全文获取类型
收费全文 | 2118篇 |
免费 | 191篇 |
国内免费 | 11篇 |
专业分类
化学 | 1911篇 |
晶体学 | 7篇 |
力学 | 19篇 |
综合类 | 2篇 |
数学 | 182篇 |
物理学 | 199篇 |
出版年
2023年 | 25篇 |
2022年 | 19篇 |
2021年 | 63篇 |
2020年 | 78篇 |
2019年 | 101篇 |
2018年 | 68篇 |
2017年 | 45篇 |
2016年 | 104篇 |
2015年 | 120篇 |
2014年 | 107篇 |
2013年 | 161篇 |
2012年 | 196篇 |
2011年 | 179篇 |
2010年 | 106篇 |
2009年 | 101篇 |
2008年 | 135篇 |
2007年 | 114篇 |
2006年 | 108篇 |
2005年 | 80篇 |
2004年 | 61篇 |
2003年 | 62篇 |
2002年 | 51篇 |
2001年 | 21篇 |
2000年 | 15篇 |
1999年 | 9篇 |
1998年 | 9篇 |
1997年 | 12篇 |
1996年 | 5篇 |
1995年 | 21篇 |
1994年 | 15篇 |
1993年 | 16篇 |
1992年 | 9篇 |
1991年 | 6篇 |
1990年 | 10篇 |
1989年 | 6篇 |
1988年 | 4篇 |
1987年 | 7篇 |
1986年 | 3篇 |
1985年 | 12篇 |
1984年 | 5篇 |
1982年 | 6篇 |
1981年 | 8篇 |
1979年 | 4篇 |
1978年 | 2篇 |
1973年 | 3篇 |
1959年 | 3篇 |
1937年 | 2篇 |
1936年 | 2篇 |
1935年 | 6篇 |
1930年 | 2篇 |
排序方式: 共有2320条查询结果,搜索用时 15 毫秒
1.
Aysun apc Mlanie M. Lorion Hui Wang Nina Simon Maria Leidenberger Mariana C. BorgesSilva Diogo R. M. Moreira Yongping Zhu Yuqing Meng Jia Yun Chen Yew Mun Lee Oliver Friedrich Barbara Kappes Jigang Wang Lutz Ackermann Svetlana B. Tsogoeva 《Angewandte Chemie (International ed. in English)》2019,58(37):13161-13161
2.
Zhihua Xie Dimitrios Pavlidis Pablo Salinas Christopher C. Pain Omar K. Matar 《国际流体数值方法杂志》2020,92(7):765-784
A novel control volume finite element method with adaptive anisotropic unstructured meshes is presented for three-dimensional three-phase flows with interfacial tension. The numerical framework consists of a mixed control volume and finite element formulation with a new P1DG-P2 elements (linear discontinuous velocity between elements and quadratic continuous pressure between elements). A “volume of fluid” type method is used for the interface capturing, which is based on compressive control volume advection and second-order finite element methods. A force-balanced continuum surface force model is employed for the interfacial tension on unstructured meshes. The interfacial tension coefficient decomposition method is also used to deal with interfacial tension pairings between different phases. Numerical examples of benchmark tests and the dynamics of three-dimensional three-phase rising bubble, and droplet impact are presented. The results are compared with the analytical solutions and previously published experimental data, demonstrating the capability of the present method. 相似文献
3.
Voskresenskaya Olga O. Skorik Nina A. 《Monatshefte für Chemie / Chemical Monthly》2020,151(4):533-542
Monatshefte für Chemie - Chemical Monthly - A comparative analysis is performed on the stability constants $${\upbeta }_{1yn}$$ and intramolecular redox decomposition rate constants $$k_{n\; =... 相似文献
4.
The Study of Nonisothermal Kinetics of Dehydration of Gibbsite in a Mixture with Zinc Oxide 下载免费PDF全文
Nonisothermal kinetics of dehydration of gibbsite in a mixture with zinc oxide has been studied by Friedman analysis (differential method) and Flynn‐Wall‐Ozawa analysis (integral method). The values of the activation energy and preexponential factor depending on the decomposition extent of gibbsite to boehmite have been determined. It has been shown that both methods give similar results. It has been established that the activation energy has a maximum value of 150–170 kJ/mol in the start stages of thermolysis (for conversion extent of less than 0.3). During further dehydration, the activation energy is reduced to 100–110 kJ/mol. It has been found that comilling of the mixture results in decreasing activation energy to 40–50 kJ/mol for a conversion extent more than 0.8. This testifies to the transition of the dehydration process out of the kinetic mode to the diffusion mode. It was explained by the accumulation of mechanical energy in the form defects of crystal lattice of gibbsite at the comilling stage. 相似文献
5.
Nanorattles or Yolk–Shell Nanoparticles—What Are They,How Are They Made,and What Are They Good For? 下载免费PDF全文
Dr. Magdalena Priebe Prof. Dr. Katharina M. Fromm 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(10):3854-3874
The development of nanotechnology has led to the design of cutting‐edge nanomaterials with increasing levels of complexity. Although “traditional” solid, uniform nanoparticles are still the most frequently reported structures, new generations of nanoparticles have been constantly emerging over the last several decades. The outcome of this nano‐art extends beyond nanomaterials with alternative compositions and/or morphologies. The current state‐of‐the‐art allows for the design of nanostructures composed of different building blocks that exhibit diverse properties. Furthermore, those properties can be a reflection of either individual features, which are characteristic of a particular building block alone, and/or synergistic effects resulting from interactions between building blocks. Therefore, the unique structures as well as the outstanding properties of nanorattles have attracted increasing attention for possible biomedical and industrial applications. Although these nanoparticles resemble core–shell particles, they have a distinctive feature, which is a presence of a void that provides a homogenous environment for the encapsulated core. In this Review, we give a comprehensive insight into the fabrication of nanorattles. A special emphasis is put on the choice of building blocks as well as the choice of preparation method, because those two aspects further influence properties and thus possible future applications, which will also be discussed. 相似文献
6.
Natalia Novikova Mikhail Kovalchuk Nina Stepina Radmir Gaynutdinov Elena Chukhrai Eleonora Yurieva 《Journal of synchrotron radiation》2015,22(4):1001-1007
The X‐ray standing‐wave method was applied to study the elemental composition and molecular organization of ordered protein films of alkaline phosphatase exposed to different xenobiotics (drug compounds, lead). Binding of metal ions from triply distilled water to protein molecules has been experimentally observed. Definite differences in the arrangement of impurity metal ions in the films have been established. The considerable enhancement of protein–metal interactions is attributed to partial rearrangement of the protein native structure, induced by xenobiotics. 相似文献
7.
8.
Dr. Joohyun Lim Ghoncheh Kasiri Dr. Rajib Sahu Kevin Schweinar Dr. Katharina Hengge Prof. Dr. Dierk Raabe Prof. Dr. Fabio La Mantia Prof. Dr. Christina Scheu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(22):4917-4922
The structural changes of copper hexacyanoferrate (CuHCF), a Prussian blue analogue, which occur when used as a cathode in an aqueous Zn-ion battery, are investigated using electron microscopy techniques. The evolution of ZnxCu1−xHCF phases possessing wire and cubic morphologies from initial CuHCF nanoparticles are monitored after hundreds of cycles. Irreversible introduction of Zn ions to CuHCF is revealed locally using scanning transmission electron microscopy. A substitution mechanism is proposed to explain the increasing Zn content within the cathode material while simultaneously the Cu content is lowered during Zn-ion battery cycling. The present study demonstrates that the irreversible introduction of Zn ions is responsible for the decreasing Zn ion capacity of the CuHCF cathode in high electrolyte concentration. 相似文献
9.
10.
Alexander A. Larin Dr. Nikita V. Muravyev Prof. Dr. Alla N. Pivkina Dr. Kyrill Yu. Suponitsky Dr. Ivan V. Ananyev Dr. Dmitry V. Khakimov Dr. Leonid L. Fershtat Prof. Dr. Nina N. Makhova 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(16):4225-4233
A series of highly energetic organic salts comprising a tetrazolylfuroxan anion, explosophoric azido or azo functionalities, and nitrogen-rich cations were synthesized by simple, efficient, and scalable chemical routes. These energetic materials were fully characterized by IR and multinuclear NMR (1H, 13C, 14N, 15N) spectroscopy, elemental analysis, and differential scanning calorimetry (DSC). Additionally, the structure of an energetic salt consisting of an azidotetrazolylfuroxan anion and a 3,6,7-triamino-7H-[1,2,4]triazolo[4,3-b][1,2,4]triazolium cation was confirmed by single-crystal X-ray diffraction. The synthesized compounds exhibit good experimental densities (1.57–1.71 g cm−3), very high enthalpies of formation (818–1363 kJ mol−1), and, as a result, excellent detonation performance (detonation velocities 7.54–8.26 kms−1 and detonation pressures 23.4–29.3 GPa). Most of the synthesized energetic salts have moderate sensitivity toward impact and friction, which makes them promising candidates for a variety of energetic applications. At the same time, three compounds have impact sensitivity on the primary explosives level (1.5–2.7 J). These results along with high detonation parameters and high nitrogen contents (66.0–70.2 %) indicate that these three compounds may serve as potential environmentally friendly alternatives to lead-based primary explosives. 相似文献