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1.
It is shown that there cannot exist a uniform exponential dichotomy for any linear delay equation with a positive finite delay. 相似文献
2.
P. Kappen P.S. Hale N. Brack W. Prissanaroon P.J. Pigram 《Applied Surface Science》2006,253(3):1473-1479
Micro-patterns (80 μm and 10 μm) of copper and semi-conducting polypyrrole on insulating fluorinated ethylene propylene substrates were characterized using synchrotron-based X-ray Photoemission Electron Microscopy (X-PEEM), Near Edge X-ray Absorption Fine Structure (NEXAFS), and Atomic Force Microscopy (AFM). Electronic states in the polypyrrole are verified using the NEXAFS data, and sample degradation upon irradiation is addressed. X-PEEM images show homogeneous distributions of the corresponding elements in the patterns. They do not exhibit dichroic effects and give information about the growth of copper and polypyrrole (i.e. nucleation of Cu, overgrowth of PPy, formation of PPy granules). AFM results are used to verify the topography of the patterns and support the findings on pattern growth. 相似文献
3.
Soderstrom E McKenna JA Abrams GS Adolphsen CE Averill D Ballam J Barish BC Barklow T Barnett BA Bartelt J Bethke S Blockus D Bonvicini G Boyarski A Brabson B Breakstone A Bulos F Burchat PR Burke DL Cence RJ Chapman J Chmeissani M Cords D Coupal DP Dauncey P DeStaebler HC Dorfan DE Dorfan JM Drewer DC Elia R Feldman GJ Fernandes D Field RC Ford WT Fordham C Frey R Fujino D Gan KK Gero E Gidal G Glanzman T Goldhaber G Gomez Cadenas JJ Gratta G Grindhammer G Grosse-Wiesmann P Hanson G Harr R 《Physical review letters》1990,64(25):2980-2983
4.
Komamiya S Abrams GS Adolphsen CE Averill D Ballam J Barish BC Barklow T Barnett BA Bartelt J Bethke S Blockus D Bonvicini G Boyarski A Brabson B Breakstone A Bulos F Burchat PR Burke DL Cence RJ Chapman J Chmeissani M Cords D Coupal DP Dauncey P DeStaebler HC Dorfan DE Dorfan JM Drewer DC Elia R Feldman GJ Fernandes D Field RC Ford WT Fordham C Frey R Fujino D Gan KK Gatto C Gero E Gidal G Glanzman T Goldhaber G Gomez Cadenas JJ Gratta G Grindhammer G Grosse-Wiesmann P Hanson G Harr R 《Physical review letters》1990,64(24):2881-2884
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[reaction: see text] Allylically oxygenated vinyl alpha-triphenylstannanes such as 22 can be readily converted into vinyl iodides and thereafter stereodefined trisubstituted alkenes with retention of configuration. 相似文献
8.
R. T. Olsson H. E. Bair V. Kuck A. Hale 《Journal of Thermal Analysis and Calorimetry》2004,76(2):367-377
Thin films of 3,4-epoxycyclohexylmethyl 3',4'-epoxycyclohexane carboxylate were UV irradiated (1.1 J cm-2) under isothermal conditions ranging from 0 to 50°C. Under these conditions the polymerization advanced quickly but only
to a conversion level of less than 10% before the reaction rate slowed by more than an order of magnitude. This drop off in
rate was not caused by the glass transition temperature, T
g, reaching or exceeding the reaction temperature, T
rxn, since the epoxide's T
g remained at least 40°C below T
rxn. Raising the sample temperature above 60°C caused a sharp increase in the conversion level. At 100°C conversion exceeds 80%
and the ultimate T
g approaches 190°C. The addition of 10 mass% 1,6-hexanediol, HD, to the epoxy caused the conversion at room temperature to
quintuple over the level obtained without the alcohol present. The heat liberated from this alcohol epoxy blend during cure
on a UV conveyor belt system caused the sample's temperature to increase by about 100°C above ambient whereas the epoxy alone
under these conditions only experienced a modest temperature rise of about 26°C. If the amount of HD in the blend is increased
above 10% the heat of reaction at 23°C decreases due to HD being trapped in a nonreactive crystalline phase. Boosting reaction
temperatures above 50°C melts the HD crystals and yields significantly improved conversion ratios. As the level of alcohol
blended with the epoxy is raised its ultimate T
g is lowered and when the concentration of alcohol in the blend nears 30 mass%T
g drops below room temperature.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
9.
Richard A. Bunce Derrick M. Herron Lu Y. Hale 《Journal of heterocyclic chemistry》2003,40(6):1031-1039
A tandem reduction‐reductive amination reaction has been applied to the synthesis of 3,4‐dihydro‐2H‐1,4‐benzoxazines and 1‐acetyl‐1,2,3,4‐tetrahydroquinoxalines. The nitroketones required for the benzoxazine ring closures were prepared by (A) alkylation of the anion derived from 2‐nitrophenol with an allylic halide or (B) nucleophilic aromatic substitution of an allylic alkoxide on 2‐fluoro‐1‐nitrobenzene followed by ozonolysis. Precursors for the quinoxalines were prepared by alkylation of the anion of 2‐nitroacetanilide with an allylic halide followed by ozonolysis. Catalytic hydrogenation of the nitroketones using 5% palladium‐on‐carbon in methanol then gave the target heterocycles by a reduction‐reductive amination sequence. The N‐methyl derivatives for both ring systems were easily prepared by adding 5‐10 equivalents of aqueous formaldehyde prior to the reduction. The dihydrobenzoxazines were isolated in high yield following purification by chromatographic methods; tetrahydroquinoxalines were isolated in a similar manner and possessed differentiated functionality on the two nitrogens. 相似文献
10.