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排序方式: 共有123条查询结果,搜索用时 78 毫秒
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THE REACTIONS OF N3P3CL6 AND RELATED COMPOUNDS WITH DIFUNCTIONAL REAGENTS. COMPARISONS AND CONTRASTS
Abdulla H. Alkubaisi W. Francis Deutsch Michael B. Hursthouse Harold G. Parkes Leylacaron S. Shaw Robert A. Shaw 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-2):229-237
Abstract The reactions of N3P3Cl6 with a variety of difunctional reagents are discussed. NMR spectroscopic and X-ray crystallographic investigations are presented. 相似文献
3.
Sahar Al Akoum-Ebrik Mohamed Ansar Rahima Mouhoub Claude Vaccher Marie-Pierre Vaccher Nathalie Flouquet 《光谱学快报》2013,46(5):925-944
The enantiomeric composition and absolute configuration of 4-Amino-3-(benzo[b]furan-2-yl)-Butanoic Acids and of 4-Amino-3-(thien-2-yl)-Butanoic Acids 1 may be accurately determined by 1H and 13C nuclear magnetic resonance analysis of the corresponding derivatives 3 prepared by reaction with chiral reagents. Correlation with HPLC is signaled. 相似文献
4.
A variant of Simulated Annealing termed Simulated Annealing with Multiplicative Weights (SAMW) has been proposed in the literature. However, convergence was dependent on a parameter β(T), which was calculated a-priori based on the total iterations T the algorithm would run for. We first show the convergence of SAMW even when a diminishing stepsize βk → 1 is used, where k is the index of iteration. Using this SAMW as a kernel, a stochastic multi-armed bandit (SMAB) algorithm called SOFTMIX can be improved to obtain the minimum-possible log regret, as compared to log2 regret of the original. Another modification of SOFTMIX is proposed which avoids the need for a parameter that is dependent on the reward distribution of the arms. Further, a variant of SOFTMIX that uses a comparison term drawn from another popular SMAB algorithm called UCB1 is then described. It is also shown why the proposed scheme is computationally more efficient over UCB1, and an alternative to this algorithm with simpler stepsizes is also proposed. Numerical simulations for all the proposed algorithms are then presented. 相似文献
5.
Yahui Yan Rahima Abdulla Xiaoyan Liu Shuping Li Haji Akber Aisa 《Journal of separation science》2022,45(13):2148-2160
6.
A micro-bimorph cantilever with self-aligned nanotips is monolithically integrated with a photonic crystal based device using optical and deep UV lithography techniques. Upon electrostatic actuation, the dielectric nanotips perturb the optical field, providing electromechano-optical modulation of light. Static tuning of the optical transmission spectra by more than 600 pm is measured with a sub-1 V drive voltage, resulting in a modulation as high as 21 dB. The observed strong electromechano-optical effect may find application in power efficient devices for optical communication networks, such as wavelength routing elements. 相似文献
7.
In this paper, we investigate the problem of robust global exponential stability analysis for a class of neutral-type neural networks. The interval time-varying delays allow for both slow and fast time-varying delays. The values of the time-varying uncertain parameters are assumed to be bounded within given compact sets. Improved global exponential stability condition is derived by employing new Lyapunov-Krasovskii functional and the integral inequality. The developed nominal and robust stability criteria is delay-dependent and characterized by linear-matrix inequalities (LMIs). The developed results are less conservative than previous published ones in the literature, which are illustrated by representative numerical examples. 相似文献
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Michael Barfield Abdulla S. Babaqi David M. Doddrell Hans P.W. Gottlieb 《Molecular physics》2013,111(1):153-164
The anisotropic hyperfine coupling constants (AHCC) from the electron spin resonance (E.S.R.) spectra of a variety of atoms in organic radicals have been calculated by means of semiempirical molecular orbital wavefunctions in the INDO approximation. Hyperfine tensors involving 1H, 13C and 19F nuclei are obtained for the ?H, ?H3, CH3?H2, (CH3)3? hydrocarbon radicals, malonic acid radical, ?H2F, ?F2H, ?F3 and CF3?H2 radicals. The calculated values are compared with available experimental, non-empirical and semiempirical values for these radicals. All integrals of the operator entering the electronic contributions have been evaluated over Slater type orbitals. The introduction of deorthogonalized wavefunctions gives generally better calculated results. In particular, the tensor components of the 19F AHCC are in good agreement with the experimental results without the necessity of readjusting the effective nuclear charges. 相似文献
10.
Summary Tetrachlorouranium complexes containing a Schiff base ligand, p-XC6H4NH=CHC6H4OH(L), derived from p-XC6H4NH2 and salicylaldehyde, have been prepared. Atris complex was obtained when X=NO2 andbis complexes for the other p-substituted Schiff bases when X=Cl, Br, OH and Me. 相似文献