The Destruction of Carbon Tetrachloride Dissolved in Water in a Dielectric Barrier Discharge in Oxygen

The kinetics of decomposition of tetrachloromethane (TCM) in its aqueous solutions and the kinetics of decomposition products formation was investigated under the action of DBD at atmospheric pressure in oxygen in a falling-flow reactor. The range of initial concentrations of TCM was 25–325 μmol/l, the discharge power—2–11 W and O₂ flow rates—1–3 cm³/s. It is shown that the kinetics of the TCM decomposition can be described by the equation of pseudo-first kinetic order. The rate constant depended weakly on the discharge parameters and was?~?5 s^?1. The energy efficiency of the decomposition, depending on the parameters, was 0.1–1.3 molecules per 100 eV. When the residence time of the solution with the discharge zone is more than 1 s, it is possible to achieve almost 100% degree of TCM decomposition. It is shown that the main products of the TCM decomposition in the liquid phase are aldehydes and Cl^? ions, and in the gas phase—the molecules CO and CO₂. The results for energy efficiency are compared with the results obtained in other AOP’s processes (Fenton process, photocatalytic process, the radiation process by the action of high-energy electron flux). It is shown that the action of the DBD is more effective than the action of the above processes.

     

Impacts of fast meteoroids and the separation of dust particles from the surface of the Moon

The possibility of the separation of dust particles owing to impacts of micrometeoroids on the surface of the Moon has been discussed. It has been shown that this effect is significant and should be taken into account when determining the number of particles rising over the surface of the Moon at the formation of a plasma–dust system. The average number of regolith particles leaving the surface of the Moon owing to the impacts of fast meteoroids has been determined for various altitudes over the Moon. The size distribution function of particles leaving the surface of the Moon because of impacts of meteoroids has been determined. It has been shown that impacts of meteoroids constitute an important source of dust microparticles in the plasma–dust system over the surface of the Moon.     

Dusty plasma system in the surface layer of the illuminated part of the moon

The dusty plasma system in the surface layer of the illuminated part of the Moon has been considered. The maximum height of the dust rise has been determined. It has been shown that a dead zone, where dust particles cannot rise over the surface of the Moon, is absent near a lunar latitude of 80°. The size and height distributions of dust have been determined.     

Water Purification to Remove Naphthalene by Treatment with Dielectric-Barrier Discharge in Oxygen

High Energy Chemistry - The destruction of naphthalene (NAP), one of polycyclic aromatic hydrocarbons, in its aqueous solution by treatment with atmospheric-pressure dielectric-barrier discharge in...     

Destruction of 2,4-Dichlorophenol in Water Solution Using a Combined Process of Sorption and Plasma Exposure to DBD

The results of studies of the decomposition of 2,4-dichlorophenol (2,4-DCP) in its aqueous solution under the action of atmospheric pressure DBD in an oxygen flow are presented. A new reactor design was used in which the discharge zone was filled with a sorbent (diatomite). It was found that the kinetics of decomposition obeys a first-order kinetic equation for the concentration of 2,4-DCP. The presence of an adsorbent significantly improves the parameters of the decomposition process. Decomposition rates, rate constants and energy efficiency are doubled. So, at a specific discharge power of 1.8 W/cm³ in the presence of a sorbent, the rate constant was ~1 s^?1, and without it, ~0.5 s^?1. The energy efficiency was 0.031 and 0.016 molecules per 100 eV, respectively. The parameters of the treated solution are improved in terms of its potential toxicity. The concentrations of the main decomposition products (aldehydes, carboxylic acids) in the presence of a sorbent are significantly less than without it. This is due to an increase in the rate of conversion of these products into carbon dioxide molecules. It was also shown that the decomposition of one 2,4-DCP molecule leads to the formation of two chloride ions in solution, and the ozone formed in the discharge does not significantly affect the destruction process.

     

On the distributions of photoelectrons over the illuminated part of the moon

The existing view of the photoemission properties of lunar regolith does not provide the unambiguous treatment of the parameters and distributions of photoelectrons over the illuminated part of the Moon. This is indicated by the present calculations of the density, temperature, and distribution function of photoelectrons. It has been demonstrated that the quantum yield of lunar regolith is the main parameter determining the generation of photoelectrons near the surface of the Moon. At present, this parameter is determined with significant uncertainty. The measurement of the quantum yield of regolith directly on the surface of the Moon has been proposed as a variant of the solution of the indicated problem. Such measurements can be performed in the framework of future lunar missions.