Oxidative Conversion of 3‐Alkoxyfurans to 2‐Hydroxy‐3(2H)‐furanones and 2‐Hydroxy‐2‐butene‐1,4‐diones with 2,3‐Dichloro‐5,6‐dicyano‐1,4‐benzoquinone (DDQ) or Phenyltrimethylammonium Tribromide (PTAB) in t‐BuOH

2‐Alkoxy‐1,3,4‐triphenylfurans were oxidized to 3‐alkoxy‐2,4,5‐triphenyl‐ 2‐butene‐1,4‐diones with 2,3‐dichloro‐5,6‐dicyano‐1,4‐benzoquinone (DDQ) in t‐BuOH. In contrast, various 3‐alkoxy‐2,4,5‐triphenylfurans were directly converted to 2‐hydroxy‐3(2H)‐furanone with phenyltrimethylammonium tribromide (PTAB) in t‐BuOH. The oxidative ring opening of 3‐alkoxy‐2,5‐diphenylfurans to cis‐2‐hydroxy‐2‐butene‐1,4‐dione was also accomplished with PTAB in t‐BuOH under the same reaction conditions.     

Magnetic circular dichroism of [Co/Pd] and [CoB/Pd] multilayered films

Magnetic circular dichroism (MCD) and X-ray absorption spectra (XAS) at the Co L_2,3-edge of [Co/Pd]₂₀ and [CoB/Pd]₂₀ multilayered films, which were fabricated at 260 °C with different magnetic layer thicknesses (δ), have been measured. The lineshapes of XAS–MCD show that the electronic state of Co 3d of the films hardly changes even when sputtered at higher temperatures. The expectation values of orbital and spin angular momentum (〈L_z〉 and 〈S_z〉) are estimated using the sum rule, and it is found that 〈L_z〉/〈S_z〉 in δ<0.5 nm is larger than that in δ>0.5 nm.     

Suppression of Sea-Ice Clutter Observed by a Millimeter Wave Radar Using a New Log-Weibull/CFAR System

Sea-ice clutter was measured using a millimeter wave radar with frequency of 34.860GHz, beamwidth of 0.25° and pulse length of 30ns. To determine the sea-ice clutter amplitude statistics, we investigated the log-normal, Weibull, log-Weibull and K-distributions using the Akaike Information Criterion (AIC), which is more rigorous fit of the distribution to the data than the least-squares method. It is shown that the amplitude of sea-ice clutter obeys the log-Weibull distribution with shape parameters of 2.36 to 2.93 for both entire data and data within the beam width of an antenna. We propose a new log-Weibull/CFAR system uses a modified cell-averaging LOG/CFAR system. It is found that this log-Weibull/CFAR procedure is effective for suppression of sea-ice clutter and detection of target.     

Complex genetic evolution of artificial self‐replicators in cellular automata

It is widely believed that evolutionary dynamics of artificial self‐replicators realized in cellular automata (CA) are limited in diversity and adaptation. Contrary to this view, we show that complex genetic evolution may occur within simple CA. The evolving self‐replicating loops (“evoloops”) we investigate exhibit significant diversity in macro‐scale morphologies and mutational biases, undergoing nontrivial genetic adaptation by maximizing colony density and enhancing sustainability against other species. Nonmutable subsequences enable genetic operations that alter fitness differentials and promote long‐term evolutionary exploration. These results demonstrate a unique example of genetic evolution hierarchically emerging from local interactions between elements much smaller than individual replicators. © 2004 Wiley Periodicals, Inc. Complexity 10: 33–39, 2004     

Multimodality analysis of a class of multistage allocation problems

Multiple optimum solutions of a multistage allocation problem, well-known to chemical engineers, are analyzed. The number of local optima becomes greater with a decrease in the initial-condition value of the first stage or with an increase in the total stage number. The fact that this behavior is closely related to the flat portion of the profile of a curvef(x), which determines the objective function, is revealed. A construction method by Aris is used to give an excellent insight into this behavior. Moreover, the construction curves ensure that all stationary points are found. Finally, a theorem to discriminate local optima from stationary points, without evaluating second-order derivatives, is presented.The authors would like to thank Dr. I. Hashimoto and Dr. H. Nishitani for valuable discussions. Computations were carried out with the assistance of Messrs. H. Unno, H. Nakano, Y. Era, and Y. Ueno. The authors are indebted to the computing centers of Osaka University, Kyoto University, and Nagoya University for the use of their facilities.     

L?sungseigenschaften von synthetischen Polypeptiden. 11. Mitt

Ohne Zusammenfassung