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Magnetophoretic velocimetry is a novel technique to measure the magnetic susceptibility of a single microparticle. This technique could be applied to study the interfacial adsorption equilibria of a paramagnetic dysprosium(III) ion with capric, lauric or stearic acid for a single 2-fluorotoluene microdroplet. The observed magnetic susceptibility of the micro-organic droplets was reciprocally proportional to its radius in each case. From the proportional constant, the interfacial concentration of Dy(III) was determined. Furthermore, the dependences of the interfacial concentration on the initial Dy(III) concentration and pH were examined in order to analyze the adsorption equilibrium. Finally, the saturated interfacial concentration and the interfacial adsorption constant at the infinite dilution of Dy(III)-laurate complex were evaluated as 4.8 x 10(-10) mol cm(-2) and 3.4 x 10(-2) dm, respectively. 相似文献
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Noriyuki Suwa 《Mathematische Zeitschrift》1987,195(1):13-16
Sans résumé 相似文献
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We successfully synthesized two enantiomers of bicyclic enones, (7R,7aR)- and (7S,7aS)-9, from the hemiacetal 2a, which we first synthesized from the symmetrical diketone 1a via diastereoselective carbon-oxygen bond formation between one of the carbonyl groups and the chiral alcohol on the C2 side chain in a 2,2-disubstituted 1,3-cycloalkanedione derivative. We also report the total synthesis of natural (+)-lycopladine A [(+)-6] from (7R,7aR)-9 and the formal synthesis of unnatural (-)-lycopladine A [(-)-6] from (7S,7aS)-9. 相似文献
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Takeshi Suwa Terutaka Watanabe Jiro Okamoto Sueo Machi 《Journal of polymer science. Part A, Polymer chemistry》1978,16(11):2931-2944
The radiation-induced emulsifier-free emulsion polymerization of tetrafluoroethylene was carried out at an initial pressure of 2–25 kg/cm2, temperature of 30–110°C, and under a dose rate of 0.57 × 104?3.0 × 104 rad/hr. The rate of polymerization was shown to be proportional to 1.0 and 1.3 powers of the dose rate and initial pressure, respectively, and is maximal at about 70°C. The molecular weight of polytetrafluoroethylene (PTFE) lies in the range of 105?106, increases with reaction time in the early stage of polymerization, and is maximal at 70°C but is almost independent of the dose rate. An interesting discovery is that PTFE, a hydrophobic polymer, forms as a stable latex in the absence of emulsifier. When PTFE latex coagulates during polymerization under certain conditions, the polymerization rate decreases, probably because polymerization proceeds mainly on the polymer particle surface. The observed rate acceleration and successive increase in polymer molecular weight may be due to slow termination of propagating radicals in the rigid PTFE particles. 相似文献
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Daniel Lehmann Marcio Soares Tatsuo Suwa 《Bulletin of the Brazilian Mathematical Society》1995,26(2):183-199
In this article we define and compute an index for a holomorphic vector field on a (possibly singular) subvariety of a complex manifold, provided the subvariety is a local complete intersection. This index reduces to the usual Poincaré-Hopf index in case the subvariety is smooth, and is equal more generally to the index defined in [GSV] and [SS]. 相似文献
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Tatsuo Suwa 《Mathematische Annalen》1979,240(3):281-286