On the stereospecific conversion of proximally-oxygenated trisubstituted vinyltriphenylstannanes into stereodefined trisubstituted alkenes |
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Authors: | Dimopoulos Paschalis Athlan Audrey Manaviazar Soraya Hale Karl J |
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Institution: | The Christopher Ingold Laboratories, The Chemistry Department, University College London, 20 Gordon Street, London WC1H 0AJ, United Kingdom. |
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Abstract: | reaction: see text] Allylically oxygenated vinyl alpha-triphenylstannanes such as 22 can be readily converted into vinyl iodides and thereafter stereodefined trisubstituted alkenes with retention of configuration. |
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