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排序方式: 共有217条查询结果,搜索用时 31 毫秒
1.
Kota Tanaka Saki Okamura Ken Shibata Naoki Ikenaga Nobuyuki Tanaka Kazumi Hakamada Jun Miyake 《Research on Chemical Intermediates》2016,42(11):7723-7730
Renewable energy is regarded as a clean energy source but has some problems, one of which is intermittency. To reduce this, the time-delay of hydrogen production by photosynthetic bacteria can be effective. In this study, we qualitatively evaluated the time-delay of hydrogen production by photosynthetic bacteria under various irradiation conditions, and we also quantitatively evaluated it by fitting the experimental data and the hydrogen production model with a genetic algorithm. As a result of model fitting, we found that the relationship between the lengths of the optimized time-delay of hydrogen production by photosynthetic bacteria and the amount of light irradiation is linear. And we also found that the time-delay of hydrogen production by photosynthetic bacteria had an upper limit under low light intensity. We have suggested the existence of an energy store mechanism in photosynthetic bacteria. 相似文献
2.
Dr. Bozheng Sun Dr. Meagan S. Oakley Dr. Kota Yoshida Yanwen Yang Prof. Matteo Tommasini Dr. Chiara Zanchi Dr. Andrea Lucotti Dr. Michael J. Ferguson Dr. Frank Hampel Prof. Mariusz Klobukowski Prof. Rik R. Tykwinski 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(38):e202200616
Cyclic tetraaryl[5]cumulenes ( 1 a–f ) have been synthesized and studied as a function of increasing ring strain. The magnitude of ring strain is approximated by the extent of bending of the cumulenic core as assessed by a combination of X-ray crystallographic analysis and DFT calculations. Trends are observed in 13C NMR, UV-vis, and Raman spectra associated with ring strain, but the effects are small. In particular, the experimental HOMO-LUMO gap is not appreciably affected by bending of the [5]cumulene framework from ca. 174° (λmax=504 nm) in 1 a to ca. 178° (λmax=494 nm) in 1 f . 相似文献
3.
Cover Picture: Electron–Proton Decoupling in Excited‐State Hydrogen Atom Transfer in the Gas Phase (Angew. Chem. Int. Ed. 50/2015) 下载免费PDF全文
4.
The aim of this paper is to find the global solutions of uncertain optimization problems having a quadratic objective function and quadratic inequality constraints. The bounded epistemic uncertainties in the constraint coefficients are represented using either universal or existential quantified parameters and interval parameter domains. This approach allows to model non-controlled uncertainties by using universally quantified parameters and controlled uncertainties by using existentially quantified ones. While existentially quantified parameters could be equivalently considered as additional variables, keeping them as parameters allows maintaining the quadratic problem structure, which is essential for the proposed algorithm. The branch and bound algorithm presented in the paper handles both universally and existentially quantified parameters in a homogeneous way, without branching on their domains, and uses some dedicated numerical constraint programming techniques for finding a robust, global solution. Several examples clarify the theoretical parts and the tests demonstrate the usefulness of the proposed method. 相似文献
5.
Noriki Kutsumura Kota Shibuya Hitoshi Yamaguchi Takao Saito 《Tetrahedron letters》2017,58(43):4099-4102
Regioselective elimination of a vicinal bis-triflate having an adjacent ether oxygen functional group has been developed. Considered in the context of our studies of the regioselective elimination of vicinal dibromide, the key to the mechanism involves the electron-withdrawing inductive effect of the neighboring oxygen functional group. Aliphatic vinyl triflate was shown to be effective in Suzuki–Miyaura cross coupling compared with corresponding aliphatic vinyl bromide. 相似文献
6.
Kanji Shibagaki Kota Kawano Atsuto Mori 《Applied Physics A: Materials Science & Processing》2013,110(4):805-808
Shape-memory alloys are crucial in various industrial fields. However, a high-quality film synthesis method has not been established yet. Here we examine optimum conditions for synthesis of thin films by pulsed laser deposition of Ti–Ni alloy target in vacuum. We investigated surface morphologies and chemical compositions of the films which were obtained under various conditions. We found that the suitable Ti/Ni ratio was obtained by adjusting the distance between the target and the substrate in vacuum. In parallel, we analyzed plasma plume by optical emission spectroscopy and time-of-flight mass spectrometry. We discuss the basic behavior of ablated particles in vacuum. 相似文献
7.
Nagi Reddy Vanga Anudeep Kota Ramakrishna Sistla Mallavadhani Uppuluri 《Molecular diversity》2017,21(2):273-282
8.
9.
Minami Odagi Kota Furukori Tatsuya Watanabe Prof. Dr. Kazuo Nagasawa 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(49):16740-16745
Highly enantioselective catalytic oxidation of 1‐tetralone‐derived β‐keto esters was achieved by using a guanidine–urea bifunctional organocatalyst in the presence of cumene hydroperoxide (CHP), a safe, commercially available oxidant. The α‐hydroxylation products were obtained in 99 % yield with up to 95 % enantiomeric excess (ee). The present oxidation was successfully applied to synthesize a key intermediate of the anti‐cancer agent daunorubicin ( 2 ). 相似文献
10.
Embedded random matrix ensembles are generic models for describing statistical properties of finite isolated interacting quantum many-particle systems. For the simplest spinless fermion (or boson) systems, with say m fermions (or bosons) in N single particle states and interacting via k-body interactions, we have EGUE(k) [embedded GUE of k-body interactions] with GUE embedding and the embedding algebra is U(N). A finite quantum system, induced by a transition operator, makes transitions from its states to the states of the same system or to those of another system. Examples are electromagnetic transitions (then the initial and final systems are same), nuclear beta and double beta decay (then the initial and final systems are different), particle addition to or removal from a given system and so on. Towards developing a complete statistical theory for transition strength densities (transition strengths multiplied by the density of states at the initial and final energies), we have derived formulas for the lower order bivariate moments of the strength densities generated by a variety of transition operators. Firstly, for a spinless fermion system, using EGUE(k) representation for a Hamiltonian that is k-body and an independent EGUE(t) representation for a transition operator that is t-body and employing the embedding U(N) algebra, finite-N formulas for moments up to order four are derived, for the first time, for the transition strength densities. Secondly, formulas for the moments up to order four are also derived for systems with two types of spinless fermions and a transition operator similar to beta decay and neutrinoless beta decay operators. In addition, moments formulas are also derived for a transition operator that removes k0 number of particles from a system of m spinless fermions. In the dilute limit, these formulas are shown to reduce to those for the EGOE version derived using the asymptotic limit theory of Mon and French (1975). Numerical results obtained using the exact formulas for two-body (k=2) Hamiltonians (in some examples for k=3 and 4) and the asymptotic formulas clearly establish that in general the smoothed (with respect to energy) form of the bivariate transition strength densities take bivariate Gaussian form for isolated finite quantum systems. Extensions of these results to bosonic systems and EGUE ensembles with further symmetries are discussed. 相似文献