two types of cubic phase, one with Im 3 m symmetry in the low temperature region and the other with Ia 3 d in the high temperature region, were observed both on heating and cooling. The phase diagram with respect to T and n* is very similar to that of pure one-component ANBC- n , which is a function of T and the number of carbon atoms in the alkoxy group n . 相似文献