全文获取类型
收费全文 | 26485篇 |
免费 | 2374篇 |
国内免费 | 1397篇 |
专业分类
化学 | 13224篇 |
晶体学 | 434篇 |
力学 | 1751篇 |
综合类 | 108篇 |
数学 | 2657篇 |
物理学 | 12082篇 |
出版年
2023年 | 327篇 |
2022年 | 458篇 |
2021年 | 571篇 |
2020年 | 572篇 |
2019年 | 591篇 |
2018年 | 600篇 |
2017年 | 536篇 |
2016年 | 880篇 |
2015年 | 757篇 |
2014年 | 1003篇 |
2013年 | 1491篇 |
2012年 | 1901篇 |
2011年 | 2134篇 |
2010年 | 1598篇 |
2009年 | 1519篇 |
2008年 | 1603篇 |
2007年 | 1529篇 |
2006年 | 1558篇 |
2005年 | 1289篇 |
2004年 | 1013篇 |
2003年 | 800篇 |
2002年 | 733篇 |
2001年 | 1096篇 |
2000年 | 772篇 |
1999年 | 668篇 |
1998年 | 478篇 |
1997年 | 519篇 |
1996年 | 419篇 |
1995年 | 367篇 |
1994年 | 331篇 |
1993年 | 255篇 |
1992年 | 258篇 |
1991年 | 229篇 |
1990年 | 219篇 |
1989年 | 185篇 |
1988年 | 145篇 |
1987年 | 116篇 |
1986年 | 114篇 |
1985年 | 109篇 |
1984年 | 74篇 |
1983年 | 52篇 |
1982年 | 43篇 |
1981年 | 34篇 |
1980年 | 25篇 |
1978年 | 20篇 |
1977年 | 20篇 |
1976年 | 28篇 |
1975年 | 34篇 |
1974年 | 22篇 |
1973年 | 23篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
1.
Liu Zhu Sun Wen-Yang Fan Xiao-Gang Wang Dong Ye Liu 《International Journal of Theoretical Physics》2021,60(7):2412-2422
International Journal of Theoretical Physics - In this paper, we investigate Einstein-Podolsky-Rosen steering, Bell non-locality, first-order coherence and concurrence in the spin- $\frac {1}{2}$... 相似文献
2.
Nonlinear Dynamics - Epilepsy is the second largest neurological disease which seriously threatens human life and health. The one important reason of inducing epileptic seizures is ischemic stroke... 相似文献
3.
Atopic dermatitis is characterized by leukocyte migration into the skin dermis and typically driven by excessive chemokine production at the site of inflammation. Conventional topical formulations such as gels, creams, and ointments are insufficient for this treatment because of low penetration of drug molecules into the targeted skin tissues. Herein, using a simple, green, sustainable strategy, we have developed novel primary zein nanoparticles embedded in curcumin (Cur) and coated with silk sericin (ZHSCs) for the topical delivery of Cur to penetrate into the dermis and exercise anti-dermatitis effects on the lesion with minimal side-effects. Transdermal delivery experiments and porcine skin fluorescence imaging indicated that ZHSCs facilitate the penetration of Cur across the epidermis layer of skin to reach deep-seated sites. Notably, ZHSCs = 1:0.25 (zein-to-silk sericin mass ratios of 1:0.25) markedly elevated the skin permeability and cumulative turnover of Cur transferred, which were provided a greater than a 3.8-fold increase relative to free Cur. The special nanoparticles of ZHS = 1:0.25 possessed the deepest localization depth and experience a transition of the particle structure and core-shell separation after penetrating into the dermis of skin. In a cell model of dermatitis induced by tumor necrosis factor α/interferon γ co-stimulation, compared with free Cur, Cur-loaded ZHS nanoparticles down-regulated the generation of inflammatory cytokines and chemokines in keratinocytes through suppression of the nuclear translocation of NF-κBp65 and hence exerted an anti-dermatitis effect. This strategy may provide new avenues and direction for the demanding issues of valid topical delivery systems. 相似文献
4.
Liu Wenbin Huang Yiwei Huang Guolin Fan Lijiao Xie Yuming Shi Jeffery 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(5):2055-2068
Journal of Radioanalytical and Nuclear Chemistry - Eco-friendly and low-cost composite, amidoxime-functionalized microcrystalline cellulose/mesoporous silica (MCC/MS-AO), were synthesized by... 相似文献
5.
Zhongxian Fan Jiaen Xie Dr. Tumpa Sadhukhan Chao Liang Can Huang Wenqing Li Tingxuan Li Dr. Pingyu Zhang Dr. Samya Banerjee Dr. Krishnan Raghavachari Dr. Huaiyi Huang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(3):e202103346
Four photo-catalysts of the general formula [Ir(CO6/ppy)2(L)]Cl where CO6=coumarin 6 ( Ir1 – Ir3 ), ppy=2-phenylpyridine ( Ir4 ), L=4′-(3,5-di-tert-butylphenyl)-2,2′ : 6′,2′′-terpyridine ( Ir1 ), 4′-(3,5-bis(trifluoromethyl)phenyl)-2,2′ : 6′,2′′-terpyridine ( Ir2 and Ir4 ), and 4-([2,2′ : 6′,2′′-terpyridin]-4′-yl)-N,N-dimethylaniline ( Ir3 ) were synthesized and characterized. These photostable photo-catalysts ( Ir1 – Ir3 ) showed strong visible light absorption between 400–550 nm. Upon light irradiation (465 and 525 nm), Ir1 – Ir3 generated singlet oxygen and induced rapidly photo-catalytic oxidation of cellular coenzymes NAD(P)H. Ir1 – Ir3 showed time-dependent cellular uptake with excellent intracellular retention efficiency. Upon green light irradiation (525 nm), Ir2 provided a much higher photo-index (PI=793) than the clinically used photosensitizer, 5-aminolevulinicacid (5-ALA, PI>30) against HeLa cancer cells. The observed necro-apoptotic anticancer activity of Ir2 was due to the Ir2 triggered photo-induced intracellular redox imbalance (by NAD(P)H oxidation and ROS generation) and change in the mitochondrial membrane potential. Remarkably, Ir2 showed in vivo photo-induced catalytic anticancer activity in mouse models. 相似文献
6.
High Energy Chemistry - Modification of Polyvinylidene fluoride (PVDF) by radiation grafting is a research hotspot in recent years. In this study, the monomer 2-Hydroxyethyl methacrylate (HEMA) was... 相似文献
7.
Journal of Algebraic Combinatorics - A dessin is called circular if the boundary of each face is a circuit (a simple cycle). In this paper, we address the problem of characterizing edge-transitive... 相似文献
8.
Recent success in strain engineering has triggered tremendous interest in its study and potential applications in nanodevice design. In this paper, we establish a coupled piezoelectric/semiconducting model for a wurtzite structure ZnO nanofiber under the local mechanical loading. The energy band structure tuned by the local mechanical loading and local length is calculated via an eight-band k·p method, which includes the coupling of valance and conduction bands. Poisson's effect on the distribution of electric potential inversely depends on the local mechanical loading. Numerical results reveal that both the applied local mechanical loading and the local length exhibit obvious tuning effects on the electric potential and energy band. The band gap at band edges varies linearly with the applied loading. Changing the local length shifts the energy band which is far away from the band edges. This study will be useful in the electronic and optical enhancement of semiconductor devices. 相似文献
9.
Crystallography Reports - A di-nuclear uranyl complex with the formula of [(UO2)2(L)4(H2O)2]?4H2O (1) (HL = quinoline-6-carboxylic acid) was synthesized hydrothermally and characterized by... 相似文献
10.
Li Y. Shi W. H. Dong L. M. Xu S. X. Huang H. J. Yin J. R. 《Journal of Applied Spectroscopy》2022,89(3):534-541
Journal of Applied Spectroscopy - Sr3B2O6:Dy3+, Eu3+ single-matrix white-light-emitting materials are prepared using the high-temperature solid-state method. The microstructure, emission spectrum,... 相似文献