CuI-catalyzed Coupling Reactions of Aryl Iodides with Amides Using L-Proline and KF/Al2O3

An efficient experimentally simple and inexpensive catalyst system for the selective amidation of aryl iodides using 15 mol% of CuI as catalyst, 15 mol% of L-proline as ligand and KF/Al2O3 as a base in toluene is described.     

二氧化钛纳米粒子催化合成Hantzsch酯和多氢喹啉衍生物(英文)

1,4-Dihydropyridine and polyhydroquinoline derivatives have been prepared efficiently in a one-pot synthesis via Hantzsch condensation using nanosized titanium dioxide as a heterogeneous catalyst.The present methodology offers several advantages such as excellent yields,short reaction times (30-120 min),environmentally benign,and mild reaction conditions.The catalyst can be readily separated from the reaction products and recovered in excellent purity for direct reuse.     

以有序介孔二氧化硅纳米粒子为可再生催化剂多组分一锅法合成4H-氧萘衍生物(英文)

A simple,efficient and environmentally benign protocol for the synthesis of 4H-chromene derivatives was developed using bio-compatible,neutral,and recoverable mesoporous silica nanoparticles as a catalyst.The 4H-chromene derivatives were obtained in excellent yields by three component reaction of an aldehyde or isatin,malononitrile,and cyclic 1,3-diketones in ethanol at 60℃.     

一个简单、环境友好的硅胶固载硫酸催化Biginelli反应体系(英文)

A protocol for the synthesis of 3,4-dihydropyrimidin-2(1H)-ones and-thiones was developed by means of a three-component condensation of an aldehyde,a β-dicarbonyl compound,and urea or thiourea in acetic acid catalyzed by silica-bonded S-sulfonic acid.Compared to the classical Biginelli reaction conditions,this new protocol has the advantages of consistently excellent yields and short reaction times.After the reaction,the catalyst could be recovered easily and reused with little change in its activity.     

H3PW12O40催化水相介质中苯并恶嗪和喹唑啉合成（英文）简

A heteropolyacid efficiently catalyzed the cyclocondensation reaction of 2-aminobenzamide and salicylamide with aldehydes and ketones to afford good yields of benzoxazine and quinazoline ring systems in an aqueous medium. The method gives clean reactions, has simple workup procedure, and uses environment friendly conditions.     

H_3PW_(12)O_(40)催化水相介质中苯并恶嗪和喹唑啉合成（英文）

A heteropolyacid efficiently catalyzed the cyclocondensation reaction of 2‐aminobenzamide and salicylamide with aldehydes and ketones to afford good yields of benzoxazine and quinazoline ring systems in an aqueous medium. The method gives clean reactions, has simple workup procedure, and uses environment friendly conditions.