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排序方式: 共有706条查询结果,搜索用时 31 毫秒
1.
Nayak Debasis Dora J. K. Ghosh Sudipto Adyam Venimadhav 《Journal of Solid State Electrochemistry》2022,26(5):1231-1239
Journal of Solid State Electrochemistry - Sodium-ion batteries have emerged as an exciting alternative to commercially dominant lithium-ion batteries for electric vehicles and other applications.... 相似文献
2.
Sreenivasa Nayak Meghashyama P. Bhat A.C. Udayashankar T.R. Lakshmeesha Nagaraja Geetha Sudisha Jogaiah 《应用有机金属化学》2020,34(4):e5567
Dillenia indica L. is a traditional medicinal plant well known for its ability to cure various human diseases. In the current study, silver nanoparticles have been synthesized by simple and eco-friendly method using Dillenia indica extract. The green synthesized nanoparticles were characterized by Fourier transform infrared (FTIR), UV–visible spectroscopy, Atomic force microscopy (AFM), High-resolution transmission electron microscopy (HR-TEM), Zeta Potential and Size Distribution. UV–visible and FTIR spectra, AFM, HR-TEM and Zeta Potential readings and size distribution conformed that the synthesized silver particles were in the size of nano. The green synthesized silver nanoparticles were subjected for antibacterial activity against Gram-positive bacteria Enterococcus faecalis and Gram-negative bacteria Escherichia coli by agar well diffusion method. The synthesized AgNPs exhibited significant inhibition of 27 and 16 mm against the test bacteria at 0.25 mg/ml. Further the antibacterial activity was confirmed by live and dead cell assay by fluorescence microscopy and morphological changes of bacteria were studied by Scanning electron microscope (SEM). The study recommends that the synthesized silver nanoparticles using Dillenia indica extract have potential application in inhibition of bacteria owing to their potent antibacterial activity. 相似文献
3.
Mithilesh Kumar Nayak Jessica Stubbe Dr. Nicolás I. Neuman Dr. Ramakirushnan Suriya Narayanan Sandipan Maji Prof. Dr. Carola Schulzke Prof. Vadapalli Chandrasekhar Prof. Dr. Biprajit Sarkar Dr. Anukul Jana 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(19):4425-4431
This work presents a stepwise reversible two-electron transfer induced hydrogen shift leading to the conversion of a bis-pyrrolinium cation to an E-diaminoalkene and vice versa. Remarkably, the forward and the reverse reaction, which are both reversible, follow two completely different reaction pathways. Establishing such unprecedented property in this type of processes was possible by developing a novel synthetic route towards the starting dication. All intermediates involved in both the forward and the backward reactions were comprehensively characterized by a combination of spectroscopic, crystallographic, electrochemical, spectroelectrochemical, and theoretical methods. The presented synthetic route opens up new possibilities for the generation of multi-pyrrolinium cation scaffold-based organic redox systems, which constitute decidedly sought-after molecules in contemporary chemistry. 相似文献
4.
Suchhanda S. Swain Lakshmi Unnikrishnan Smita Mohanty Sanjay K. Nayak 《Surface and interface analysis : SIA》2023,55(1):10-25
Carbonaceous nanomaterials and their derivatives have been inspired tremendous enthusiasm in the scientific community. They have been excogitated as the encouraging attributes and the qualified dispersed phase to develop multi-functional composites. Particularly, graphene and carbon nanotube (anisotropic fillers) have gained substantial research interest owing to their promising characteristics. This highlights an innovative technique to synthesize hybridized nanotube and nanosheet. Initially, parent materials have been synthesized: The pristine CNT has been modified by acid mixture solution, and reduced graphene oxide has been prepared by chemical reduction method. Henceforth, the self-assembly in situ sol–gel technique has been endorsed here. The synthesized nanohybrids have been characterized by different spectroscopic techniques: FTIR, Raman, UV, and XPS to confirm the attachment of multifunctionalities; meanwhile, the composition and stability have been investigated from XRD and TGA plots. The magnitude of surface charge and particle size distribution have been evaluated for the parent and hybridized products; further, morphology of all the samples has been authenticated from FESEM and TEM. 相似文献
5.
Anna Chandrasekar Murali Prakash Nayak Shashwat Nayak Sabyasachi Das Dr. Satyaprasad P. Senanayak Prof. Krishnan Venkatasubbaiah 《Angewandte Chemie (International ed. in English)》2023,62(11):e202216871
Development of new n-type semiconductors with tunable band gap and dielectric constant has significant implication in dissociating bound charge carrier relevant for demonstrating high performance optoelectronic devices. Boron-β-thioketonates (MTDKB), analogues to boron-β-diketonates containing a sulfur atom in the framework of β-diketones were synthesized. Bulk transport measurement exhibited an outstanding bulk electron mobility of ≈0.003 cm2 V−1 s−1, which is among the best values reported till date in these class of semiconducting materials and correspondingly a single junction photo responsivity of upto 6 mA W−1 was obtained. This new family of O,S-chelated boron compounds exhibited luminescence in the far red/near-infrared region. The remarkable red shift of 89 nm (fluorescence) observed for 4 a in comparison with analogues boron-β-diketonate signifies the importance of sulfur in these molecules. MTDKBs with amine functionality have also been investigated as an ON/OFF fluorescent sensor. 相似文献
6.
Dr. Anoop Kumar Kushwaha Sushri Soumya Jena Dr. Mihir Ranjan Sahoo Dr. Debashish Das Prof. Saroj Kumar Nayak 《Chemphyschem》2023,24(18):e202300032
High-voltage alkali metal-ion batteries (AMIBs) require a non-hazardous, low-cost, and highly stable electrolyte with a large operating potential and rapid ion conductivity. Here, we have reported a halogen-free high-voltage electrolyte based on SiB11(BO)12−. Because of the weak π-orbital interaction of −BO as well as the mixed covalent and ionic interaction between SiB11-cage and −BO ligand, SiB11(BO)12− has colossal stability. SiB11(BO)12− possesses extremely high vertical detachment energy (9.95 eV), anodic voltage limit (∼10.05 V), and electrochemical stability window (∼9.95 V). Furthermore, SiB11(BO)12− is thermodynamically stable at high temperatures, and its large size allows for faster cation movement. The alkali salts MSiB11(BO)12 (M=Li, Na, and K) are easily dissociated into ionic components. Electrolytes based on SiB11(BO)12− greatly outperform commercial electrolytes. In short, SiB11(BO)12−-based compound is demonstrated to be a high-voltage electrolyte for AMIBs. 相似文献
7.
Vignesh Nayak Mannekote Shivanna Jyothi Prof. R Geetha Balakrishna Dr. Mahesh Padaki Prof. Ahmad Fauzi Ismail 《ChemistryOpen》2015,4(3):278-287
Herein we present a new approach for the complete removal of CrVI species, through reduction of CrVI to CrIII, followed by adsorption of CrIII. Reduction of chromium from water is an important challenge, as CrIV is one of the most toxic substances emitted from industrial processes. Chitosan (CS) thin films were developed on plain polysulfone (PSf) and PSf/TiO2 membrane substrates by a temperature-induced technique using polyvinyl alcohol as a binder. Structure property elucidation was carried out by X-ray diffraction, microscopy, spectroscopy, contact angle measurement, and water uptake studies. The increase in hydrophilicity followed the order: PSf < PSf/TiO2 < PSf/TiO2/CS membranes. Use of this thin-film composite membrane for chromium removal was investigated with regards to the effects of light and pH. The observations reveal 100 % reduction of CrVI to CrIII through electrons and protons donated from OH and NH2 groups of the CS layer; the reduced CrIII species are adsorbed onto the CS layer via complexation to give chromium-free water. 相似文献
8.
S. N. V. M. S. Gupta A. K. Nayak U. B. Misra Balaji Rao Yarasi C. Phani Babu G. Kalyanakrishnan 《Journal of Radioanalytical and Nuclear Chemistry》2017,313(3):571-579
The present paper describes a new analytical method developed for direct determination of boron in steels using radio frequency glow discharge optical emission spectrometer. “Single parameter alternative method” technique has been used to optimize the various experimental conditions of glow discharge plasma such as forward power, gas pressure inside plasma chamber, pre-integration time, and integration time. Different emission lines for boron were studied and inter element interference effect is also discussed in the paper. A complete statistical analysis has been done to validate the developed method. A RSD of less than ±5% is achieved for boron in the range of 0.0010–0.020% in Steels using this method. 相似文献
9.
A modular approach to 5-acylated naphtho[2,1-b]benzofurans was developed where Sonogashira cross-coupling and intramolecular alkyne carbonyl metathesis were sequentially employed to build the aromatic benzene C ring of naphtho[2,1-b]benzofuran with an acyl group at the C5 position. 相似文献
10.
Robert D. Bongard Michael Lepley Khushabu Thakur Marat R. Talipov Jaladhi Nayak Rachel A. Jones Lipinski Chris Bohl Noreena Sweeney Ramani Ramchandran Rajendra Rathore Daniel S. Sem 《BMC biochemistry》2017,18(1):10