An efficient edge based data structure for the compressible Reynolds-averaged Navier–Stokes equations on hybrid unstructured meshes

An efficient edge based data structure has been developed in order to implement an unstructured vertex based finite volume algorithm for the Reynolds-averaged Navier–Stokes equations on hybrid meshes. In the present approach, the data structure is tailored to meet the requirements of the vertex based algorithm by considering data access patterns and cache efficiency. The required data are packed and allocated in a way that they are close to each other in the physical memory. Therefore, the proposed data structure increases cache performance and improves computation time. As a result, the explicit flow solver indicates a significant speed up compared to other open-source solvers in terms of CPU time. A fully implicit version has also been implemented based on the PETSc library in order to improve the robustness of the algorithm. The resulting algebraic equations due to the compressible Navier–Stokes and the one equation Spalart–Allmaras turbulence equations are solved in a monolithic manner using the restricted additive Schwarz preconditioner combined with the FGMRES Krylov subspace algorithm. In order to further improve the computational accuracy, the multiscale metric based anisotropic mesh refinement library PyAMG is used for mesh adaptation. The numerical algorithm is validated for the classical benchmark problems such as the transonic turbulent flow around a supercritical RAE2822 airfoil and DLR-F6 wing-body-nacelle-pylon configuration. The efficiency of the data structure is demonstrated by achieving up to an order of magnitude speed up in CPU times.     

Thermal performances and stabilities of nanofluids in an electrical oil heater

Journal of Thermal Analysis and Calorimetry - In this study, different nanofluids synthesized with aluminium oxide (alumina) and titanium dioxide in mass ratios of 1%, 3%, and 5% were tested in an...     

Regioselective One‐pot Synthesis of New Unsymmetric Spiro Dihydrofurans in the Reaction of Mixed Two Different Cyclic β‐Dicarbonyl Compounds with BrCN and Aldehydes in the Presence of Et3N

Crossed one‐pot reaction of mixed cyclic β‐dicarbonyl with various aldehydes in the presence of cyano gen bromide and triethylamine leads to the selective and efficient formation of crossed new unsymmetri cal spiro dihydrofurans at room temperature. The products were obtained in good to excellent yields. Structure elucidation was carried out by ¹H NMR, ¹³C NMR, FT‐IR spectroscopy, Mass analyses and X‐ray crystallography technique. A proposed mechanism was discussed for the formation of products.     

Control of vortex formation from a vertical cylinder in shallow water: Effect of localized roughness elements

Vortex formation from a vertical cylinder in shallow water is controlled by placement of a narrow transverse strip of roughness elements on the bed (bottom surface). A technique of high-image-density particle image velocimetry is employed to obtain global, instantaneous representations of the flow patterns, which lead to phase- and time-averaged patterns of streamline topology and Reynolds stress on planes at and above the bed. Near the bed, the overall form of the streamline topology is maintained, even at larger heights of the roughness elements. With increasing height of the elements, the downstream saddle point is further displaced in the streamwise direction. Correspondingly, the streamwise extent of the negative pocket of the streamwise velocity component, i.e., the region of reverse flow along the bed surface, increases substantially in the streamwise direction. The Reynolds stress in the very near-wake, at locations upstream of the roughness elements, is significantly attenuated, even for small height of roughness. This attenuation occurs not only near the bed surface, but also at the midplane of the shallow water wake, and thereby indicates that the consequence of localized roughness is to exert a global influence. In fact, corresponding patterns of instantaneous velocity and vorticity indicate that consistent formation of large-scale vortices in the very near-wake region is attenuated with relatively small surface roughness on the bed. Downstream of the roughness elements, the patterns of Reynolds stress near the bed surface, as well as at the midplane of the water layer, are significantly altered relative to the case of no roughness. Near the bed, highly concentrated patterns of positive and negative Reynolds stress in the absence of roughness give way to lower-level regions of Reynolds stress in the form of alternating concentrations; the particular pattern depends on the height of the roughness elements. At the midplane of the water layer, the Reynolds stress patterns maintain their same overall form, but the extrema of the Reynolds stress concentrations are attenuated in magnitude and are shifted in the downstream direction, with increasing height of the roughness elements. These observations are complemented by patterns of instantaneous velocity and vorticity.     

A Taguchi approach for determination of optimum design parameters for a heat exchanger having circular-cross sectional pin fins

The present work submits an investigation about the optimal values of design parameters and performance analysis for a heat exchanger having cylindrical pin fins positioned in a rectangular channel. The experiments covered the following range: Reynolds number 13,500–42,000, the clearance ratio (C/H) 0, 0.33 and 1, the interfin spacing ratio (S _y /D) 1.208, 1.944 and 3.417. In the experimentation, Taguchi method was employed, and Nusselt number and friction factor were considered as performance parameters. While the optimum parameters were determined, due to the goals (above aims) more than one being, the trade-off among goals was considered. First of all, each goal was optimized, separately. Then, all goals were optimized together, considering the priority of goals, and the optimum results were found to be Reynolds number of 42,000, fin height of 50 mm and pitch of 3.417. The performance analysis also was made under a constant pumping power constraint, and the results showed that the use of cylindrical pin fins may lead to an advantage on the basis of heat transfer enhancement.     

Selective formation of spiro dihydrofurans from one-pot reaction of dimedone with BrCN and aldehydes in the presence of Et3N

Reaction of 5,5-dimethylcyclohexane-1,3-dione (dimedone), aldehydes and cyanogen bromide in the presence of triethylamine leads to the selective formation of spiro dihydrofurans in moderate to good yields at room temperature.     

Synthesis of Chiral Calix[4]arene Derivative and Evaluation of its Recognition Properties

The article describes the synthesis and extraction properties of a new chiral calix[4]arene Schiff base ligand 5, which has been synthesized from 5,17-diformyl-25,27-bis-(4-nitrobenzyloxy)-26,28-dihidroxycalix[4]arene (4) by treatment with (S)-(-)-1-phenylethylamine. In this synthesis, it was thought to explore the role of chiral, as well as Schiff base sites in the recognition of targeted species ions (such as dichromate anions) as well as neutral/chiral molecules. At low pH, the ligand 5 is more effective for transferring the dichromate anions from an aqueous into a dichloromethane layer; may be due to the protonation of nitrogen atoms.

The extraction properties of ligand 5 towards the some selected α -amino acid methylesters are also reported. However, the ligand 5 did not display any selectivity towards the selected α-amino acid methylesters.     

Furo- and thieno-fused 1,3-diazepine-4,6-diones

We report the first preparation of furo- and thieno-fused 1,3-diazepine-4,6-dione derivatives starting from ethyl 2-(2-methoxy-2-oxoethyl)-3-furancarboxylate and -thiophencarboxylate. The ester functionalities connected to the hetero-ring were converted regiospecifically into the desired amides. The ester groups attached to the methylene unit were converted into isocyanates via Curtius rearrangement. The ring-closure reaction was performed in the presence of lithium bis(trimethylsilyl)amide at room temperature to give furo- and thieno-fused diazepinone derivatives.