Two new eudesmane derivatives from Verbesina virginica

<正>Two new eudesmane derivatives were isolated from the leaves and flowers of Verbesina virginica,along with the known 6-O-β-E -p-coumaroyl-4α-hydroxyeudesmane(1).Their structures were determined as 6-O-β-Z-p-coumaroyl-4α-hydroxyeudesmane(2) and 6-O-α-E-p-coumaroyl-1β-4α-dihydroxyeudesmane(3) by spectroscopic methods.     

Efficient algorithms for finding minimum spanning trees in undirected and directed graphs

Recently, Fredman and Tarjan invented a new, especially efficient form of heap (priority queue). Their data structure, theFibonacci heap (or F-heap) supports arbitrary deletion inO(logn) amortized time and other heap operations inO(1) amortized time. In this paper we use F-heaps to obtain fast algorithms for finding minimum spanning trees in undirected and directed graphs. For an undirected graph containingn vertices andm edges, our minimum spanning tree algorithm runs inO(m logβ (m, n)) time, improved fromO(mβ(m, n)) time, whereβ(m, n)=min {i|log⁽ⁱ⁾ n ≦m/n}. Our minimum spanning tree algorithm for directed graphs runs inO(n logn + m) time, improved fromO(n log n +m log log log_(m/n+2) n). Both algorithms can be extended to allow a degree constraint at one vertex. Research supported in part by National Science Foundation Grant MCS-8302648. Research supported in part by National Science Foundation Grant MCS-8303139. Research supported in part by National Science Foundation Grant MCS-8300984 and a United States Army Research Office Program Fellowship, DAAG29-83-GO020.     

The nucleolus in games with major and minor players

In this paper, we considern-person weighted majority games with major and minor players. We prove under certain conditions that if the minor players split into equal “mini-minor” players the nucleolus' components which correspond to the major players do not change.     

Effect of Pr-Ca substitution on the transport and magnetic behavior of LaMnO3 perovskite

The effect of simultaneous substitution of a fluctuating cation and a divalent cation in LaMnO₃ perovskite modifies the properties of the material to exhibit large valence colossal magnetoresistance (CMR) effect. A good example of these properties is (La_1−2x Pr _x Ca _x )MnO₃ (LPCMO) type CMR material. In this communication it is reported that, with the increase in x (for x=0.1, 0.15, 0.2), the T _c varies between 100 and 120 K with improvisation in metal-insulator transition. Interestingly, resistance increases with x from few hundred ohms to few kilo ohms with corresponding decrease in the unit cell volume. The results of the studies using X-ray diffraction (XRD), electrical resistivity, magnetoresistance and ac susceptibility measurements on LPCMO samples for understanding the structural, transport and magnetic properties are discussed in detail.     

PRESSURE-VELOCITY EQUILIBRIUM HYDRODYNAMIC MODELS

This article describes mathematical models for phase separated mixtures of materials that are in pressure and velocity equilibrium but not necessarily temperature equilibrium. General conditions for constitutive models for such mixtures that exhibit a single mixture sound speed are discussed and specific examples are described.     

Investigation of modified orange peel in the removal of Cd2+, Co2+ and Zn2+ from wastewater

Journal of Radioanalytical and Nuclear Chemistry - Eco-friendly and cost-effective adsorbent material was successfully synthesized from orange peel (OP). Using H2O2, the modification of the...     

Simultaneous determination of dimethoate and its metabolite omethoate in curry leaf using LC-MS/MS and risk assessment

This study presents the method development, validation, and simultaneous determination of dimethoate and its metabolite omethoate in curry leaf. Samples were extracted following modified quick, easy, cheap, effective, rugged, and safe extraction protocol and analyzed using liquid chromatography-tandem mass spectrometry. The limit of quantification in the matrix was 0.005 μg g⁻¹ for dimethoate and omethoate. Extraction using acetonitrile recorded the average recoveries in the range of 82.25 to 112.97% for dimethoate and 85.57 to 107.22% for omethoate at 0.005, 0.025 and 0.050 μg g⁻¹ fortification levels and relative standard deviation less than 5%. Similarly, the relative standard deviation values for intraday (Repeatability) and interday (Reproducibility) tests were less than 15%. Dissipation kinetics of dimethoate 30% emulsifiable concentrate at 200 and 400 g a.i h⁻¹ recorded initial deposits of 5.20 and 10.05 μg g⁻¹ and 0.33 and 0.48 μg g⁻¹ for dimethoate and omethoate, respectively, and half-life of 3.07 and 3.34 days. The estimated hazard index value found more than one at a day after dimethoate application. It is not safe for consumer health to use curry leaves in the initial days after application.