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1.
Giridharan Loganathan Suresh Krishnaraj Jayaprakash Muthumanickam Ravichandran K 《Journal of Chemometrics》2015,29(1):59-68
In order to bring out the nature of the factors influencing lake water composition, multivariate statistical analysis and trend analysis were performed based on the hydrochemical data of the study area, namely, South Chennai. Change in land use pattern and settlements along the banks of the lakes alters the quality and quantity of the surface water. In the present study, the R‐mode factor analysis and cluster analysis were applied to the geochemical parameters of the water to identify the factors affecting the chemical composition of the lake water. Dendograms of both the seasons give three major clusters, reflecting the groups of unpolluted to moderately polluted, polluted, and heavily polluted stations. The movement of stations from one cluster to another clearly brings out the seasonal variation in the chemical composition of the lake water. The complex hydrochemical data of the surface water were interpreted by condensing them into three major factors. Factor score analysis was used successfully to delineate the stations under study and the role of the contributing factors, and the nature of factors responsible for the variation in chemical composition of the water has been clearly brought out. Results of trend analysis using ArcGIS clearly indicate that the trend in water quality is deteriorating at a faster rate in the eastern part of the study area. It is understood that although natural shifts probably can account for some of the variation, it is most likely that human activities play a major role in affecting the water quality on a regional scale. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
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K. R. Jayaprakash Yuli Starosvetsky Alexander F. Vakakis Maxime Peeters Gaetan Kerschen 《Nonlinear dynamics》2011,63(3):359-385
We study standing waves (nonlinear normal modes—NNMs) and band zones in finite granular chains composed of spherical granular
beads in Hertzian contact, with fixed boundary conditions. Although these are homogeneous dynamical systems in the notation
of Rosenberg (Adv. Appl. Mech. 9:155–242, 1966), we show that the discontinuous nature of the dynamics leads to interesting effects such as separation between beads, NNMs
that appear as traveling waves (these are characterized as pseudo-waves), and localization phenomena. In the limit of infinite
extent, we study band zones, i.e., pass and stop bands in the frequency–energy plane of these dynamical systems, and classify
the essentially nonlinear responses that occur in these bands. Moreover, we show how the topologies of these bands significantly
affect the forced dynamics of these granular media subject to narrowband excitations. This work provides a classification
of the coherent (regular) intrinsic dynamics of one-dimensional homogeneous granular chains with no pre-compression, and provides
a rigorous theoretical foundation for further systematic study of the dynamics of granular systems, e.g., the effects of disorders
or clearances, discrete breathers, nonlinear localized modes, and high-frequency scattering by local disorders. Moreover,
it contributes toward the design of granular media as shock protectors, and in the passive mitigation of transmission of unwanted
disturbances. 相似文献
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P. Sangeetha P. Jayaprakash M. Nageshwari M. Peer Mohamed G. Vinitha M. Lydia Caroline 《Chinese Journal of Physics (Taipei)》2018,56(2):721-739
We synthesized noncentrosymmetric single crystals of L-phenylalanine nitrate (LPN) and tris L-(phenylalanine) L-phenylalaninium nitrate (TPLPN) by slow solvent evaporation technique. Both crystallized in monoclinic system with different acentric space groups namely P21 (LPN) and C2 (TPLPN) respectively. The IR and Raman spectral investigation was done for LPN and TPLPN and discussed. The UV-vis-studies accomplished the excitation wavelength of the grown crystals suitable to exhibit second harmonic generation signal. From the absorption data, remarkable optical properties such as direct band gap energy, Urbach energy, extinction coefficient were evaluated. The mechanical strength of the grown crystal was examined by Vickers micro hardness test. The temperature of decomposition was confirmed by TG/DSC analysis. Fluorescence emission spectrum of LPN and TPLPN were recorded and lifetime was also studied. The dielectric constant and dielectric loss of LPN and TPLPN has been determined as a function of frequency and temperature. Also the surface topologies of the crystallized salts were assessed by SEM studies. The third-order nonlinearities of LPN and TPLPN were determined by Z-scan technique with Nd: YAG at 532?nm and thereby from closed and open Z-scan data, third-order susceptibilities were calculated to be χ(3)?=?8.826?×?10?6 esu for LPN and χ(3)?=?2.552?×?10?7 esu for TPLPN. 相似文献
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Hun-Gi Jung Sung Woo Oh Jin Ce N. Jayaprakash Yang-Kook Sun 《Electrochemistry communications》2009,11(4):756-759
Anatase phase mesoporous TiO2 with I41/amd space group was synthesized via the urea assisted hydrothermal method. The existence of mono phasic TiO2 sub-microspheres of uniform particle size (ca. 400 nm) encompassing an average crystallite size of 14 nm was demonstrated using the XRD, FE-SEM and TEM analysis. Surface area of ca. 116.49 m2/g along with a pore size of 7 nm was calculated using the BET and adsorption isotherm measurements which authenticated the mesoporous nature of the synthesized material. Suitable calcination temperature for the better electrochemical property was established via the optimization process. Accordingly, the mesoporous TiO2 calcined at 400 °C displayed improved cycleability with excellent rate capability ever reported, even at 20 C-rate of discharge. The reason for the superior rate capability is corroborated to the highly mesoporous nature of the TiO2 sub-microspheres that has imparted desirable surface area apposite for enhanced ionic and electronic diffusion. 相似文献
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Synthesis of Diverse Oxa‐Carbocycle‐Annulated Flavones Using the Combined Claisen Rearrangement and Ring‐Closing Metathesis 下载免费PDF全文
A simple and efficient route for the synthesis of oxepine‐, oxocine‐, oxepinone‐, and dioxocine‐angularly annulated flavone skeletons has been developed. The combined Claisen rearrangement and the ring‐closing metathesis are used as key steps for the construction of C7/C8–C6–C6 tricyclic core structures. 相似文献
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Synthesis and Characterization of the Rubidium Thiophosphate Rb6(PS5)(P2S10) and the Rubidium Silver Thiophosphates Rb2AgPS4, RbAg5(PS4)2 and Rb3Ag9(PS4)4 下载免费PDF全文
Fatimah Alahmari Bambar Davaasuren Jayaprakash Khanderi Alexander Rothenberger 《无机化学与普通化学杂志》2016,642(5):361-367
The metal thiophosphates Rb2AgPS4 ( 2 ), RbAg5(PS4)2 ( 3 ), and Rb3Ag9(PS4)4 ( 4 ) were synthesized by stoichiometric reactions, whereas Rb6(PS5)(P2S10) ( 1 ) was prepared with excess amount of sulfur. The compounds crystallize as follows: 1 monoclinic, P21/c (no. 14), a = 17.0123(7) Å, b = 6.9102(2) Å, c = 23.179(1) Å, β = 94.399(4)°; 2 triclinic, P$\bar{1}$ (no. 2), a = 6.600(1) Å, b = 6.856(1) Å, c = 10.943(3) Å, α = 95.150(2)°, β = 107.338(2)°, γ = 111.383(2)°; 3 orthorhombic, Pbca (no. 61), a = 12.607(1) Å, b = 12.612(1) Å, c = 17.759(2) Å; 4 orthorhombic, Pbcm (no. 57), a = 6.3481(2) Å, b = 12.5782(4) Å, c = 35.975(1) Å. The crystal structures contain discrete units, chains, and 3D polyanionic frameworks composed of PS4 tetrahedral units arranged and connected in different manner. Compounds 1 – 3 melt congruently, whereas incongruent melting behavior was observed for compound 4 . 1 – 4 are semiconductors with bandgaps between 2.3 and 2.6 eV and thermally stable up to 450 °C in an inert atmosphere. 相似文献
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