Around Multicolour Disordered Lattice Gas

We consider a system of multicolour disordered lattice gas, following closely the (monocolour) introduced by Faggionato and Martinelli^(3,4). We study the projection on the monocolour system and we derive an estimate of the closeness between grand canonical and canonical Gibbs measures. AMS Classification: Primary: 60K35, 82C20, 82C22     

Selective one-pot synthesis of substituted pyrrole-3-phosphonates from α-cyanomethyl-β-ketoesters

A one-step synthesis of 5-alkoxypyrrole-3-phosphonates is presented starting from suitable α-cyanomethyl-β-ketophosphonates. The key step in the synthesis involves a one-pot addition and heteroannulation sequence. The zinc perchlorate-catalyzed addition of alcohols to the nitrile carbon of α-cyanomethyl-β-ketophosphonates followed by annulation furnished 5-alkoxypyrrole-3-phosphonates. The addition-annulation process is carried out in the presence of water and 4,5-dihydro-5-oxo-1H-pyrrole-3-phosphonates (pyrrolinones) are obtained in good yields.     

A Gibbs Approach to Chargaff’s Second Parity Rule

Chargaff’s second parity rule (CSPR) asserts that the frequencies of short polynucleotide chains are the same as those of the complementary reversed chains. Up to now, this hypothesis has only been observed empirically and there is currently no explanation for its presence in DNA strands. Here we argue that CSPR is a probabilistic consequence of the reverse complementarity between paired strands, because the Gibbs distribution associated with the chemical energy between the bonds satisfies CSPR. We develop a statistical test to study the validity of CSPR under the Gibbsian assumption and we apply it to a large set of bacterial genomes taken from the GenBank repository.     

Construction of biosensor for hypoxanthine determination by immobilization of xanthine oxidase and uricase in polypyrrole-paratoluenesulfonate film

Journal of Solid State Electrochemistry - A highly selective and stable amperometric biosensor for the determination of the hypoxanthine (Hx) molecule was designed in this study. For this purpose,...     

直觉Menger空间中的广义压缩映射原理及其在微分方程中的应用

利用Atanassov的思路,将直觉Menger空间定义为由Menger提出的Menger空间的自然推广.同时也得出一个新广义压缩映射,并运用该压缩映射证明了直觉Menger空间中微分方程解的存在性定理.     

Asymptotic behaviour of a Brownian motion on exterior domains

We study the asymptotic behaviour of the transition density of a Brownian motion in ?, killed at ∂?, where ? ^c is a compact non polar set. Our main result concern dimension d = 2, where we show that the transition density p ^? _t (x, y) behaves, for large t, as u(x)u(y)(t(log t)²)⁻¹ for x, y∈?, where u is the unique positive harmonic function vanishing on (∂?) ^r , such that u(x) ∼ log ∣x∣. Received: 29 January 1999 / Revised version: 11 May 1999     

Generalized contraction mapping principle in intuitionistic Menger spaces and application to differential equations

Using the idea of Atanassov, we define the notion of intuitionistic Menger spaces as a netural generalizations of Menger spaces due to Menger. We also obtain a new generalized contraction mapping and utilize this contraction mapping to prove the existance theorems of solutions to differential equations in intuitionistic Menger spaces.     

Ratio limit theorem for parabolic horn-shaped domains

We prove that for horn-shaped domains of parabolic type, the ratio of the heat kernel at different fixed points has a limit when the time tends to infinity. We also give an explicit formula for the limit in terms of the harmonic functions.

     

Level–wise Approximation of a Markov Process Associated to the Boundary of an Infinite Tree

We study an approximation of a Markov process associated to the boundary of an infinite rooted tree. This approximation is constructed by projecting the infinitesimal generator of the original process (defined on the boundary) onto the spaces associated to the filtration spanned by the successive levels of the rooted tree. S. Martínez and J. San Martín acknowledge the support by Nucleus Millenium Information and Randomness P04-069-F. D. Remenik current address: Center for Applied Mathematics, Cornell University, 657 Rhodes Hall, Ithaca, NY 14853. The author acknowledges the partial support by Nucleus Millenium Information and Randomness P01-005 for his work in his undergraduate thesis at Universidad de Chile.     

The pianigiani-yorke measure for topological markov chains

We prove the existence of a Pianigiani-Yorke measure for a Markovian factor of a topological Markov chain. This measure induces a Gibbs measure in the limit set. The proof uses the contraction properties of the Ruelle-Perron-Frobenius operator.