全文获取类型
收费全文 | 370篇 |
免费 | 10篇 |
国内免费 | 2篇 |
专业分类
化学 | 330篇 |
晶体学 | 2篇 |
力学 | 4篇 |
数学 | 30篇 |
物理学 | 16篇 |
出版年
2022年 | 3篇 |
2021年 | 6篇 |
2020年 | 6篇 |
2019年 | 5篇 |
2017年 | 5篇 |
2016年 | 3篇 |
2015年 | 11篇 |
2014年 | 6篇 |
2013年 | 29篇 |
2012年 | 14篇 |
2011年 | 17篇 |
2010年 | 6篇 |
2009年 | 10篇 |
2008年 | 28篇 |
2007年 | 27篇 |
2006年 | 23篇 |
2005年 | 20篇 |
2004年 | 22篇 |
2003年 | 22篇 |
2002年 | 13篇 |
2001年 | 4篇 |
2000年 | 3篇 |
1998年 | 4篇 |
1997年 | 5篇 |
1996年 | 6篇 |
1995年 | 3篇 |
1994年 | 3篇 |
1993年 | 4篇 |
1991年 | 6篇 |
1990年 | 3篇 |
1989年 | 3篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 4篇 |
1985年 | 4篇 |
1984年 | 3篇 |
1983年 | 2篇 |
1982年 | 5篇 |
1981年 | 3篇 |
1979年 | 4篇 |
1978年 | 11篇 |
1977年 | 2篇 |
1976年 | 1篇 |
1975年 | 4篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1972年 | 3篇 |
1970年 | 1篇 |
1969年 | 4篇 |
1955年 | 1篇 |
排序方式: 共有382条查询结果,搜索用时 415 毫秒
1.
Liang Chen Yu Fan Jieru Qiu Dr. Régis Laurent Jin Li Prof. Dr. Jérôme Bignon Prof. Dr. Serge Mignani Prof. Dr. Anne-Marie Caminade Prof. Dr. Xiangyang Shi Prof. Dr. Jean-Pierre Majoral 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(26):5903-5910
First-in-class CuII and AuIII metaled phosphorus dendrons were synthesized and showed significant antiproliferative activity against several aggressive breast cancer cell lines. The data suggest that the cytotoxicity increases with reducing length of the alkyl chains, whereas the replacement of CuII with AuIII considerably increases the antiproliferative activity of metaled phosphorus dendrons. Very interestingly, we found that the cell death pathway is related to the nature of the metal complexed by the plain dendrons. CuII metaled dendrons showed a potent caspase-independent cell death pathway, whereas AuIII metaled dendrons displayed a caspase-dependent apoptotic pathway. The complexation of plain dendrons with AuIII increased the cellular lethality versus dendrons with CuII and promoted the translocation of Bax into the mitochondria and the release of Cytochrome C (Cyto C). 相似文献
2.
3.
Queiroz Ana Luiza P. Kerins Brian M. Yadav Jayprakash Farag Fatma Faisal Waleed Crowley Mary Ellen Lawrence Simon E. Moynihan Humphrey A. Healy Anne-Marie Vucen Sonja Crean Abina M. 《Cellulose (London, England)》2021,28(14):8971-8985
Cellulose - Microcrystalline cellulose (MCC) is a semi-crystalline material with inherent variable crystallinity due to raw material source and variable manufacturing conditions. MCC crystallinity... 相似文献
4.
Quentin Vanbellingen Paul Servin Anaïs Coinaud Sonia Mallet-Ladeira Rgis Laurent Anne-Marie Caminade 《Molecules (Basel, Switzerland)》2021,26(8)
Pyridine, pyridine imine, and bipyridine imine ligands functionalized by a phenol have been synthesized and characterized, in many cases by X-ray diffraction. Several of these N-, N,N-, and N,N,N,-ligands have been grafted onto the surface of phosphorhydrazone dendrimers, from generation 1 to generation 3. The complexation ability of these monomers and dendrimers towards palladium(II) has been assayed. The corresponding complexes have been either isolated or prepared in situ. In both cases, the monomeric and dendritic complexes have been tested as catalysts in Heck couplings and in Sonogashira couplings. In some cases, a positive dendritic effect has been observed, that is, an increase of the catalytic efficiency proportional to the dendrimer generation. 相似文献
5.
6.
Anne-Marie Caminade Jean-Pierre Majoral Valérie Maraval Rosa-Maria Sebastián 《Phosphorus, sulfur, and silicon and the related elements》2013,188(6-7):1493-1497
Several series of phosphorus-containing dendrimers have been designed to study the variation of their properties, depending on the type, the location (surface, branches, core, and cavities), and the number of functions implied. 相似文献
7.
Rané Mathieu Anne-Marie Caminade Jean-Pierre Majoral 《Phosphorus, sulfur, and silicon and the related elements》2013,188(3-4)
Abstract One of the possible ways of getting phosphacumulene complexes could be the complexation of phosphinoalkynes, which might induce the migration of hydrogen from phosphorus to the β carbon of the alkynyl group. 相似文献
8.
Jean-Pierre Majoral René Mathieu Anne-Marie Caminade Serge Attali Michel Sanchez 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-2):443-446
Abstract A new entry to non classical phosphorus complexes is reported. 相似文献
9.
A. M. Caminade F. El Khatib M. Koenig 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-3):97-100
Abstract Ozone reacts quantitatively on tricoordinated and dicoordinated Phosphorus Compounds. The oxidative addition of ozone on phosphites leads to pentacoordinated or hexacoordinated phosphorus adducts. These adducts are unstable in solution. The decomposition gives the corresponding phosphoric ester with singlet oxygen evolution. In the same conditions, ozone reacts on diphosphene and gives after double bond rupture an adduct: the metaphosphonate. The relative stabilities and oxidative properties are discussed. 相似文献
10.
Clément Barrière Virginie Latour Pierre Fau Anne-Marie Caminade Cédric-Olivier Turrin 《Tetrahedron letters》2012,53(15):1908-1911
We present a simple strategy to obtain non-symmetrical polyethylene glycols equipped with telechelic phosphorus-containing dendrimeric moieties having adhesive phosphonate surface functions. The dendronized PEG tails were characterized by means of multi-nucleus NMR. The grafting abilities of model symmetrical PEG compounds equipped with telechelic amino-bis(methylene-dimethylphosphonates) and amino-bis(methylenephosphonic acids) were rapidly screened on plasma treated silicon wafers and activated silica. 相似文献