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排序方式: 共有2281条查询结果,搜索用时 359 毫秒
1.
Dr. Felipe L. Coelho Eduarda S. Gil Dr. Paulo F. B. Gonçalves Dr. Leandra F. Campo Dr. Paulo H. Schneider 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(34):8157-8162
In this work, a series of 2-chalcogenylindoles was synthesized by an efficient methodology, starting from chalcogenoalkynes, including a previously unreported tellurium indole derivative. For the first time, these 2-substituted chalcogenylindoles were obtained in the absence of metal catalyst or base, under thermal conditions only. In addition, the results described herein represent a methodology with inverse regioselectivity for the chalcogen functionalization of indoles. 相似文献
2.
3.
J. C. Fabris S. V. B. Gonçalves P. E. de Souza 《General Relativity and Gravitation》2002,34(12):2111-2126
The mass power spectrum for a Universe dominated by the Chaplygin gas is evaluated numerically from scales of the order of the Hubble horizon to 100 Mpc. The results are compared with a pure baryonic Universe and a cosmological constant model. In all three cases, the spectrum increases with k, the wavenumber of the perturbations. The slope of the spectrum is higher for the baryonic model and smaller for the cosmological constant model, the Chaplygin gas interpolating these two models. The results are analyzed in terms of the sound velocity of the Chaplygin gas and the moment the Universe begins to accelerate. 相似文献
4.
D. C. Oliveira Y. Messaddeq K. Dahmouche S. J. L. Ribeiro R. R. Gonçalves A. Vesperini D. Gindre J.-M. Nunzi 《Journal of Sol-Gel Science and Technology》2006,40(2-3):359-363
Organic-inorganic hybrid materials were prepared from an ureasil precursor (ureapropyltriethoxysilane designated as UPTES)
and acrylic acid modified zirconium (IV) n-propoxide. Thin films containing rhodamine 6G (Rh6G) were prepared by spin-coating on glass substrates with different Zr:Si molar ratios (Zr:Si = 75:25, 50:50 and 25:75). Refractive
index, thickness, number of propagating modes and attenuation coefficient were measured at 543.5, 632.8 and 1550 nm wavelengths
by the prism coupling technique. Distributed feedback (DFB) laser effect was observed and studied as a function of films thickness
and refractive index. 相似文献
5.
Rodrigo París José Luis de la Fuente 《Journal of polymer science. Part A, Polymer chemistry》2007,45(16):3538-3549
Different diblock copolymers constituted by one segment of a monomer supporting a reactive functional group, like allyl methacrylate (AMA), were synthesized by atom transfer radical polymerization (ATRP). Bromo‐terminated polymers, like polystyrene (PS), poly(methyl methacrylate) (PMMA), and poly(butyl acrylate) (PBA) were employed as macroinitiators to form the other blocks. Copolymerizations were carried out using copper chloride with N,N,N′,N″,N″‐pentamethyldiethylenetriamine (PMDETA) as the catalyst system in benzonitrile solution at 70 °C. At the early stage, the ATRP copolymerizations yielded well‐defined linear block copolymers. However, with the polymerization progress a change in the macromolecular architecture takes place due to the secondary reactions caused by the allylic groups, passing to a branched and/or star‐shaped structure until finally yielding gel at monomer conversion around 40% or higher. The block copolymers were characterized by means of size exclusion chromatography (SEC), 1H NMR spectroscopy, and differential scanning calorimetry (DSC). In addition, one of these copolymers, specifically P(BA‐b‐AMA), was satisfactorily modified through osmylation reaction to obtain the subsequent amphiphilic diblock copolymer of P(BA‐b‐DHPMA), where DHPMA is 2,3‐dihydroxypropyl methacrylate; demonstrating the feasibility of side‐chain modification of the functional obtained copolymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3538–3549, 2007 相似文献
6.
Given a map f: X→Y and a Nielsen root class, there is a number associated to this root class, which is the minimal number of points among all
root classes which are H-related to the given one for all homotopies H of the map f. We show that for maps between closed surfaces it is possible to deform f such that all the Nielsen root classes have cardinality equal to the minimal number if and only if either N R[f]≤1, or N R[f]>1 and f satisfies the Wecken property. Here N R[f] denotes the Nielsen root number. The condition “f satisfies the Wecken property is known to be equivalent to |deg(f)|≤N R[f]/(1−χ(M
2)−χ(M
10/(1−χ(M
2)) for maps between closed orientable surfaces. In the case of nonorientable surfaces the condition is A(f)≤N R[f]/(1−χ(M
2)−χ(M
2)/(1−χ(M
2)). Also we construct, for each integer n≥3, an example of a map f: K
n
→N from an n-dimensionally connected complex of dimension n to an n-dimensional manifold such that we cannot deform f in a way that all the Nielsen root classes reach the minimal number of points at the same time. 相似文献
7.
E. de A. Gonçalves V. M. de Oliveira A. Rosas P. R.A. Campos 《The European Physical Journal B - Condensed Matter and Complex Systems》2007,59(1):127-132
Adaptation of populations takes place with the occurrence and subsequent fixation of mutations that confer some selective
advantage
to the individuals which acquire it. For this reason, the study of the process of fixation of advantageous mutations has a
long history
in the population genetics literature. Particularly, the previous investigations aimed to find out the main evolutionary forces
affecting the strength of natural selection in the populations.
In the current work, we investigate the dynamics of fixation of beneficial mutations in a subdivided population. The subpopulations
(demes)
can exchange migrants
among their neighbors, in a migration network which is assumed to have either a random graph or a scale-free topology. We
have observed that the migration rate
drastically affects the dynamics of mutation fixation, despite of the fact that the probability of fixation is invariant on
the
migration rate, accordingly to
Maruyama's conjecture. In addition, we have noticed a topological dependence of the adaptive evolution of the population when
clonal interference
becomes effective. 相似文献
8.
Humberto César Chaves Fernandes Arthur Rodrigo Barros da Rocha 《International Journal of Infrared and Millimeter Waves》2003,24(7):1171-1176
The use of photonic materials has been used in the theory of optical waves. The PBG (Photonic Band Gap) theory and material, was developed recently for optical frequencies and can be easily applied to millimeter waves, microwaves and planar antenna frequencies. The presence of photonic materials as substrate in antennas has some good characteristics such as, supression of light spontaneous emission and suppression of surface waves, allowing the application in planar antenna array. In this work an elaborate analysis using the full wave Transverse Transmission Line - TTL method, that provides efficient and concise results is applied to the planar antennas array with PBG substrate. 相似文献
9.
This work presents a formulation based on UPML for truncating conductive media by using a local and non-orthogonal coordinate
system to solve Maxwell’s equations by the FDTD method. The detailed procedure for obtaining the UPML equations for this case
is shown and the complete equation set is provided. 相似文献
10.
Gianluigi Luppi Rodrigo J. Corrêa Angelo C. Pinto Quirinus B. Broxterman Claudia Tomasini 《Tetrahedron》2006,62(51):12017-12024
The first total synthesis of (R)-convolutamydine A has been achieved by the organocatalytic addition of acetone to 4,6-dibromoisatin. The absolute configuration was determined by single crystal X-ray diffraction. DFT studies were used to model the transition states for the aldol reaction and equilibrium geometries of the post-aldol reaction intermediates. The DFT study revealed that the aldol bond forming reaction was considerably endothermic. 相似文献