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1.
Russian Chemical Bulletin - New representatives of (O-Si)-chelate compounds, N-(fluorosilyl)methyl derivatives of N-methylacetamide, N-methylbenzamide, N-phenylacetamide, and N-phenylbenzamide,... 相似文献
2.
I. V. Sterkhova V. V. Astakhova B. А. Shainyan 《Russian Journal of General Chemistry》2017,87(8):1680-1684
The methods of IR spectroscopy and quantum chemistry (B3LYP/DGDZVP) were applied to investigation of the types of self-associates formed in solutions of N-(2-hydroxy-3,8-diiodocyclooctyl)trifluoroacetamide and N-(4-iodo-2,2,5,5-tetramethyltetrahydrofuran-3-yl)trifluoroacetamide in CCl4 by means of hydrogen bonding. The ОН group of N-(2-hydroxy-3,8-diiodocyclooctyl)trifluoroacetamide participates in the formation of intramolecular hydrogen bond ОH···О=С, while chain dimers are formed due to interactions between the NH and С=О groups of the neighboring molecules. Due to the formation of the intramolecular bond, the dimers of N-(2-hydroxy-3,8-diiodocyclooctyl)trifluoroacetamide are energetically less stable than the chain dimer of N-(4-iodo-2,2,5,5-tetramethyltetrahydrofuran-3-yl)trifluoroacetamide. 相似文献
3.
M. M. Sterkhova 《Journal of Applied Mechanics and Technical Physics》1995,36(5):647-653
Novosibirsk State University, Novosibirsk 630090. Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 36,
No. 5, pp. 7–15, September–October, 1995. 相似文献
4.
Vera V. Astakhova Bagrat A. Shainyan Mikhail Yu. Moskalik Irina V. Sterkhova 《Tetrahedron》2019,75(33):4531-4541
The reaction of trimethyl(vinyl)silane 1 and dimethyl(divinyl)silane 2 with various sulfonamides in the oxidative system (tert-BuOCl + NaI) has been studied and shown to be an efficient approach for the synthesis of silylated N-heterocycles. Triflamide demonstrated the reactivity principally different from that of arenesulfonamides. With silane 1, it afforded the products of iodochlorination and bis(triflamidation) (major), whereas arenesulfonamides gave N-arenesulfonylaziridines in up to 91% yield. Silane 2 with arenesulfonamides yielded the products of mono and bis(iodochlorination), mono and bis(aziridination), and 3,5-diiodo-4,4-dimethyl-1-(arylsulfonyl)-1,4-azasilinanes. By contrast, triflamide, apart from the products of halogenation and iodotriflamidation, unexpectedly gave 3-(trifluoromethylsulfonyl)-5-(triflamido)oxazolidine as the main product. The structure of most heterocyclic products is proved by X-ray analysis. The effect of the silyl group in the substrate and of the substituent in the reagent on the course of oxidative sulfamidation is discussed by comparing with all-carbon analogues. 相似文献
5.
L. L. Tolstikova I. V. Sterkhova B. A. Shainyan 《Russian Journal of Organic Chemistry》2014,50(9):1247-1251
Urea and thiourea form complexes with trifluoromethanesulfonic acid, its monohydrate, and lithium salt CF3SO3Li. Urea complexes with trifluoromethanesulfonic acid are also formed as a result of hydrolysis in the reaction of N,N′-bis(trimethylsilyl)carbodiimide or cyanamide with trifluoromethanesulfonic acid in water. 相似文献
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7.
I. V. Sterkhova V. I. Smirnov G. A. Kuznetsova E. A. Zel’bst 《Journal of Structural Chemistry》2016,57(1):209-212
The crystal and molecular structures of 1-(iodmethyl)silatrane and 1-(iodpropyl)silatrane are determined by X-ray diffraction. The effect of the iodine heteroatom upon silatrane moieties of the molecules through oneand three-carbon chains is studied based on the geometric characteristics of the molecules and the analysis of their packings. 相似文献
8.
I. V. Sterkhova L. V. Kamaeva V. I. Lad’yanov 《Bulletin of the Russian Academy of Sciences: Physics》2008,72(10):1365-1367
The temperature and time dependences of the Fe79Cr21 melt viscosity have been investigated by the method of damping torsional vibrations of a crucible with one or two face surfaces. Anomalies in the viscosity polytherms at certain temperatures have been found for the first time. The display of these anomalies is determined by the melt structure and the melt-crucible interaction. 相似文献
9.
I. V. Sterkhova N. N. Chipanina B. A. Shainyan V. K. Turchaninov 《Russian Journal of General Chemistry》2007,77(1):84-89
In two-centered H-complexes with protophilic solvents, the monomer of N-methyltrifluoromethanesulfonamide I behaves as a strong H-bond donor, stronger than 4-fluorophenol and ranking second after 4-nitrophenol. In protophilic media, amide I exists as monomeric H-complexes with a two-centered H-bond and 1:2 H-complexes of the open-chair dimer with a bifurcated (three-centered) hydrogen bond. The formation of a strong bifurcated H-bond weaken the bridging N-H.‥O=S bond. 相似文献
10.
Golovnev N. N. Molokeev M. S. Sterkhova I. V. Lesnikov M. K. 《Russian Journal of Coordination Chemistry》2019,45(8):569-572
Russian Journal of Coordination Chemistry - The structure of the complex [Cu(Bipy)2(BA)] ? 7H2O (I), where Bipy is 2,2'-dipyridyl, and BA2– is the barbituric acid anion (H2BA), is... 相似文献