全文获取类型
收费全文 | 292篇 |
免费 | 4篇 |
专业分类
化学 | 267篇 |
力学 | 2篇 |
数学 | 7篇 |
物理学 | 20篇 |
出版年
2021年 | 2篇 |
2020年 | 2篇 |
2019年 | 3篇 |
2018年 | 3篇 |
2016年 | 4篇 |
2015年 | 2篇 |
2014年 | 1篇 |
2013年 | 2篇 |
2012年 | 8篇 |
2011年 | 18篇 |
2010年 | 3篇 |
2009年 | 4篇 |
2008年 | 7篇 |
2007年 | 4篇 |
2006年 | 3篇 |
2005年 | 5篇 |
2004年 | 3篇 |
2003年 | 5篇 |
2002年 | 2篇 |
2000年 | 1篇 |
1999年 | 2篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1996年 | 2篇 |
1994年 | 2篇 |
1991年 | 5篇 |
1990年 | 1篇 |
1988年 | 2篇 |
1987年 | 3篇 |
1984年 | 5篇 |
1979年 | 1篇 |
1978年 | 4篇 |
1977年 | 4篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1972年 | 1篇 |
1971年 | 1篇 |
1969年 | 1篇 |
1966年 | 3篇 |
1964年 | 46篇 |
1963年 | 24篇 |
1962年 | 50篇 |
1961年 | 42篇 |
1956年 | 2篇 |
1948年 | 1篇 |
1947年 | 1篇 |
1941年 | 3篇 |
1939年 | 1篇 |
1926年 | 1篇 |
1925年 | 1篇 |
排序方式: 共有296条查询结果,搜索用时 187 毫秒
1.
Dr. Ali Abdulkarim Marvin Nathusius Rainer Bäuerle Dr. Karl-Philipp Strunk Dr. Sebastian Beck Dr. Hans Joachim Räder Prof. Annemarie Pucci Dr. Christian Melzer Daniel Jänsch Dr. Jan Freudenberg Prof. Uwe H. F. Bunz Prof. Klaus Müllen 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(1):281-288
The synthesis of unsubstituted oligo-para-phenylenes ( OPP ) exceeding para-hexaphenylene—in the literature often referred to as p-sexiphenyl—has long remained elusive due to their insolubility. We report the first preparation of unsubstituted para-nonaphenylenes ( 9PP s) by extending our precursor route to poly-para-phenylenes ( PPP ) to a discrete oligomer. Two geometric isomers of methoxylated syn- and anti-cyclohexadienylenes were synthesized, from which 9PP was obtained via thermal aromatization in thin films. 9PP was characterized via optical, infrared and solid-state 13C NMR spectroscopy as well as atomic force microscopy and mass spectrometry, and compared to polymeric analogues. Due to the lack of substitution, para-nonaphenylene, irrespective of the precursor isomer employed, displays pronounced aggregation in the solid state. Intermolecular excitonic coupling leads to formation of H-type aggregates, red-shifting emission of the films to greenish. 9PP allows to study the structure–property relationship of para-phenylene oligomers and polymers, especially since the optical properties of PPP depend on the molecular shape of the precursor. 相似文献
2.
Dr. Debangshu Chaudhuri Dr. Eva Sigmund Annemarie Meyer Lisa Röck Philippe Klemm Sebastian Lautenschlager Agnes Schmid Shane R. Yost Prof. Dr. Troy Van Voorhis Dr. Sebastian Bange Prof. Dr. Sigurd Höger Prof. Dr. John M. Lupton 《Angewandte Chemie (International ed. in English)》2013,52(50):13449-13452
3.
4.
Borka Kovacevik Annemarie Wagner Johan Boman Jens Laursen Jan B. C. Pettersson 《X射线光谱测定》2011,40(4):280-288
Aerosol samples were collected at an urban background site in Skopje, Former Yugoslavic Republic of Macedonia, during four measurement campaigns from December 2006 to October 2007. An impactor was used to collect particulate matter (PM2.5) aerosol particles and the samples were analyzed for the concentrations of particulate mass, black carbon (BC), and 17 elements. The 12‐h average PM2.5 concentrations varied in the range 10–140 µg m?3 with the highest concentrations measured during wintertime pollution episodes and during the summer period. Pair‐wise correlations and crustal enrichment were studied and the data set was analyzed by factor analysis and positive matrix factorization. Major aerosol components were identified as mineral dust (main observed tracers Si, K, Ca, Ti, Fe, Sr, and Rb), combustion (BC, S, K, V, and Ni), traffic‐related aerosol (Pb and Zn), and secondary sulfate combined with mineral dust. Combustion sources dominated during wintertime and were likely due to heavy oil combustion, biomass burning, and other industrial activities within the city area. Mineral dust was observed throughout the year, but the concentrations peaked during the unusually hot and dry summer of 2007. It is concluded that Skopje suffers from serious air pollution due to central and residential heating, the transport sector, and industrial activities within the city, and contributions from mineral dust increase the PM2.5 concentrations under dry periods. Topography and meteorological conditions aggravate the problems and make the air quality comparable with the conditions in other highly polluted cities in Southern Europe and worldwide. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
5.
Annemarie Marckwordt Fatima ElOuahabi Hadis Amani Sergey Tin Narayana V. Kalevaru Paul C. J. Kamer Sebastian Wohlrab Johannes G. deVries 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(11):3524-3528
Use of ZrO2/SiO2 as a solid acid catalyst in the ring‐opening of biobased γ‐valerolactone with methanol in the gas phase leads to mixtures of methyl 2‐, 3‐, and 4‐pentenoate (MP) in over 95 % selectivity, containing a surprising 81 % of M4P. This process allows the application of a selective hydroformylation to this mixture to convert M4P into methyl 5‐formyl‐valerate (M5FV) with 90 % selectivity. The other isomers remain unreacted. Reductive amination of M5FV and ring‐closure to ?‐caprolactam in excellent yield had been reported before. The remaining mixture of 2‐ and 3‐MP was subjected to an isomerising methoxycarbonylation to dimethyl adipate in 91 % yield. 相似文献
6.
Carsten Bundesmann Thomas Lautenschläge Daniel Spemann Annemarie Finzel Michael Mensing Frank Frost 《The European Physical Journal B - Condensed Matter and Complex Systems》2017,90(10):187
The correlation between process parameters and properties of TiO2 films grown by ion beam sputter deposition from a ceramic target was investigated. TiO2 films were grown under systematic variation of ion beam parameters (ion species, ion energy) and geometrical parameters (ion incidence angle, polar emission angle) and characterized with respect to film thickness, growth rate, structural properties, surface topography, composition, optical properties, and mass density. Systematic variations of film properties with the scattering geometry, namely the scattering angle, have been revealed. There are also considerable differences in film properties when changing the process gas from Ar to Xe. Similar systematics were reported for TiO2 films grown by reactive ion beam sputter deposition from a metal target [C. Bundesmann et al., Appl. Surf. Sci. 421, 331 (2017)]. However, there are some deviations from the previously reported data, for instance, in growth rate, mass density and optical properties. 相似文献
7.
Lukas Pietzonka Thomas Lautenschläger Daniel Spemann Annemarie Finzel Jürgen W. Gerlach Frank Frost Carsten Bundesmann 《The European Physical Journal B - Condensed Matter and Complex Systems》2018,91(10):252
TiO2 thin films were grown by ion beam sputter deposition (IBSD) using oxygen ions, with the ion energy and geometrical parameters (ion incidence angle, polar emission angle, and scattering angle) being varied systematically. Metallic Ti and ceramic TiO2 served as target materials. The thin films were characterized concerning thickness, growth rate, surface topography, structural properties, mass density, and optical properties. It was found that the scattering geometry has the main impact on the film properties. Target material, ion energy, and ion incidence angle have only a marginal influence. Former studies on reactive IBSD of TiO2 using Ar and Xe ions reported equivalent patterns. Nevertheless, the respective ion species distinctively affects the film properties. For instance, mass density and the refractive index of the TiO2 thin films are remarkably lower for sputtering with oxygen ions than for sputtering with Ar or Xe ions. The variations in the thin film properties are tentatively attributed to the angular and the energy distribution of the film-forming particles, especially, to those of the backscattered primary particles. 相似文献
8.
9.
Annemarie Luger 《Mathematische Nachrichten》2006,279(8):891-910
Generalized poles of a generalized Nevanlinna function Q ∈ ??κ (??) are defined in terms of the operator representation of Q . In this paper those generalized poles that are not of positive type and their degrees of non‐positivity are characterized analytically by means of pole cancellation functions. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
10.