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排序方式: 共有224条查询结果,搜索用时 15 毫秒
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Alexey P. Popov Alexander V. Priezzhev Risto Myllylä 《Journal of Quantitative Spectroscopy & Radiative Transfer》2011,112(11):1891-1897
We report about the results of our investigations on the alteration of optical properties of the superficial layer of human skin at four UV range wavelengths, 310, 318, 360 and 400 nm, by application of 35-200 nm-sized particles of titanium dioxide (TiO2), silicon (Si) and zinc oxide (ZnO). The theoretical study based on combination of the Mie theory and Monte Carlo simulations reveals the optimal sizes of the nanoparticles minimizing the light transmittance for the considered wavelengths. 相似文献
4.
A formalism is presented for calculating exactsolutions of covariant inhomogeneous scalar and tensorwave equations whose source terms are arbitrary ordermultipoles on a curved background spacetime. The developed formalism is based on the theory ofthe higher-order fundamental solutions for wave equationwhich are the distributions that satisfy theinhomogeneous wave equation with the corresponding order covariant derivatives of the Dirac deltafunction on the right-hand side. Like the classicalGreen's function for a scalar wave equation, thehigher-order fundamental solutions contain a direct termwhich has support on the light cone as well as a tailterm which has support inside the light cone. Knowinghow to compute the fundamental solutions of arbitraryorder, one can find exact multipole solutions of wave equations on curved spacetimes. Wepresent complete recurrent algorithms for calculatingthe arbitrary-order fundamental solutions and the exactmultipole solutions in a form convenient for practical computations. As an example we apply thealgorithm to a massless scalar wave field on aparticular Robertson-Walker spacetime. 相似文献
5.
Risto Koivula 《Central European Journal of Chemistry》2010,8(6):1179-1184
Antimony is perhaps the most frequently used doping element of tin dioxide. Although antimony of different oxidation states
have been used in the synthesis, the effect of dopant’s valence on ion exchange properties has not been investigated critically.
In our study the valence of antimony had clear effects on the metal uptake properties of Sb-doped SnO2 materials. Extremely high Tc uptake (Kd > 100 000 mL g−1) on Sb(III)-doped material was observed in conditions under which Sb(V)-doped material did not show any Tc uptake. However,
the Sb(V)-doped material showed good Ni2+ uptake properties (Kd up to 33 000 mL g−1), even at pH values below the material’s point of zero charge (pzc), while the Sb(III)-doped material showed Ni2+ uptake only at pH above its pzc. The cation uptake of Sb-doped SnO2 resembles typical weakly acidic cation exchanger character but the uptake of TcO4- does not follow a typical anion exchange pattern. Instead, we propose a sorption process related to redox reactions as the
probable Tc uptake process. 相似文献
6.
Aino J. Karhu Juho Jämsä J. Mikko Rautiainen Raija Oilunkaniemi Tristram Chivers Risto S. Laitinen 《无机化学与普通化学杂志》2017,643(7):495-500
The reaction of tBuNH2 with a mixture of SeCl2 and SeOCl2 in a 6:2:1 molar ratio produces the novel selenium‐nitrogen chain ClSeN(tBu)Se(O)Cl ( 4 ), in which the selenium atoms are in two different oxidation states, SeII and SeIV. The crystal structure of 4 is compared with that of the related SeII/SeII system ClSeN(tBu)SeCl ( 1 ) and differences are attributed to hyperconjugative effects. The energetics of the formation of 4 via two different routes are elucidated by PBE0/def2‐TZVPP calculations. 相似文献
7.
Panu T. Vesanen Jaakko O. Nieminen Koos C.J. Zevenhoven Yi-Cheng Hsu Risto J. Ilmoniemi 《Magnetic resonance imaging》2014
Electric current density can be measured noninvasively with magnetic resonance imaging (MRI). Determining all three components of the current density, however, requires physical rotation of the sample or current injection from several directions when done with conventional methods. However, the emerging technology of ultra-low-field (ULF) MRI, in which the signal encoding and acquisition is conducted at a microtesla-range magnetic field, offers new possibilities. The low applied magnetic fields can even be switched off completely within the pulse sequence, increasing the flexibility of the available sequences. In this article, we present a ULF-MRI sequence designed for obtaining all three components of a current-density pattern without the need of sample rotations. The sequence consists of three steps: prepolarization of the sample, signal encoding in the current-density-associated magnetic field without applying any MRI fields, and spatial encoding in a microtesla-range field using any standard ULF-MRI sequence. The performance of the method is evaluated by numerical simulations. The method may find applications, e.g., in noninvasive conductivity imaging of tissue. 相似文献
8.
The analytic hierarchy process with stochastic judgements 总被引:1,自引:0,他引:1
The analytic hierarchy process (AHP) is a widely-used method for multicriteria decision support based on the hierarchical decomposition of objectives, evaluation of preferences through pairwise comparisons, and a subsequent aggregation into global evaluations. The current paper integrates the AHP with stochastic multicriteria acceptability analysis (SMAA), an inverse-preference method, to allow the pairwise comparisons to be uncertain. A simulation experiment is used to assess how the consistency of judgements and the ability of the SMAA-AHP model to discern the best alternative deteriorates as uncertainty increases. Across a range of simulated problems results indicate that, according to conventional benchmarks, judgements are likely to remain consistent unless uncertainty is severe, but that the presence of uncertainty in almost any degree is sufficient to make the choice of best alternative unclear. 相似文献
9.
Multivariate Gaussian criteria in SMAA 总被引:2,自引:0,他引:2
Risto Lahdelma Simo Makkonen Pekka Salminen 《European Journal of Operational Research》2006,170(3):79-970
We consider stochastic multicriteria decision-making problems with multiple decision makers. In such problems, the uncertainty or inaccuracy of the criteria measurements and the partial or missing preference information can be represented through probability distributions. In many real-life problems the uncertainties of criteria measurements may be dependent. However, it is often difficult to quantify these dependencies. Also, most of the existing methods are unable to handle such dependency information.In this paper, we develop a method for handling dependent uncertainties in stochastic multicriteria group decision-making problems. We measure the criteria, their uncertainties and dependencies using a stochastic simulation model. The model is based on decision variables and stochastic parameters with given distributions. Based on the simulation results, we determine for the criteria measurements a joint probability distribution that quantifies the uncertainties and their dependencies. We then use the SMAA-2 stochastic multicriteria acceptability analysis method for comparing the alternatives based on the criteria distributions. We demonstrate the use of the method in the context of a strategic decision support model for a retailer operating in the liberated European electricity market. 相似文献
10.
Sari M. Kunnari Raija Oilunkaniemi Risto S. Laitinen Markku Ahlgren 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(10):o610-o611
The novel title tetraselenacalix[4]arene, C16H8S4Se4 or [(C4H2S)Se]4, has a centrosymmetric cyclic molecular structure with approximate C2h molecular symmetry. The four thienyl rings are joined together by Se bridges and exhibit a syn–syn–anti–anti arrangement around the molecule. The lattice consists of skewed stacks of molecules, with chalcogen–chalcogen close contacts binding the stacks together, forming a two‐dimensional network of molecules. 相似文献