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排序方式: 共有1747条查询结果,搜索用时 31 毫秒
1.
Lee Bryan Tian Siyu Xiong Guoping Yang Ying Zhu Xiaoshan 《Journal of nanoparticle research》2022,24(4):1-15
Journal of Nanoparticle Research - Polycrystalline metallic copper nanoparticle samples with the average particle sizes ranging from 53 to 80 nm were controllably prepared by the wet... 相似文献
2.
Y. T. Angel Wong Vinicius Martins Dr. Bryan E. G. Lucier Prof. Dr. Yining Huang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(8):1848-1853
Metal–organic frameworks (MOFs) have shown great potential in gas separation and storage, and the design of MOFs for these purposes is an on-going field of research. Solid-state nuclear magnetic resonance (SSNMR) spectroscopy is a valuable technique for characterizing these functional materials. It can provide a wide range of structural and motional insights that are complementary to and/or difficult to access with alternative methods. In this Concept article, the recent advances made in SSNMR investigations of small gas molecules (i.e., carbon dioxide, carbon monoxide, hydrogen gas and light hydrocarbons) adsorbed in MOFs are discussed. These studies demonstrate the breadth of information that can be obtained by SSNMR spectroscopy, such as the number and location of guest adsorption sites, host–guest binding strengths and guest mobility. The knowledge acquired from these experiments yields a powerful tool for progress in MOF development. 相似文献
3.
Kentarou Sakamoto Dr. Misao Akishiba Takahiro Iwata Dr. Kazuya Murata Dr. Seiya Mizuno Dr. Kenichi Kawano Dr. Miki Imanishi Prof. Dr. Fumihiro Sugiyama Prof. Dr. Shiroh Futaki 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(45):20165-20173
Endocytic pathways are practical routes for the intracellular delivery of biomacromolecules. Along with this, effective strategies for endosomal cargo release into the cytosol are desired to achieve successful delivery. Focusing on compositional differences between the cell and endosomal membranes and the pH decrease within endosomes, we designed the lipid-sensitive and pH-responsive endosome-lytic peptide HAad. This peptide contains aminoadipic acid (Aad) residues, which serve as a safety catch for preferential permeabilization of endosomal membranes over cell membranes, and His-to-Ala substitutions enhance the endosomolytic activity. The ability of HAad to destabilize endosomal membranes was supported by model studies using large unilamellar vesicles (LUVs) and by increased intracellular delivery of biomacromolecules (including antibodies) into live cells. Cerebral ventricle injection of Cre recombinase with HAad led to Cre/loxP recombination in a mouse model, thus demonstrating potential applicability of HAad in vivo. 相似文献
4.
Li-Hsiang Wang Norihiko Hayase Dr. Haruki Sugiyama Juntaro Nogami Prof. Dr. Hidehiro Uekusa Prof. Dr. Ken Tanaka 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(41):18107-18113
Single and double cyclophenylene–ethynylenes (CPEs) with axial and helical chirality have been synthesized by the Sonogashira cross-coupling of di- and tetraethynyl biphenyls with a U-shaped prearomatic diiodoparaphenylene followed by reductive aromatization. X-ray crystallographic analyses and DFT calculations revealed that the CPEs possess highly twisted bent structures. Bend angles on the edge of the paraphenylene units were close to the value of [5]cycloparaphenylene (CPP)—the smallest CPP to date. The double and single CPEs possessed stable chirality despite flexible biphenyl structures because of the high strain in the diethynyl–paraphenylene moiety. In both the single and double CPEs, orbital interactions along the biphenyl axis were observed by DFT calculations in LUMO and LUMO+2 of the single CPE and LUMO+1 of the double CPE, which likely cause lowering of these orbital energies. Concerning chiroptical properties: boosting of the gabs value was observed in the biphenyl-based double CPE, as well as the binaphthyl-based single CPE, compared to the biphenyl-based single CPE. 相似文献
5.
Aida Contreras-Ramirez Dr. Bryan E. Tomlin Gregory S. Day Prof. Dr. Abraham Clearfield Prof. Dr. Hong-Cai Zhou 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(28):6185-6194
Nanosized α-zirconium phenylphosphonate particles were successfully prepared by the reaction between different zirconium sources and molten phenylphosphonic acid in the absence of solvent. The resultant nanoplates exhibit particle sizes in the range of 15 to 30 nm. The use of a topotactic anion exchange method starting from α-zirconium phosphate instead resulted in the generation of 15 to 180 nm plates, while also resulting in nanoparticles with a higher degree of crystallinity. The topotactic anion exchange of the phosphate groups by phenylphosphonate groups could be performed to completion when performed in molten phenylphosphonic acid. Characterization of both the final products as well as the individual steps in the anion exchange were performed by powder XRD, fast neutron activation analysis, TGA, FTIR spectroscopy, TEM, solid-state NMR and XPS. 相似文献
6.
Chinomso Nwosu Tara P. Pandey Andrew M. Herring Soenke Seifert E. Bryan Coughlin 《Journal of polymer science. Part A, Polymer chemistry》2020,58(24):3446-3455
Random copolymers of poly(4-vinylpyridine) and polyisoprene were synthesized, and subsequently quaternized with 1-alkylbromides. The number of carbons on the pendant side-chain of the resultant comb-shaped polymer, n, ranged from 2–8. The comb-shaped polymers were crosslinked employing thiol-ene chemistry to give mechanically robust ion conducting membranes. Analysis by wide and medium-angle X-ray scattering show three morphology regimes that are dependent on the number of carbons on the pendant side-chains. When n = 2, ionomer cluster morphology was dominant, when n = 8 backbone-backbone morphology was dominant, and when n = 3–6, the membrane showed a coexistence of both ionomer cluster and backbone-backbone morphologies. Evaluation of the water uptake of the membranes showed a maximum water uptake per cation of 9.5 when n = 5 at 95% relative humidity (RH) and 60°C. Conductivity of the samples characterized by electrochemical impedance spectroscopy showed bromide conductivity as high as 110 mS/cm when n = 3 at 95% RH and 90°C. 相似文献
7.
Yukimasa Aida Juntaro Nogami Dr. Haruki Sugiyama Prof. Dr. Hidehiro Uekusa Prof. Dr. Ken Tanaka 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(55):12579-12588
The enantioselective synthesis of polycyclic aromatic hydrocarbon (PAH)-based planar chiral cyclophanes was achieved for the first time by the rhodium-catalyzed intramolecular regio- and enantioselective [2+2+2] cycloaddition of tethered diyne-benzofulvenes followed by stepwise oxidative transformations. The thus synthesized planar chiral bent cyclophanes, that possess bent p-terphenyl- and 9-fluorenone-cores, were converted to 9-fluorenol-based ones with excellent ee values of >99 % by diastereoselective 1,2-reduction. These 9-fluorenol-based cyclophanes exhibited high fluorescence quantum yields, which were significantly higher than that of an acyclic reference molecule (78–82 % vs. 48 %). The bending effect on the chiroptical property was also examined, which revealed that the anisotropy factors (gabs values) for electronic circular dichroism (ECD) of these 9-fluorenol-based planar chiral bent cyclophanes increase as the tether length becomes shorter. 相似文献
8.
G. Jeremy Leong Maxwell C. Schulze Matthew B Strand David Maloney Sarah L. Frisco Huyen N. Dinh Bryan Pivovar Ryan M. Richards 《应用有机金属化学》2014,28(1):1-17
Platinum‐based catalytic materials have received significant attention, particularly in the shape and size control of faceted materials for catalysis. More recently, there has been a rapid increase in the number of reports of successful preparations in this field; however, a fundamental understanding of controlled growth towards catalytic material design is essential for future implementation and broad application. In this review, we provide an overview of the recent findings reported since 2009, focusing on methods for shape control as well as the effects of exposed surface facets on select catalytic reactions. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
9.
Seong-Wook Kim Hyeonjung Jung Dr. Mahmut Sait Okyay Dr. Hyuk-Jun Noh Sein Chung Young Hyun Kim Jong-Pil Jeon Prof. Dr. Bryan M. Wong Prof. Dr. Kilwon Cho Dr. Jeong-Min Seo Prof. Dr. Jung-Woo Yoo Prof. Dr. Jong-Beom Baek 《Angewandte Chemie (International ed. in English)》2023,62(42):e202310560
The development of covalent organic frameworks (COFs) with efficient charge transport is of immense interest for applications in optoelectronic devices. To enhance COF charge transport properties, electroactive building blocks and dopants can be used to induce extended conduction channels. However, understanding their intricate interplay remains challenging. We designed and synthesized a tailor-made COF structure with electroactive hexaazatriphenylene (HAT) core units and planar dioxin (D) linkages, denoted as HD-COF. With the support of theoretical calculations, we found that the HAT units in the HD-COF induce strong, eclipsed π–π stacking. The unique stacking of HAT units and the weak in-plane conjugation of dioxin linkages leads to efficient anisotropic charge transport. We fabricated HD-COF films to minimize the grain boundary effect of bulk COFs, which resulted in enhanced conductivity. As a result, the HD-COF films showed an electrical conductivity as high as 1.25 S cm−1 after doping with tris(4-bromophenyl)ammoniumyl hexachloroantimonate. 相似文献
10.
Laser Machined Plastic Laminates: Towards Portable Diagnostic Devices for Use in Low Resource Environments 下载免费PDF全文
Jason C. Harper Bryan D. Carson George D. Bachand William D. Arndt Melissa R. Finley C. Jeffrey Brinker Thayne L. Edwards 《Electroanalysis》2015,27(11):2503-2512
Despite significant progress in development of bioanalytical devices cost, complexity, access to reagents and lack of infrastructure have prevented use of these technologies in resource‐limited regions. To provide a sustainable tool in the global effort to combat infectious diseases the diagnostic device must be low cost, simple to operate and read, robust, and have sensitivity and specificity comparable to laboratory analysis. In this mini‐review we describe recent work using laser machined plastic laminates to produce diagnostic devices that are capable of a wide variety of bioanalytical measurements and show great promise towards future use in low‐resource environments. 相似文献