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1.
N. M. Lazarev B. I. Petrov G. A. Abakumov M. A. Katkova T. V. Balashova Yu. A. Bessonova V. I. Faerman A. V. Arapova T. I. Lopatin 《Russian Journal of General Chemistry》2012,82(7):1250-1253
A new class of Sc, Eu, and Tb complexes with N,O-chelate ligands was synthesized for the first time. The mass spectra, thermogravimetric analysis, differential scanning calorimetry data, as well as the data on the saturated vapor pressure of the compounds were obtained. The main thermochemical parameters of the compounds were calculated. 相似文献
2.
E. V. Balashova B. B. Krichevtsov F. B. Svinarev N. V. Zaitseva 《Physics of the Solid State》2016,58(7):1397-1406
Thin films of partially deuterated betaine phosphate have been grown by the evaporation on Al2O3(110) and NdGaO3(001) substrates with a preliminarily deposited structure of interdigitated electrodes. The grown films have a polycrystalline block structure with characteristic dimensions of blocks of the order of 0.1–1.5 mm. The degree of deuteration of the films D varies in the range of 20–50%. It has been found that, at the antiferroelectric phase transition temperature Tcafe = 100–114 K, the fabricated structures exhibit an anomaly of the electrical capacitance C, which is not accompanied by a change in the dielectric loss tangent tanδ. The strong-signal dielectric response is characterized by the appearance of a ferroelectric nonlinearity at temperatures T >Tcafe, which is transformed into an antiferroelectric nonlinearity at T <Tcafe. With a further decrease in the temperature, double dielectric hysteresis loops appear in the antiferroelectric phase. The dielectric properties of the films have been described within the framework of the Landau-type thermodynamic model taking into account the biquadratic coupling ξP2η2 between the polar order parameter P and the nonpolar order parameter η with a positive coefficient ξ. The E–T phase diagram has been constructed. 相似文献
3.
Temperature dependences of the dielectric permittivity of betaine phosphite crystals are studied both without and under application of an electric bias. It is shown that, in view of the fact that the high-temperature improper ferroelastic (antiferrodistorsive) phase transition at T c1=355 K is nearly tricritical, the nonlinear temperature dependence of inverse dielectric permittivity in the paraelectric phase and the effect of the field on the dielectric permittivity can be described within a phenomenological model containing two coupled (polar and nonpolar) order parameters with a negative coupling coefficient. An analysis of the model revealed that, in the case where two phase transitions, a nonpolar and a ferroelectric one, can occur in the crystal, all of its dielectric properties, including the polarization response in a field, can be described by one dimensionless parameter a. For the crystal under study, we have a=?2.5. This value of the parameter corresponds to a second-order ferroelectric transition far from the tricritical point, at which a=?1. It is shown that the polarization response in the paraelectric phase in an electric field calculated within this model differs radically from that in the ferroelectric phase-transition model for which the Curie-Weiss law holds in the paraelectric phase. 相似文献
4.
5.
Summary Certain chelate compounds, containing nickel and zinc, can serve as chemical models of alcohol dehydrogenase in the dehydrogenation of ethyl alcohol.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimisheskaya, No. 7, pp. 1273–1274, July, 1965 相似文献
6.
Triglycine sulfate (TGS) films have been prepared by evaporation from a saturated aqueous solution on substrates of fused
quartz coated by a layer of thermally deposited aluminum (Al/SiO2) and white sapphire (α-Al2O3) on whose surface interdigital electrodes have been deposited by photolithography. The TGS films have a polycrystalline structure
made up of blocks measuring 0.1–0.3 mm (Al/SiO2) and 0.1 × 1.0 mm (α-Al2O3). The polar axis in the blocks is mostly confined to the substrate plane. The temperature dependences of the capacitance
and dielectric losses normal to and in the film plane have maxima at the temperature coinciding with that of the ferroelectric
phase transition in a bulk crystal, T
c
. The low-frequency conductivity G in TGS/Al/SiO2 structures displays a frequency dispersion described by the relation G ∼ ω
s
(s ≈ 0.82). The conduction can be tentatively ascribed to the hopping mechanism involving localized carriers with a ground state
energy of 0.8–0.9 eV. At temperatures above and below T
c
, the low-frequency conductivity in TGS/α-Al2O3 films operates through a thermally-activated mechanism with an activation energy of 0.9–1.0 eV. At the phase transition,
an additional contribution to conductivity appears in TGS/α-Al2O3 films with a dispersion G ∼ ω0.5, which can be associated with domain-wall relaxation. 相似文献
7.
E. V. Balashova B. B. Krichevtsov F. B. Svinarev V. V. Lemanov 《Physics of the Solid State》2013,55(5):995-1001
Polycrystalline textured films of deuterated glycine phosphite consisting of single-crystal blocks with lateral dimensions ~(50–100) μm and a thickness d ~ (1–5) μm have been grown by evaporation on NdGaO3(100) and α-Al2O3 substrates with preliminarily deposited interdigitated electrodes, as well as on Al substrates. The c* (Z) crystallographic axis in the blocks is normal to the film plane, and the a (X) axis and the polar axis b (Y) are oriented in the film plane. The temperature dependences of the capacitance of the structures measured with the interdigitated electrode system reveal a strong dielectric anomaly at the film transition to the ferroelectric state. The phase transition temperature T c depends on the degree of deuteration D of the glycine phosphite. The maximum value T c = 275 K obtained in the structures studied corresponds to a degree of deuteration of the glycine phosphite D ~ 50%. The frequency behavior of the dielectric hysteresis loops in glycine phosphite films differs radically from that of the previously studied films of deuterated betaine phosphite, which evidences that polarization switching in these structures proceeds by different mechanisms. It has been that application of a dc bias to the electrodes changes the shape of the dielectric hysteresis loops and shifts them along the electric field axis. The shift of the loops depends on the sign, magnitude, and time of application of the bias. Possible mechanisms underlying the induced unipolarity are discussed. 相似文献
8.
Balashova T. V. Baranov E. V. Fukin G. K. Ilichev V. A. Grishin I. D. Yablonskiy A. N. Andreev B. A. Bochkarev M. N. 《Russian Journal of Coordination Chemistry》2019,45(10):712-720
Russian Journal of Coordination Chemistry - The synthesis of complexes LnI(C6F5O)2 and LnCp(L)2 (Ln = Er, Yb; L = C6F5O, SONF), which are convenient precursors for the preparation of heteroligand... 相似文献
9.
L. L. Balashova 《Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques》2014,8(2):288-291
The temperature dependence of axially channeled antiprotons in a Si crystal is studied using computer simulation. The number of channeled particles and the energy and angular distributions are calculated for antiprotons with an energy of 300 keV in the temperature range of 100 to 1000 K in the 〈100〉, 〈110〉, and 〈111〉 channels. The roles of the potential and atomic thermal vibrations are studied thoroughly. It is found that dechanneling depends on the crystal temperature. There exists an optimal temperature, which is dependent on the axis direction, for which dechanneling is minimal. 相似文献
10.
Radiophysics and Quantum Electronics - We generalize a variant of the auxiliary-source method, which was proposed earlier for solving the problem of electromagnetic-wave scattering by a structure... 相似文献