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排序方式: 共有108条查询结果,搜索用时 500 毫秒
1.
Dr. Kathiravan Murugesan Vishwas G. Chandrashekhar Dr. Carsten Kreyenschulte Prof. Dr. Matthias Beller Dr. Rajenahally V. Jagadeesh 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(40):17561-17565
Herein, we report the synthesis of specific silica-supported Co/Co3O4 core–shell based nanoparticles prepared by template synthesis of cobalt-pyromellitic acid on silica and subsequent pyrolysis. The optimal catalyst material allows for general and selective hydrogenation of pyridines, quinolines, and other heteroarenes including acridine, phenanthroline, naphthyridine, quinoxaline, imidazo[1,2-a]pyridine, and indole under comparably mild reaction conditions. In addition, recycling of these Co nanoparticles and their ability for dehydrogenation catalysis are showcased. 相似文献
2.
Chandrashekhar Khare 《Compositio Mathematica》1998,112(3):365-378
Given an irreducible, modular, mod p representation p, we analyse the local components at p of newforms f which give rise to it. 相似文献
3.
This short review is focused on recent findings on the role of ionic liquids (ILs) in catalysing the hydrogenation of levulinic acid (LA) to gamma valerolactone (GVL), which is a cascade reaction involving more than one type of reaction. A brief introduction on green aspects of IL as a catalyst followed by various types of ILs being used for hydrogenation of LA to GVL are discussed. The unique characteristics of ILs responsible for hydrogenation reaction are also explained along with the current and upcoming scenario of IL catalysed hydrogenation of LA to GVL. 相似文献
4.
Hemant P. Borase Bipinchandra K. Salunke Rahul B. Salunkhe Chandrashekhar D. Patil John E. Hallsworth Beom S. Kim Satish V. Patil 《Applied biochemistry and biotechnology》2014,173(1):1-29
Uses of plants extracts are found to be more advantageous over chemical, physical and microbial (bacterial, fungal, algal) methods for silver nanoparticles (AgNPs) synthesis. In phytonanosynthesis, biochemical diversity of plant extract, non-pathogenicity, low cost and flexibility in reaction parameters are accounted for high rate of AgNPs production with different shape, size and applications. At the same time, care has to be taken to select suitable phytofactory for AgNPs synthesis based on certain parameters such as easy availability, large-scale nanosynthesis potential and non-toxic nature of plant extract. This review focuses on synthesis of AgNPs with particular emphasis on biological synthesis using plant extracts. Some points have been given on selection of plant extract for AgNPs synthesis and case studies on AgNPs synthesis using different plant extracts. Reaction parameters contributing to higher yield of nanoparticles are presented here. Synthesis mechanisms and overview of present and future applications of plant-extract-synthesized AgNPs are also discussed here. Limitations associated with use of AgNPs are summarised in the present review. 相似文献
5.
Patil Seema P. Jadhav Sanjay N. Rode Chandrashekhar V. Shejwal Rajendra V. Kumbhar Arjun S. 《Transition Metal Chemistry》2020,45(6):403-411
Transition Metal Chemistry - A simple and efficient protocol for the ligand-free Mizoroki–Heck coupling reaction of various aryl bromides with different olefins has been reported by using in... 相似文献
6.
Chandrashekhar Khare 《Proceedings of the American Mathematical Society》2003,131(10):3021-3023
In this note we relate the property of a semisimple -adic Galois representation being ``-split' to its having abelian image.
7.
Gowravaram Sabitha Kurra Yadagiri Martha Bhikshapathi Gajangi Chandrashekhar Jhillu Singh Yadav 《Tetrahedron: Asymmetry》2010,21(20):2524-2529
The construction of the C32–C42 fragment of etnangien is described using a desymmetrization strategy generating five stereogenic centers from a bicyclic lactone. Another notable feature includes the use of the Sharpless asymmetric epoxidation to generate a stereogenic center at C40. 相似文献
8.
Rahul P. Dixit Chandrashekhar R. Barhate Mangal S. Nagarsenker 《Chromatographia》2008,67(1-2):101-107
Simvastatin and ezetimibe are used to treat hyperlipidemia. A simple, selective and stability-indicating HPTLC method has
been established for analysis of simvastatin and ezetimibe. The method has been validated so that both drugs can routinely
be analyzed simultaneously. The method uses aluminum-backed silica gel 60F254 TLC plates as stationary phase with n-hexane–acetone 6:4 (v/v) as mobile phase. Densitometric analysis of both drugs was carried out in absorbance mode at 234 nm. This system was found
to give compact bands for simvastatin and ezetimibe (R
F 0.39 ± 0.05 and 0.50 ± 0.05, respectively). Linear relationships were obtained between response and amount of drug in the
range 200–1,600 ng per band with high correlation coefficients (r
2 = 0.9917 ± 0.0018 for simvastatin and r
2 = 0.9927 ± 0.0021 for ezetimibe). The method was validated for precision, robustness, and recovery. The limits of detection
and quantitation were 25 and 150 ng per band, respectively. Simvastatin and ezetimibe were subjected degradation by acid,
pH 6.8 phosphate buffer, oxidation, dry heat, and wet heat. The degradation products were well resolved from the pure drug
with significantly different R
F values. Because the method could effectively separate the drug from its degradation products, it can be used for stability-indicating
analysis. 相似文献
9.
10.
Gowravaram Sabitha Gajangi Chandrashekhar Kurra Yadagiri Jhillu Singh Yadav 《Tetrahedron: Asymmetry》2011,22(18-19):1729-1735
The total syntheses of the first examples of diarylheptanoid natural products (5S)-5-acetoxy-1,7-bis(4-hydroxy-3-methoxyphenyl)-3-heptanone 1, and (3S,5S)-3,5-diacetoxy-1,7-bis(4-hydroxy-3-methoxyphenyl)heptane 2 isolated from the rhizomes of Zingiber officinale were accomplished using Sharpless epoxidation and cross-metathesis reactions as the key steps. 相似文献