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Direct catalytic oxidative conversion of light alkanes to alcohols using molecular oxygen as an oxidant is a challenging and important synthetical goal, which might be met by transition metal porphyrin complexes that are capable of forming active metal oxo intermediates via direct reaction with O2 in the presence of a co-reductant[1]. It was found that iron complexes of halogenated porphyrins were remarkably active catalysts for the hydroxylation of light alkanes by O2 without added co-reductants in an organic solvent such as benzene 相似文献
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R. R. Akhmetvaleev G. M. Baibulatova I. F. Nuriev O. V. Shitikova M. S. Miftakhov 《Russian Journal of Organic Chemistry》2001,37(8):1083-1087
Analog of chlorvulone II containing an extra chlorine atom at C11 was synthesized starting with 1,4-dioxa-6,7-dichlorospiro[4.4]non-6-ene. 相似文献
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Back Cover: Synthesis of Tetrazino‐tetrazine 1,3,6,8‐Tetraoxide (TTTO) (Angew. Chem. Int. Ed. 38/2016) 
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下载免费PDF全文 Dr. Michael S. Klenov Alexey A. Guskov Dr. Oleg V. Anikin Prof. Dr. Aleksandr M. Churakov Dr. Yurii A. Strelenko Dr. Ivan V. Fedyanin Dr. Konstantin A. Lyssenko Prof. Dr. Vladimir A. Tartakovsky 《Angewandte Chemie (International ed. in English)》2016,55(38):11688-11688
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Cover Picture: Two‐Dimensional Ketone‐Driven Metal–Organic Coordination on Cu(111) (Chem. Eur. J. 24/2016) 下载免费PDF全文
下载免费PDF全文 Dr. Ada Della Pia Dr. Massimo Riello James Lawrence Dr. Daphne Stassen Prof. Tim S. Jones Prof. Davide Bonifazi Prof. Alessandro De Vita Prof. Giovanni Costantini 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(24):7989-7989