Plasma Destruction of Ozone Depleting Substances

The literature on the plasma destruction of ozone depleting substances (ODS) such as CCl₂F₂ and CBrF₃ is reviewed, and compared with more recent work on the decomposition of CCl₂F₂ and CBrClF₂ in oxygen and steam. A comprehensive kinetic scheme for the decomposition of CBrClF₂, which includes the decomposition of CCl₂F₂ and CBrF₃, is presented. Simulations performed with this scheme, and experimental results, demonstrate the importance of allowing for the interconversion of ODS in the assessment of plasma destruction devices.Both experimental and modeling results show that the efficiency of operation of a practical plasma ODS destruction device can be quantified in terms of a throughput parameter, the feed to plasma power ratio (units mol (kWh)^-1), or in terms of the thermochemical mixing temperature, T_m, of the plasma, ODS and oxidant. At low throughputs and high T_m, essentially complete destruction may be achieved, with below-ppm quantities of ODS remaining in the plasma exhaust gases. As throughput rises and Tm falls, a threshold is reached above which the ODS residual rises steeply towards the practical working limit set for ODS destruction by the Montreal Protocol (a destruction level of 99.99%). The assessment of this limit must include all ODS in the exhaust gases, weighted for ozone depleting potential. The use of steam, rather than oxygen, as the oxidizing gas gives superior destruction performance.