Research on Chemical Intermediates - A novel magnetically heterogeneous nanocatalyst has been successfully synthesized via the immobilization of piperazine on tris (hydroxymethyl)... 相似文献
Electrochemical hydrogen storage in porous carbon materials is emerging as a cost-effective hydrogen storage and transport technology with competitive power and energy densities. The merits of electrochemical hydrogen storage using porous conductive carbon-based electrodes are reviewed. The employment of acidic electrolytes in such storage systems is compared with alkaline electrolytes. The recent innovations of a proton battery for smaller-scale electricity storage, and a proton flow reactor system for larger (grid)-scale storage and bulk export of hydrogen produced from renewable energy, are briefly described. It is argued that such systems, along with variants proposed by others, all of which rely on electrochemical hydrogen storage in porous carbons, can contribute to the search for energy storage technologies essential for the transition to a zero-emission global economy. 相似文献
Research on Chemical Intermediates - In this study, an efficient and novel procedure has been reported for loading sulfanilic acid on the surface of magnetite Fe3O4 nanoparticles using... 相似文献
A statistical evaluation of 13,000 numerical simulations of random porous structures is used to establish a correlation between permeability, porosity, tortuosity and conductance. The random structures are generated with variable porosities, and parameters such as the permeability and the tortuosity are determined directly from the structures. It is shown that the prevalent definition of tortuosity, as the ratio of length of the real flow path to the projected path in the overall flow direction, does not correlate with permeability in the general case. Also, the correlation between the conductance of the medium, as an indicator of the accessible cross section of a flow path and permeability is no more reliable than the permeability–porosity correlation. However, if the definition of tortuosity is corrected using the cross-sectional variations, the resulting parameter (i.e., the minimum-corrected tortuosity) has a reliable correlation with permeability and can be used to estimate permeability with an acceptable error for most of the simulations of the random porous structures. The feasibility of extending the conclusions from 2-dimensional to 3-dimensional configurations and the numerical percolation thresholds for random structures are also discussed. 相似文献
The first synthesis of Tröger’s base analogues bearing three and four atoms in the apical strap is reported, leading to a dramatic change in the shape of the aromatic scaffold with respect to the Tröger’s base framework. 相似文献
In this work, a new, green and beneficial nanomagnetic catalyst was easily fabricated using sulfuric acid as an acidic group on Fe3O4 nanoparticles coated with tris (hydroxymethyl) aminomethane (THAM). The synthesized catalyst was characterized by FT-IR, TGA/DTG, XRD, TEM, EDS, VSM, and SEM analyses. Next, its catalytic activity was studied for the synthesis of dihydropyrano[2,3-c]pyrazole derivatives. This catalyst has advantages such as high catalytic activity, non-toxicity, easy separation from the reaction mixture using an external magnet and reuses for several times without significantly reducing in its catalytic activity. 相似文献
A variety is a class of Banach algebras , for which there exists a family of laws such that is precisely the class of all Banach algebras which satisfies all of the laws (i.e. for all , . We say that is an -variety if all of the laws are homogeneous. A semivariety is a class of Banach algebras , for which there exists a family of homogeneous laws such that is precisely the class of all Banach algebras , for which there exists 0$"> such that for all homogeneous polynomials , , where . However, there is no variety between the variety of all -algebras and the variety of all -algebras, which can be defined by homogeneous laws alone. So the theory of semivarieties and the theory of varieties differ significantly. In this paper we shall construct uncountable chains and antichains of semivarieties which are not varieties.
At the nanoscale, methods to measure surface charge can prove challenging. Herein we describe a general method to report surface charge through the measurement of ion current rectification of a nanopipette brought in close proximity to a charged substrate. This method is able to discriminate between charged cationic and anionic substrates when the nanopipette is brought within distances from ten to hundreds of nanometers from the surface. Further studies of the pH dependence on the observed rectification support a surface-induced mechanism and demonstrate the ability to further discriminate between cationic and nominally uncharged surfaces. This method could find application in measurement and mapping of heterogeneous surface charges and is particularly attractive for future biological measurements, where noninvasive, noncontact probing of surface charge will prove valuable. 相似文献
Research on Chemical Intermediates - The aim of this research is the synthesis of a novel acidic nanocatalyst using the layer-by-layer assembly technique. The CoFe2O4@TRIS@sulfated boric acid... 相似文献