Subtle Alignment of Organic Semiconductors at the Donor/Acceptor Heterojunction Facilitates the Photoelectric Conversion Process

Chinese Journal of Polymer Science - The aligned molecular packing structure is vital to the anisotropic charge transport in conjugated polymer and small molecule thin films. However, how this...     

非均匀部分相干光束在自由空间中的传输

本文介绍了非均匀部分相干光束的概念, 并用数值模拟的方法详细研究了其在自由空间传输后的变化. 研究结果表明, 经过自由空间传输后非均匀部分相干光束会发生不同于传统相干模型光束的显著变化. 这种变化和光束传输距离、光源空间相干度分布、光源光强分布密切相关. 经过传输后, 源平面自相干附近点的空间相干度发生突变, 在短距离传输过程中源平面高相干区域的空间相干度会降低, 接收面各点的空间相干曲线不再相同, 随着传输距离增加, 非均匀空间相干度会逐渐趋于均匀.     

High-dimensional model representations generated from low order terms--lp-RS-HDMR

High-dimensional model representation (HDMR) is a general set of quantitative model assessment and analysis tools for improving the efficiency of deducing high dimensional input-output system behavior. RS-HDMR is a particular form of HDMR based on random sampling (RS) of the input variables. The component functions in an HDMR expansion are optimal choices tailored to the n-variate function f(x) being represented over the desired domain of the n-dimensional vector x. The high-order terms (usually larger than second order, or equivalently beyond cooperativity between pairs of variables) in the expansion are often negligible. When it is necessary to go beyond the first and the second order RS-HDMR, this article introduces a modified low-order term product (lp)-RS-HDMR method to approximately represent the high-order RS-HDMR component functions as products of low-order functions. Using this method the high-order truncated RS-HDMR expansions may be constructed without directly computing the original high-order terms. The mathematical foundations of lp-RS-HDMR are presented along with an illustration of its utility in an atmospheric chemical kinetics model.     

Monte Carlo Simulation of Optical Properties of Wake Bubbles

Based on Mie scattering theory and the theory of multiple light scattering, the light scattering properties of air bubbles in a wake are analysed by Monte Carlo simulation. The results show that backscattering is enhanced obviously due to the existence of bubbles, especially with the increase of bubble density, and that it is feasible to use the Monte Carlo method to study the properties of light scattering by air bubbles.     

Analysis of Cr atom focusing deposition properties in the double half Gaussian standing wave field

The use of the dipole force on atoms is a new technology that is used to build nanostructures. In this way, a high quality standard nano-grating can be obtained. Based on the semi-classical model, the motion equation is investigated and the trajectories of atoms in double half Gaussian standing wave field are simulated. Compared with the Gaussian standing wave field, the double half Gaussian standing wave can well focus the Cr atoms. In order to obtain this kind of beam, a prism is designed and the experimental result shows that the beam is well generated.     

Structured mirror array for two-dimensional collimation of a chromium beam in atom lithography

Direct-write atom lithography,one of the potential nanofabrication techniques,is restricted by some difficulties in producing optical masks for the deposition of complex structures.In order to make further progress,a structured mirror array is developed to transversely collimate the chromium atomic beam in two dimensions.The best collimation is obtained when the laser red detunes by natural line-width of transition 7S3 → 7P40 of the chromium atom.The collimation ratio is 0.45 vertically(in x axis),and it is 0.55 horizontally(in y axis).The theoretical model is also simulated,and success of our structured mirror array is achieved.     

Electrode process of Nd-Fe alloy formed on iron electrode in molten chlorides

The cyclic voltammetry, convolution voltammetry and chronopotentiometry were used to study the electrode process of Nd (III) reduced on iron electrode in molten NaCl-KCl-NdCl₃ from 700 to 850°C. The electrodeposited products were analysed by X-ray diffraction. The results indicate that the intermetallic compound Fe₂Nd forms first, and then the metallic neodymium deposits when Nd (III) is reduced on iron electrode. The Nd-Fe alloys rich in neodymium can be obtained by electrolysis with iron cathode in molten chlorides. The Nd-Fe alloys are composed of Fe₂Nd and Nd.     

Lithium electrochromism of atmospheric pressure plasma jet-synthesized NiO x C y thin films

Reversible lithium intercalation and deintercalation behavior of atmospheric pressure plasma jet (APPJ)-synthesized organonickel oxide (NiO _x C _y ) thin films under various substrate distances is testified in an electrolyte (1?M LiClO₄–propylene carbonate solution) at low driving voltages from ?0.5 to 1.5?V. Fast responses of 2?s bleaching at ?0.5?V and 6?s coloration at +1.5?V are accomplished for the nano-porous NiO _x C _y thin films. This study reveals that a rapid synthesis of electrochromic NiO _x C _y thin films in a single process via APPJ by 21?s is investigated. This study presents a noteworthy electrochromic performance in a light modulation with up to 43% of transmittance variation and a coloration efficiency of 36.3?cm²/C at a wavelength of 830?nm after 200?cycles of cyclic voltammetry measurements.     

不同结构碳黑填充的复合体系的太赫兹时域光谱研究

利用熔融共混、压片的方法制备了两种不同结构的碳黑(乙炔碳黑和高结构碳黑)填充的高密度聚乙烯复合材料,并利用太赫兹时域光谱研究了复合体系在太赫兹波段的介电性质.研究发现,随着频率的增加,体系的吸收系数逐渐增大而折射率则逐渐降低;在相同的频率下,吸收系数和折射率均随颗粒浓度的增加而增大;与乙炔碳黑相比,相同浓度的高结构碳熙填充的复合体系具有较大的吸收系数和较低的折射率,这与碳黑的颗粒结构以及颗粒间的团聚状态是紧密相关的.假定复合体系的介电损耗是由碳黑颗粒内部载流子的极化和聚乙烯基体的界面极化所导致的,利用双德拜模型对实验结果进行了解释,分别得到了两种极化模式所对应的弛豫时间和弛豫强度等信息.     

Supercapacitive performance of porous graphene nanosheets in bis(trifluoromethylsulfony)imide and bis(fluorosulfonyl)imide ionic liquid electrolytes

Journal of Solid State Electrochemistry - A method of high-heating-rate thermal reduction is used to produce porous graphene nanosheets (PGNSs). This material is characterized by a unique holey...