Hydrothermal Synthesis and Crystal Structure of a 2D Zinc（Ⅱ） Coordination Polymer with 5-Hydroxynicotinic Acid

The title compound,[Zn(5-hydroxynicotinate) 2 2H 2 O] n,has been synthesized by reacting zinc sulfate vitriol with 5-hydroxynicotinic acid under hydrothermal conditions,and its structure was determined by X-ray crystallography with the following data:monoclinic,space group C2/c,C 12 H 12 N 2 O 8 Zn,M r=377.61,a=10.223(3),b=10.319(3),c=13.613(4),β=105.922(6)°,Z=4,V=1380.9(8)3,F(000)=768,D c=1.816 g/cm 3,μ(MoKα)=1.826 mm-1,the final R=0.0401 and wR=0.1380 for 1157 observed reflections (I > 2σ(I)).In the structure of the title compound,the Zn II ion located in an inversion center lies in a distorted tetrahedral environment at a N 2 O 2 coordination mode,and the 5-hydroxynicotinic acid ligand links symmetry-related Zn II ions at a μ 2-N,O bridging way forming a two-dimensional covalent structure.In the crystal,solvent water molecules form intermolecular O-H O hydrogen bonds and pyridine rings of adjacent layers form π-π stacking (3.346),which connect adjacent two-dimensional sheets into a three-dimensional supramolecular network.     

关于Q（√4k^2n＋1）的理想类群的循环子群

设ｄ,ａ,ｋ,ｎ是适合４ｋ＾２ｎ＋１＝ｄａ＾２,ｋ〉１,ｎ〉２,ｄ无平方因子的正整数;又设Ｃ（Ｋ）和ｈ（Ｋ）分别是实二次域Ｋ＝Ｑ（√ｄ）的理想类群和类数。本文证明了：当ａ〈０．５ｋ＾０．５６ｎ时,则ｈ（Ｋ）≡０（ｍｏｄ ｎ）和Ｃ（Ｋ）必有ｎ阶循环子群。     

二维配位聚合物[K2(5-nbdc)2Cd(Ⅱ)·imH·H2O]∞的合成和晶体结构(英)

The crystal structure of the title complex, [K₂(5-nbdc)₂Cd(Ⅱ)·imH·H₂O]_∞ (5-nbdc=5-nitro-1,3-benzenedicarbonate, imH=imidazole) has been determined by X-ray diffraction analysis. The crystal data are: tetragonal, space group P4₁, M_r=694.93 for CdC₁₉H₁₂N₄O₁₃K₂, a=1.018 6(10) nm, b=1.018 6(10) nm, c=2.436 7(5) nm; Z=4, V=2.528 2(6) nm³, F(000)=1 376, D_c=1.826 Mg·m^-3, μ=1.267 mm^-1. The title polymeric complex exhibits a two-dimensional framework, in which adjacent Cd(Ⅱ) ions are bridged by μ-O₄-5-nitro-1,3-benzenedicarbonate groups forming one-dimensional chains that are further linked by μ-O₃-5-nitro-1,3-benzenedicarbonate groups into two-dimensional anion rectangle sheets with large 32-membered rings. The strong π-π stacks of the benzene rings link these adjacent sheets into a three-dimensional van der Waals network. CCDC: 245527.     

S—系统的赋值与值位

本文给出赋值Ｎｅａｒ－环，Ｓ－系统赋值与Ｆ－位值的定义，并分别对Ｓ－系统的赋值和值伴进行了研究，从而得出Ｓ－系统的等价赋值类和赋值Ｎｅａｒ－环之间的对应关系以及等价的值位类和赋值Ｎｅａｒ－环之间的对应关系。     

实二次域Q(P(1/2))(p≡3(mod 4))类数的上界

设p是适合p≡3（Pod4）的奇素数,h,ε分别是实二次域Q的类数和基本单位．本文运用初等方法证明了：εh＜（p+a+2)a+2/4(a+2)!,其中     

1,10-邻啡啰啉取代的希夫碱配体及其双核配合物的合成

Recentstudyattentionsoncoordinationchem-istryhavebeendevotedtothedesignandsynthesisofmulti-dentateligandswithlarge仔-conjugationsystemsastheirabilitiesonintramolecularelectro/energy-transferevenifmostreportedligandscontainonlyonetypeofcoordinationsite(suc…     

1,10-邻啡啰啉取代的希夫碱配体及其双核配合物的合成(英)

A new ligand N, N′-Bis(salicyidene)-5,6-phenanthrolinenediamine (H₂L) 1 and its four binuclear complexes [M²⁺LM²⁺(B^-)₂]( M=Cu²⁺, B^-=Ac^-, 1a; M=Ni²⁺, B^-=Ac^-, 1b; M=Co²⁺, B^-=Cl^-, 1c; M=Ni²⁺, B^-=Cl^-, 1d) have been prepared by condensing 1 equiv. of 5,6-diamino-1,10-Phenanthroline with 2 equiv. of 2-hydroxybenzaldehyde and reaction of 1 with metal salts, and characterized by IR, ¹H and ¹³C NMR, UV-Vis and EI-MS analysis.     

关于Q(√/4k2x+1)的理想类群的循环子群

设d,a,k,n是适合4k2n+1 =da2, k>1, n>2, d无平方因子的正整数;又设C(K)和h(K)分别是实二次域K=Q(√d)的理想类群和类数.本文证明了:当a<0.5k0.56n时,则h(K)≡0(mod n)和C(K)必有n阶循环子群.     

S－系统的赋值与值位

本文给出赋值Ｎｅａｒ─环，Ｓ─系统赋值与Ｆ─位值的定义，并分别对Ｓ─系统的赋值和值位进行了研究，从而得出Ｓ─系统的等价赋值类和赋值Ｎｅａｒ─环之间的对应关系以及等价的值位类和赋值Ｎｅａｒ─环之间的对应关系。     

二维配位聚合物[K_2(5-nbdc)_2Cd(Ⅱ)·imH·H_2O]_∞的合成和晶体结构(英文)

In recentyears,asym m etric organic ligands (suchas m 鄄pyridinecarboxylates) have been used as bi/tri鄄dentate bridges to build chiral coordination polym ersofCd髤orZn髤forexploring non鄄linearopticalm ate鄄rials[1]. In these reported coordination polym