全文获取类型
收费全文 | 1349篇 |
免费 | 52篇 |
国内免费 | 1篇 |
专业分类
化学 | 790篇 |
晶体学 | 6篇 |
力学 | 7篇 |
综合类 | 1篇 |
数学 | 373篇 |
物理学 | 225篇 |
出版年
2022年 | 8篇 |
2021年 | 26篇 |
2020年 | 14篇 |
2019年 | 22篇 |
2018年 | 23篇 |
2017年 | 49篇 |
2016年 | 58篇 |
2015年 | 44篇 |
2014年 | 53篇 |
2013年 | 98篇 |
2012年 | 54篇 |
2011年 | 45篇 |
2010年 | 54篇 |
2009年 | 55篇 |
2008年 | 49篇 |
2007年 | 49篇 |
2006年 | 40篇 |
2005年 | 63篇 |
2004年 | 63篇 |
2003年 | 58篇 |
2002年 | 23篇 |
2001年 | 31篇 |
2000年 | 25篇 |
1999年 | 13篇 |
1998年 | 16篇 |
1997年 | 13篇 |
1996年 | 20篇 |
1995年 | 24篇 |
1994年 | 14篇 |
1993年 | 10篇 |
1992年 | 8篇 |
1991年 | 12篇 |
1990年 | 10篇 |
1989年 | 13篇 |
1988年 | 10篇 |
1987年 | 17篇 |
1986年 | 7篇 |
1985年 | 19篇 |
1984年 | 12篇 |
1983年 | 14篇 |
1982年 | 11篇 |
1981年 | 20篇 |
1980年 | 8篇 |
1979年 | 11篇 |
1978年 | 15篇 |
1975年 | 6篇 |
1974年 | 6篇 |
1973年 | 13篇 |
1972年 | 7篇 |
1966年 | 6篇 |
排序方式: 共有1402条查询结果,搜索用时 922 毫秒
1.
Dapeng Liu Binod R. Giri Milán Szőri Béla Viskolcz Et-touhami Es-sebbar Aamir Farooq 《Proceedings of the Combustion Institute》2021,38(1):967-976
NOx mitigation is a central focus of combustion technologies with increasingly stringent emission regulations. NOx can also enhance the autoignition of hydrocarbon fuels and can promote soot oxidation. The reaction between allyl radical (C3H5) and NOx plays an important role in the oxidation kinetics of propene. In this work, we measured the absolute rate coefficients for the redox reaction between C3H5 and NOx over the temperature range of 1000–1252 K and pressure range of 1.5–5.0 bar using a shock tube and UV laser absorption technique. We produced C3H5 by shock heating of C3H5I behind reflected shock waves. Using a Ti:Sapphire laser system with frequency quadrupling, we monitored the kinetics of C3H5 at 220 nm. Unlike low-temperature chemistry, the two target reactions, C3H5 + NO → products (R1) and C3H5 + NO2 → products (R2), exhibited a strong positive temperature dependence for this radical-radical type reaction. However, these reactions did not show any pressure dependence over the pressure range of 1.5–5.0 bar, indicating that the measured rate coefficients are close to the high-pressure limit. The measured values of the rate coefficients resulted in the following Arrhenius expressions (in unit of cm3/molecule/s):To our knowledge, these are the first high-temperature measurements of allyl + NOx reactions. The reported data will be highly useful in understanding the interaction of NOx with resonantly stabilized radicals as well as the mutual sensitization effect of NOx on hydrocarbon fuels. 相似文献
2.
3.
Bajdik J. Pintye-Hódi K. Novák Cs. Kelemen A. Regdon G. Erős I. 《Journal of Thermal Analysis and Calorimetry》2002,68(2):613-627
The extents of the protective effects of coating films on the surface of crystals were determined. Three different samples
were made with different quantities of coating fluid (Sepifilm LP 010 in 10% aqueous solution). Since the atomizing rate was
constant, the coating time increased in parallel with the volume of coating fluid applied. The direct measurement of film
thickness and smoothness is very difficult, and therefore indirect methods were used. Dimenhydrinate was chosen as model drug;
this is a heat-sensitive antihistamine with a low melting point. This temperature can be reached during the tableting process.
The behaviour of samples on exposure to heat was examined by differential scanning calorimetry. The water uptakes of the samples
were determined with an Enslin apparatus. Plasticity was studied with an instrumented tablet machine. These indirect methods
(thermal conductivity, water uptake and plasticity measurements) revealed connections between the results of the various experiments.
An overlong coating time decreased the protective effect of the coating film.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
4.
Miklós Csörgő 《Periodica Mathematica Hungarica》2005,50(1-2):1-27
Summary This article provides a glimpse of some of the highlights of the joint work of Endre Csáki and Pál Révész since 1979. The topics of this short exploration of the rich stochastic milieu of this inspiring collaboration revolve around Brownian motion, random walks and their long excursions, local times and additive functionals, iterated processes, almost sure local and global central limit theorems, integral functionals of geometric stochastic processes, favourite sites--favourite values and jump sizes for random walk and Brownian motion, random walking in a random scenery, and large void zones and occupation times for coalescing random walks. 相似文献
5.
利用激光溅射 分子束的技术 ,结合反射飞行时间质谱计 ,研究了Cu+、Ag+、Au+与乙硫醇的气相化学反应。结果显示这三种金属离子与 (CH3 CH2 SH) n 反应形成一系列团簇离子M+(CH3 CH2 SH) n,且团簇离子尺寸不一样。Ag+、Au+与乙硫醇的反应还生成了 (CH3 CH2 SH) +n ,由此推测Cu+、Ag+、Au+与乙硫醇团簇的反应存在两种通道 ,一种通道是生成M+(CH3 CH2 SH) n,另一种是生成 (CH3 CH2 SH) +n 。Cu+、Au+与乙硫醇的反应还生成了M+(H2 S) (M =Cu、Au) ,但是实验中没有观察到Ag+(H2 S) ,理论计算表明Ag+(H2 S)很不稳定。另外 ,分析产物离子M+(CH3 CH2 SH) n 的强度发现 ,n =1~ 2之间存在明显的强度突变现象 相似文献
6.
Periodica Mathematica Hungarica - 相似文献
7.
The function lattice, or generalized Boolean algebra, is the set of ℓ-tuples with the ith coordinate an integer between 0 and a bound ni. Two ℓ-tuples t-intersect if they have at least t common nonzero coordinates. We prove a Hilton–Milner type theorem for systems of t-intersecting ℓ-tuples.Received September 29, 2004 相似文献
8.
9.
10.
Sándor Csörgő 《Acta Appl Math》2007,96(1-3):159-174
We consider the generalized convolution powers G
α
*u
(x) of an arbitrary semistable distribution function G
α
(x) of exponent α∈(0,2), and prove that for all j, k∈{0,1,2,…} and u>0 the derivatives G
α
(k,j)(x;u)=∂
k+j
G
α
*u
(x)/∂
x
k
∂
u
j
, x∈ℝ, are of bounded variation on the whole real line ℝ. The proof, along with an integral recursion in j, is new even in the special case of stable laws, and the result provides a framework for possible asymptotic expansions in
merge theorems from the domain of geometric partial attraction of semistable laws.
An erratum to this article can be found at 相似文献