基于锚形谐振腔的等离子体波导特性研究

基于表面等离子体激元在金属-介质-金属结构中优良的传输特性,设计了一种由直波导和锚形谐振腔组成的波导滤波器。仿真分析了波导滤波器传输特性和电场分布随结构参数和谐振腔内介质折射率变化规律。结果表明,该锚形谐振腔最佳结构时滤波器半峰全宽低至8 nm,品质因数高达121.9。利用共振波长与结构参数变化规律,设计了光通信波长窗口的窄带带阻滤波器。根据SPPs对谐振腔介质折射率敏感的特性,发现透射谱线随折射率变大而发生红移。本文提出的基于锚形谐振腔的等离子体MIM波导滤波器为设计特定波长的窄带带阻滤波器提供了新思路,也为基于谱线红移特性设计的介质折射率传感器提供了技术支持。     

Synthesis and Biological Activities of 4-Arylmethylidene-1-aryl-2-（selenomorpholin-4-yl） -2-imidazolin-5-one

In a search for novel agrochemical with high activity and low toxicity, a series of substituted 4,5-dihydro-imidazol-5-one containing selenomorpholine group were synthesized by a three-step synthetic route starting from 2-azido-3-aryl-acrylic acid ethyl ester. The structures of title compounds were confirmed by ^1H NMR, IR, mass spectroscopy and elemental analysis. The preliminary bioassay against GibbereUa zeae, Fusarium oxysporum, Pellicularia sasakii, Physalospora piricola and Cercospora beticola indicated that most title compounds displayed fungicidal activity at the concentration of 50 ppm and compounds 41,4n, 40 were found to have particularly high activities against Physalospora piricola. A further in vivo test showed that compounds 41, 4n and 4o possessed better fungicidal activity against Physalospora piricola at a concentration of 100 ppm than Carbendazim. To our knowledge, this is first report that 4,5-dihy-dro-imidazol-5-one containing selenomorpholine group display fungicidal activity against Physalospora piricola.     

含1H-吡啶和噻（二）唑的新型双杂环化合物的合成及其生物活性

以苯肼、乙酰乙酸乙酯和氨基杂环为原料，合成了两类含双杂环的新型吡唑甲 酰胺衍生物，其结构经元素分析、~1H NMR，MS及IR确证。初步的生物活性测试结 果表明：部分化合物对水稻纹枯病菌、小麦赤霉病菌和苹果轮纹病菌具有良好的抑 制效果。