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1.
WS2由于其优异的物理和光电性质引起了广泛关注。本研究基于第一性原理计算方法,探索了本征单层WS2及不同浓度W原子替位钇(Y)掺杂WS2的电子结构和光学特性。结果表明本征单层WS2为带隙1.814 eV的直接带隙半导体。进行4%浓度(原子数分数)的Y原子掺杂后,带隙减小为1.508 eV,依旧保持着直接带隙的特性,随着Y掺杂浓度的不断增大,掺杂WS2带隙进一步减小,当浓度达到25%时,能带结构转变为0.658 eV的间接带隙,WS2表现出磁性。适量浓度的掺杂可以提高材料的导电性能,且掺杂浓度增大时,体系依旧保持着透明性并且在红外光和可见光区对光子的吸收能力、材料的介电性能都有着显著提高。本文为WS2二维材料相关光电器件的研究提供了理论依据。 相似文献
2.
Dang Huyen Vu Xuan Dang Hanh Vu Bich Doan Huu Dung Nguyen Tan Phong 《Research on Chemical Intermediates》2022,48(3):1311-1311
Research on Chemical Intermediates - 相似文献
3.
Bao Nguyen Xuan Duy Khanh Phan Quoc Tung Nguyen Minh 《Set-Valued and Variational Analysis》2022,30(2):465-486
Set-Valued and Variational Analysis - We aim to establish Karush-Kuhn-Tucker multiplier rules involving higher-order complementarity slackness under Hölder metric subregularity. These rules... 相似文献
4.
Rongrong Li Hongjie Peng Qingping Wu Xuejun Zhou Jiang He Hangjia Shen Minghui Yang Chilin Li 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(29):12227-12236
Herein, we propose the construction of a sandwich-structured host filled with continuous 2D catalysis–conduction interfaces. This MoN-C-MoN trilayer architecture causes the strong conformal adsorption of S/Li2Sx and its high-efficiency conversion on the two-sided nitride polar surfaces, which are supplied with high-flux electron transfer from the buried carbon interlayer. The 3D self-assembly of these 2D sandwich structures further reinforces the interconnection of conductive and catalytic networks. The maximized exposure of adsorptive/catalytic planes endows the MoN-C@S electrode with excellent cycling stability and high rate performance even under high S loading and low host surface area. The high conductivity of this trilayer texture does not compromise the capacity retention after the S content is increased. Such a job-synergistic mode between catalytic and conductive functions guarantees the homogeneous deposition of S/Li2Sx, and avoids thick and devitalized accumulation (electrode passivation) even after high-rate and long-term cycling. 相似文献
5.
A new environment-friendly bentonite intercalation composite was successfully obtained from alumina sol intercalation. This process used industrial grade pseudo boehmite as the aluminum source and provided with the advantage of zero emission of acidic wastewater. The bentonite intercalation composite was investigated by XRF, ICP, XRD, FT-IR, BET, and pyridine-FTIR. Results indicated that the basal spacing was enlarged from 14.72 to 15.60 Å; the specific surface area increased by 128%; and the total acid content increased from 65.32 to 245.76 μmol/g. The catalytic activity of this composite was tested by alkylation of aromatics with olefins. The results show that the weak Lewis acid generated by extra-framework aluminum and specific surface area play a decisive role, while weak Brønsted acid site is not the active site for this alkylation reaction. 相似文献
6.
You Qin Rongrong Zhou Jian Jin Jing Xie Hao Liu Ping Cai Jun Shu Yahui Zhao Luqi Huang Shuihan Zhang 《Biomedical chromatography : BMC》2020,34(8):e4841
Ophiocordyceps xuefengensis (O. xuefengensis), a new species of caterpillar fungus, has been identified as the sister taxon of Ophiocordyceps sinensis (O. sinensis). The aims of the present study are to evaluate the anticancer activity and to qualitatively analyze the potential bioactive chemical constituents of O. xuefengensis and O. sinensis, comparatively. An MTT assay was used to evaluate the in vitro anticancer activities of different fractions from O. xuefengensis and O. sinensis. The results show that ethyl acetate fractions of O. xuefengensis and O. sinensis have significant in vitro anticancer activity. These two bioactive fractions were analyzed by ultra-performance liquid chromatography–electrospray ionization with quadrupole–time of flight tandem mass spectrometry technology. A total of 82 compounds and 101 compounds were identified or tentatively characterized in the bioactive fractions of O. xuefengensis and O. sinensis, respectively. Among these compounds, 68 existed in both O. xuefengensis and O. sinensis. A total of 67 compounds were reported in O. xuefengensis and 8 compounds were reported in caterpillar fungus for the first time. This is the first detailed comparative analysis of the in vitro anticancer activity and chemical ingredients between O. xuefengensis and O. sinensis. The application of this work will provide reliable fundamental pharmacological substances for the use of O. xuefengensis by Yao people. 相似文献
7.
为探索油-气-水三相流持气率测量难题,该文开展了脉冲透射式超声传感器持气率测量动态实验研究。首先,利用超声传感器与光纤传感器组合,测取了油-气-水三相流中段塞流、混状流、泡状流的响应信号;其次,提取了超声脉冲信号的最大值序列来反映不同流型时超声传感器响应特性,同时,借助双头光纤传感器与相关测速法,计算得到了流体中气泡弦长序列;最后,结合流型与泡径信息,利用超声传感器测量了不同流型下持气率,并分析了不同流型持气率预测的误差来源,为其他油-气-水三相流持气率测量传感器设计提供了借鉴。 相似文献
8.
9.
Khaled Tawfik Alali Dr. Jingyuan Liu Dr. Rongrong Chen Dr. Qi Liu Dr. Hongsen Zhang Jundong Li Jindi Hou Prof. Rumin Li Prof. Jun Wang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(51):11892-11902
Semiconductor metal oxides (SMO)-based gas-sensing materials suffer from insufficient detection of a specific target gas. Reliable selectivity, high sensitivity, and rapid response–recovery times under various working conditions are the main requirements for optimal gas sensors. Chemical warfare agents (CWA) such as sarin are fatal inhibitors of acetylcholinesterase in the nerve system. So, sensing materials with high sensitivity and selectivity toward CWA are urgently needed. Herein, micro-nano octahedral Co3O4 functionalized with hexafluoroisopropanol (HFIP) were deposited on a layer of reduced graphene oxide (rGO) as a double-layer sensing materials. The Co3O4 micro-nano octahedra were synthesized by direct growth from electrospun fiber templates calcined in ambient air. The double-layer rGO/Co3O4-HFIP sensing materials presented high selectivity toward DMMP (sarin agent simulant, dimethyl methyl phosphonate) versus rGO/Co3O4 and Co3O4 sensors after the exposure to various gases owing to hydrogen bonding between the DMMP molecules and Co3O4-HFIP. The rGO/Co3O4-HFIP sensors showed high stability with a response signal around 11.8 toward 0.5 ppm DMMP at 125 °C, and more than 75 % of the initial response was maintained under a saturated humid environment (85 % relative humidity). These results prove that these double-layer inorganic–organic composite sensing materials are excellent candidates to serve as optimal gas-sensing materials. 相似文献
10.
Bo Zhang Dr. Jinhui Li Feng Liu Tao Wang Ying Wang Rui Xuan Prof. Guoping Zhang Prof. Rong Sun Prof. Ching-Ping Wong 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(50):11715-11724
The practical application of advanced personalized electronics is inseparable from flexible, durable, and even self-healable energy storage devices. However, the mechanical and self-healing performance of supercapacitors is still limited at present. Herein, highly transparent, stretchable, and self-healable poly(2-acrylamido-2-methyl-1-propanesulfonic acid) (PAMPSA)/poly(vinyl alcohol) (PVA)/LiCl polyelectrolytes were facilely prepared by one-step radical polymerization. The cooperation of PAMPSA and PVA significantly increased the mechanical and self-healing capacity of the polyelectrolyte, which exhibited superior stretchability of 938 %, stress of 112.68 kPa, good electrical performance (ionic conductivity up to 20.6 mS cm−1), and high healing efficiency of 92.68 % after 24 h. After assembly with polypyrrole-coated single-walled carbon nanotubes, the resulting as-prepared supercapacitor had excellent electrochemical properties with high areal capacitance of 297 mF cm−2 at 0.5 mA cm−2 and good rate capability (218 mF cm−2 at 5 mA cm−2). Besides, after cutting in two the supercapacitor recovered 99.2 % of its original specific capacitance after healing for 24 h at room temperature. The results also showed negligible change in the interior contact resistance of the supercapacitor after ten cutting/healing cycles. The present work provides a possible solution for the development of smart and durable energy storage devices with low cost for next-generation intelligent electronics. 相似文献