Riboflavin as a green sorbent in dispersive micro-solid-phase extraction of several pesticides from fruit juices combined with dispersive liquid–liquid microextraction

A vortex-assisted dispersive micro-solid-phase extraction procedure using a new and green sorbent was developed as a simple, fast, and efficient sample preparation method for the extracting five pesticides in several fruit juice samples. In this study, for the first time, riboflavin was used as an efficient sorbent. A few milligrams of riboflavin was directly added into the aqueous solution containing the analytes to adsorb them. After adsorption the analytes, they were desorbed and more concentrated by a dispersive liquid–liquid microextraction procedure. The influence of several effective parameters such as amount of riboflavin, pH, vortex time, eluent nature and volume, and extraction solvent type and volume on the extraction efficiency was investigated. In optimal conditions, linear ranges of the calibration curves were broad. The limits of detection and quantification were attained in the ranges of 0.56–1.5  and 1.9–0.52 ng mL⁻¹, respectively. The proposed method demonstrated to be suitable for concurrent extraction of the studied pesticides in various fruit juice samples with high enrichment factors (320–360) and precision (relative standard deviation ≤7.8% for intra- [n = 6] and interday [n = 4] precisions at a concentration of 25 ng mL⁻¹ of each pesticide).     

PKI域间互操作性研究

Internet作为电子商务和数字通信的基础平台面临着很多安全威胁.PKI技术为安全电子交易提供了保障.电子商务中.在不同的PKI域之间需要实现互操作.本文提出了一种不使用交叉证书的情况下连接多个独立的PKI域的新方法.该方法是将多个PKl域整合成一个PKI域来实现PKl域之间的互操作.本文采用形式化的方法来描述合并过程.     

Efficient regeneration of aldehydes from their corresponding 1,3-oxathiolanes in the absence of solvent

A mild and efficient method for the oxidative deprotection of 1,3-oxathiolanes with Fe（NO₃）₃·9H₂O and Cu（NO₃）₂·3H₂O in the absence of solvent is reported.     

基于数字证书的校园网安全通信模型的实现

用户名＋口令的简单身份认证方式以及在Intranet内基于B／S模式的信息以明文交换的方式已经无法满足校园网内部通信的安全性需求．本文在对相关理论知识进行介绍的基础上提出了基于数字证书的校园网安全通信模型，分析了模型的逻辑结构和工作流程，并具体实现了该模型．     

V(HSO_4)_3 promoted oxidation of alcohols and trimethylsilyl,tetrahyropyranyl and methoxymethyl ethers with Cu(NO_3)_2·3H_2O in the absence of solvent

V(HSO_4)_3 has been found to be an efficient reagent for the promotion of the oxidation of alcohols and trimethylsilyl, tetrahydropyranyl and methoxymethyl ethers to their corresponding carbonyl compounds with Cu(NO_3)_2·3H_2O in the absence of solvent.