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排序方式: 共有168条查询结果,搜索用时 20 毫秒
1.
Erbilen Nesibe Zor Erhan Saf Ahmet Ozgur Akgemci Emine Guler Bingol Haluk 《Journal of Solid State Electrochemistry》2019,23(9):2695-2705
Journal of Solid State Electrochemistry - Chirality is a universal characteristic of natural systems and discrimination of enantiomers of a chiral molecule plays a major role particularly in... 相似文献
2.
Emine
zge Karaca Osman ifti lknur
zdemir Gül Yakali Muhittin Aygün Nevin Gürbüz smail
zdemir 《应用有机金属化学》2019,33(7)
Platinum (II) complexes bearing N‐heterocyclic carbene (NHC) ligands have been widely used in catalytic chemistry, but there are very few reports of biological properties of this type of complexes. A series of [PtCl2(NHC)(PEt3)] complexes were synthesized. The structures of all compounds were characterized by 1H‐NMR, 13C‐NMR, IR and elemental analysis techniques, which supported the proposed structures. The single crystal structures of complexes 1a and 1e were determined. The title complexes show slightly distorted square‐planar coordination around the platinum (II) metal center. The cytotoxic properties of the platinum (II)–NHC complexes have been assessed in various human cancer lines, including cisplatin‐sensitive and resistant cells. IC50 values of these four complexes were determined by the MTS‐based assay on three human cell lines—brain (SHSY5Y), colon (HTC116) and liver (HEP3B). These complexes have been highlighted cancer therapeutic agent with unique structures and functions. 相似文献
3.
Cemal Özeroğlu Emine Doğan Gönül Keçeli 《Journal of Radioanalytical and Nuclear Chemistry》2011,289(2):577-586
In this study, a crosslinked copolymer bearing sodium methacrylate functional groups has been proposed to remove Cs(I) ions
from aqueous solutions. For this purpose, the crosslinked copolymer of ethylene glycol dimethacrylate (EGDM) and methacrylic
acid (MA) containing 25% MA as weight percentage was synthesized by using benzoyl peroxide (BPO)-N,N-dimethyl aniline initiator system. The available carboxyl groups in copolymer were converted to the groups of sodium methacrylate
using 2 N NaOH. The adsorption behavior of cesium ions on the densely crosslinked poly(sodium methacrylate) from aqueous solutions
were investigated by the technique of ICP-MS measurements of cesium ions in solutions. Batch adsorption method was used to
analyze the Cs(I) adsorption as a function of parameters such as the amount of adsorbent, contact time, pH of solution, initial
Cs(I) concentration and temperature. The adsorption data were evaluated by the Freundlich, Langmuir and Dubinin–Radushkevich
(D–R) isotherms. The adsorption capacity and free energy change were calculated by using D–R isotherm. The adsorption data
obtained from experimental results have been tested by the fractional power, the Elovich, the pseudo-first order and the pseudo-second
order kinetic models. 相似文献
4.
O?uzhan Demirel Emine Soytürk Seyrantepe 《Journal of Mathematical Analysis and Applications》2011,374(2):566-572
In this paper we present a new characterization of Möbius transformations by use of hyperbolic regular polygons. 相似文献
5.
Emine Özge Karaca Mitat Akkoç Muhammad Nawaz Tahir Cengiz Arıcı Fatma İmik Nevin Gürbüz Sedat Yaşar İsmail Özdemir 《Tetrahedron letters》2017,58(36):3529-3532
A series of seven-membered ditopic ring-expanded N-heterocyclic carbene (dre-NHC) precursors, bearing sterically demanding and electron-rich aryl groups, were synthesised in moderate yields via the reaction of 1,2,4,5-tetrakis(bromomethyl)benzene with the corresponding N,N′-diarylformamidines in the presence of K2CO3 in acetonitrile under an air atmosphere. All new compounds were characterised by HRMS, NMR spectroscopy, and microanalysis, as well as X-ray crystallography for compound 1c. The development of an efficient catalytic system for the Suzuki-Miyaura coupling reaction of aryl chlorides with various boronic acids was also investigated using the in situ generated dre-NHC ligands. 相似文献
6.
Nadeem ur Rehman Öznur Gölbaşı Emine Koç 《Rendiconti del Circolo Matematico di Palermo》1938,62(2):245-251
Let \((R,*)\) be a \(2\)-torsion free \(*\)-prime ring with involution \(*\), \(L\ne \{0\}\) be a \(*\)-Lie ideal of \(R\). An additive mapping \(d:R\rightarrow R\) is called an \((\alpha ,\beta )\)-derivation of \(R\) such that \(d(xy)=d(x)\alpha (y)+\beta (x)d(y)\). In the present paper, we shall show that when \(L\) satisfies any of several identities involving \(d\), then \(L\) is central. 相似文献
7.
Aybüke A. İsbir Turan Zafer Üstündağ Ali Osman Solak Emine Kılıç Ayça Avseven 《Electroanalysis》2008,20(15):1665-1670
This work describes the characterization of the grafted 2‐benzo[c]cinnoline (2BCC) molecules at a glassy carbon (GC) electrode surface by voltammetry and spectroscopy. Attachment of the molecule to the carbon substrate was achieved by the electrochemical reduction of 2‐benzo[c]cinnoline diazonium salt (2BCC‐DAS). GC electrode modification was carried out in aprotic solution with 2BCC diazonium salt. Dopamine (DA) and ascorbic acid (AA) were used to prove the surface modification to see the blockage of the electron transfer. The presence of 2BCC at the GC electrode surface was characterized by cyclic voltammetry and Raman spectroscopy. Raman spectroscopy was used to monitor molecular bound properties of the adsorbates at the 2BCC‐GC surface and confirm the attachment of 2BCC molecules onto the GC surface. The thickness of the 2BCC film on GC was also investigated by ellipsometric measurement. 相似文献
8.
The electrochemical behavior of some podands at a benzo[c]cinnoline modified glassy carbon electrode
Aybüke A. ?sb?r Zafer Üstünda? Selen B?lge Amgalan Natsagdorj Emine Kiliç Zeynel Kiliç 《Analytica chimica acta》2005,547(1):59-63
This paper describes the grafting of benzo[c]cinnoline (BCC) molecules on glassy carbon (GC) electrode surface. The attachment of BCC molecules to carbon substrate is induced by the electrochemical reduction of the corresponding diazonium salt. The modification of GC with BCC diazonium salt was done in aprotic solution and proved by blocking of dopamine electron transfer. The presence of BCC at the GC surface was characterized by cyclic voltammetry and X-ray photoelectron spectroscopy (XPS). On modified surface, the electrochemical behavior of two different types of podands and the catalytic effects of the GC-BCC surface were studied. The XPS was used to monitor element characteristics of the adsorbates on the GC surface and confirm the attachment of BCC molecules to the GC surface. 相似文献
9.
Emine Sarigllü 《商业与工业应用随机模型》1994,10(1):27-46
Prediction of customer choice behaviour has been a big challenge for marketing researchers. They have adopted various models to represent customers purchase patterns. Some researchers considered simple zero–order models. Others proposed higher–order models to represent explicitly customers tendency to seek [variety] or [reinforcement] as they make repetitive choices. Nevertheless, the question [Which model has the highest probability of representing some future data?] still prevails. The objective of this paper is to address this question. We assess the predictive effectiveness of the well–known customer choice models. In particular, we compare the predictive ability of the [dynamic attribute satiation] (DAS) model due to McAlister (Journal of Consumer Research, 91, pp. 141–150, 1982) with that of the well–known stochastic variety seeking and reinforcement behaviour models. We found that the stochastic [beta binomial] model has the best predictive effectiveness on both simulated and real purchase data. Using simulations, we also assessed the effectiveness of the stochastic models in representing various complex choice processes generated by the DAS. The beta binomial model mimicked the DAS processes the best. In this research we also propose, for the first time, a stochastic choice rule for the DAS model. 相似文献
10.
M. Yakup Arca Meltem Ylmaz Emine Yaln Gülay Bayramo
lu 《Journal of membrane science》2004,240(1-2):167-178
Poly(hydroxyethyl methacrylate), pHEMA, and a composite pHEMA/chitosan networks were synthesized in the membrane form via UV initiated photo-polymerisation in the presence of an initiator ,′-azoisobutyronitrile. Reactive Yellow 2 (RY-2) was covalently immobilised as a dye–ligand onto both membranes. The polarity and surface energy of the investigated membranes were determined by contact angle measurement. The incorporation of chitosan in the pHEMA networks produced more hydrophilic surface, as indicated by contact angle analysis. The binding characteristics of lysozyme, γ-globulins, human serum albumin (HSA) and bovine serum albumin (BSA) to pHEMA-RY-2 and pHEMA/chitosan-RY-2 affinity membranes have been investigated from aqueous solution and their dye–ligand free forms were used as control systems. When chitosan was incorporated in the pHEMA network as a cationic polymer led to higher adsorption capacity for the lysozyme. Selective adsorption behaviour was also observed in the case of pHEMA/chitosan-RY-2 membrane for the lysozyme. The non-specific adsorptions of the lysozyme on the pHEMA and pHEMA/chitosan membranes were about 1.9 and 7.2 mg/ml, respectively. These were negligible for all others investigated proteins. The lysozyme adsorption data was analysed using the first-order and the second-order models. The first-order equation in both affinity membrane systems is the most appropriate equation to predict the adsorption capacities of the adsorbents. The adsorption isotherms well fitted the combined Langmuir–Freundlich model. A theoretical analysis has been conducted to estimate the thermodynamic contributions (changes in enthalpy, entropy and Gibbs free energy) for the adsorption of lysozyme to both dye–ligand immobilised membranes. The adsorption capacities of both dye–ligand immobilised membranes increased with increasing the temperature while decreased with increasing the NaCl concentration. Both affinity membranes are stable when subjected to sanitization with sodium hydroxide after repeated separation–elution cycles. 相似文献