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Ukrainian Mathematical Journal - We establish new properties of the solutions of a functional-differential equation with linearly transformed argument. 相似文献
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The First One‐Pot Synthesis of Metal–Organic Frameworks Functionalised with Two Transition‐Metal Complexes 下载免费PDF全文
Dr. Ana E. Platero‐Prats Dr. Antonio Bermejo Gómez Dr. Louise Samain Prof. Xiaodong Zou Prof. Belén Martín‐Matute 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(2):861-866
The synthesis of a metal–organic framework (UiO‐67) functionalised simultaneously with two different transition metal complexes (Ir and Pd or Rh) through a one‐pot procedure is reported for the first time. This has been achieved by an iterative modification of the synthesis parameters combined with characterisation of the resulting materials using different techniques, including X‐ray absorption spectroscopy (XAS). The method also allows the first synthesis of UiO‐67 with a very wide range of loadings (from 4 to 43 mol %) of an iridium complex ([IrCp*(bpydc)(Cl)Cl]2?; bpydc=2,2′‐bipyridine‐5,5′‐dicarboxylate, Cp*=pentamethylcyclopentadienyl) through a pre‐functionalisation methodology. 相似文献
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Andreu Presa Rosa F. Brissos Ana Belén Caballero Ivana Borilovic Dr. Luís Korrodi‐Gregório Prof. Ricardo Pérez‐Tomás Dr. Olivier Roubeau Prof. Patrick Gamez 《Angewandte Chemie (International ed. in English)》2015,54(15):4561-4565
The photoactivation of potential anticancer metal complexes is a hot topic of current research as it may lead to the development of more selective drugs. Photoactivated chemotherapy (PACT) with coordination compounds is usually based on a (photo)chemical reaction taking place at the metal center. Herein, a new strategy is exploited that consists of “photomodifying” a ligand coordinated to metal ions. Platinum(II) complexes from photoswitchable 1,2‐dithienylethene‐containing ligands have been prepared, which exhibit two interconvertible photoisomeric forms that present distinct DNA‐interacting properties and cytotoxic behaviors. 相似文献
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In this contribution, an inverse identification strategy of constitutive laws for elastoplastic behaviour is presented. The proposed inverse algorithm is composed on an appropriate finite element calculation combined with an optimisation procedure. It is applied to identify material anisotropic coefficients using a set up of easy performed laboratory tests. The used experimental data are the plane tensile test and the off axes tensile tests. The identified behaviour models are mainly based on Hill's quadratic yield criterion. Two cases of this yield criterion have been considered: the transverse isotropic and the orthotropic one under an associated and non-associated flow rule assumptions for each case. The yield surface has been assumed to expand isotropically (isotropic strain hardening law) as a function of the plastic work.In order to better describe anisotropic plastic properties of the studied materials, a recently planar anisotropic yield function is used. It is a non-quadratic yield criterion which takes account of anisotropic yield stresses as well as anisotropic strain ratios. It is subsequently shown that the agreement between inverse identification results and experimental measurements were improved.We prove also that the presented strategy is a good alternative to the simplified homogeneous tests assumption, especially for the plane tensile test. 相似文献
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D.V. Bel’skii 《Nonlinear Oscillations》2006,9(2):166-172
We establish new properties of C
1[−1, +∞)-solutions of the linear functional differential equation ẋ(t) = ax(t) + bx(qt) + hx(t−1) + cẋ(qt) + rẋ(t−1) in the neighborhood of the singular point t = +∞.
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Translated from Neliniini Kolyvannya, Vol. 9, No. 2, pp. 170–177, April–June, 2006. 相似文献
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Leont’eva N. N. Drozdov V. А. Bel’skaya О. B. Cherepanova S. V. 《Russian Journal of General Chemistry》2020,90(3):509-522
Russian Journal of General Chemistry - Results of studying the structural defects in MgAl and NiAl layered double hydroxides and in the products of their thermal decomposition to 1000°C,... 相似文献
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A. Yu. Spivak D. A. Nedopekina E. R. Shakurova R. R. Khalitova R. R. Gubaidullin V. N. Odinokov U. M. Dzhemilev Yu. P. Bel’skii N. V. Bel’skaya S. A. Stankevich E. V. Korotkaya V. A. Khazanov 《Russian Chemical Bulletin》2013,62(1):188-198
New derivatives of lupane triterpenoids, viz., 20,29-dihydrobetulinic and 3-epi-20,29-dihydrobetulinic acid derivatives containing triphenylphosphonium fragments as substituents were synthesized. These compound considerably exceed betulinic acid in antitumor activity. 相似文献
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