柴油溶剂中脂肪酶催化高酸值废油脂酯化制备生物柴油

采用0＃柴油作为反应溶剂,利用固定化脂肪酶催化高酸值废油脂与甲醇酯化反应制备生物柴油。来源于Candida antarctica的固定化脂肪酶Novozym435在0＃柴油溶剂中具有极高的催化活性。以酸价高达157×10-3的废油脂为原料,废油脂质量比10%的Novozym435,甲醇与废油脂初始摩尔比2∶1,0＃柴油与废油脂质量比5∶1,摇床摇速170r/min,50℃下反应2h甲酯化率可达95.10%。0＃柴油作为反应溶剂有效地溶解了高酸值废油脂和甲醇,降低了反应体系的黏度和消除了甲醇对Novozym435的负面影响,提高了Novozym435的稳定性。同时,0＃柴油溶剂对未脱胶废油脂中残留的对脂肪酶有害的磷脂等胶类物质具有一定的稀释作用。该工艺省却了溶剂蒸馏的繁琐工序,直接得到脂肪酸甲酯和石化柴油的混合燃料。     

量子等离子体中波的色散关系以及朗道阻尼

利用动理学理论研究量子等离子体中波的色散关系和电子朗道阻尼.从电子的量子流体动力学方程和动理学描述下的光子运动方程出发,研究量子效应对光子朗道阻尼的修正.研究发现量子效应只对纵波模式,即电子等离子体波的色散关系有修正,对横向电磁波的色散关系没有影响.量子效应减小了朗道阻尼,起着朗道增长的作用. 关键词： 量子等离子体 朗道阻尼 电子等离子体波 色散关系     

对称二醇的选择性乙酰化及其在昆虫性信息素合成中的应用

α、ω-烷二醇的单保护衍生物是合成昆虫性信息素、前列腺素等天然产物的重要中间体。有关它的合成方法的研究,已引起了人们广泛的兴趣。1979年,James 等人首次报道了用连续抽提法进行对称二醇的选择性单酰化反应,并指出反应体系中水的用最是影响反应选择性的关键。然而,我们按文献[7]的配比多次重复,产率仅在50%左右,单酰化产物与双酰化产物之比小于10∶1。我们在文献[7]的基础上,采用经典的液-液提取法,用硫酸作催化剂,提高反应温度     

Synthesis,Crystal Structure and Bioactivity of N-Phenethyl-4-hydroxy-4-phenyl Piperidine Hydrochloride

A novel compound N-phenethyl-4-hydroxy-4-phenyl piperidine hydrochloride （C19H24ClNO·H2O） has been synthesized and structurally characterized by elemental analysis, IR, ^1H NMR spectra and single-crystal X-ray diffraction. The crystal belongs to orthorhombic, space group P212121 with a = 8.6306（8）, b = 11.0464（10）, c = 19.3221（18）A^°, V = 1842.1（3）A^°^3, Z = 4, Dc =1.211 g/cm^3,μ = 0.217 mm^-1, Mr= 335.86, F（000） = 720, S = 0.973, R = 0.0420 and wR = 0.1009 for 3627 unique reflections with 3157 observed ones （I 〉 2σ（I））. In the crystal, the dihedral angles made by piperidine ring with two benzene rings are 84.8（6） and 62.5（7）°, respectively. Intermolecular O-H…O and O-H…Cl hydrogen bonds involving water molecules form chains along the b axis, which stabilizes the crystal structure. The preliminary bioactivity tests indicated that the title compound has good effect of cellular growth inhibition to K562 cells and potential bioactivity of anti-leukemia.     

Modification of gravitational redshift of x-ray burst produced by pulsar surface magnetoplasma

In this paper, the propagation of x-ray bursts in the magnetoplasma of pulsar magnetosphere is discussed. The electromagnetic interaction between x-ray bursts and magnetoplasma is described as some geometry. The electromagnetic effects of surface superstrong magnetic field and dynamic effects of outflowing magnetoplasma of pulsars are treated as an optical metric. The Gordon metric is introduced to represent the gravitational metric and optical metric. So the propagation of x-ray bursts in magnetoplasma of pulsars can be described as x-ray bursts transmitting in an effective space characterized by Gordon metric. The modification of gravitational redshift, attributed to the flowing magnetoplasma of pulsars, is obtained and it is shown that the modification is of redshift and can reach the same magnitude as the gravitational redshift for ordinary pulsars.     

Syntheses and Crystal Structures of 1,5-Disubstituted 1,3,5-Hexahydro-triazine-2-（N-nitro）imines

The title compounds,C9H13ClN6O2S 1 and C15H17ClN6O2S 2,were synthesized and structurally characterized by elemental analysis,IR,1H NMR spectra and single-crystal X-ray diffraction.Compound 1 is in the monoclinic system,space group P21/c with a=13.7711(5),b=10.3883(4),c=9.7623(2),V=1344.47(8)3,Dc=1.506 g/cm3,C9H13ClN6O2S,Mr=304.76,F(000)=632,μ=0.448 mm-1,Z=4,S=1.084,R=0.0497 and wR=0.1328 for 2640 unique reflections(Rint=0.0787) with 2089 observed ones(I2σ(I)).Compound 2 belongs to the monoclinic system,space group P21/n with a=8.3828(5),b=14.5285(7),c=14.2456(4),V=1729.74(14)3,Dc=1.462 g/cm3,C15H17ClN6O2S,Mr=380.86,F(000)=792,μ=0.364 mm-1,Z=4,S=1.057,R=0.0598 and wR=0.1582 for 3384 unique reflections(Rint=0.0469) with 2833 observed ones(I2σ(I)).Compounds 1 and 2 are homologues and stabilized by intermolecular and intramolecular hydrogen bonds.Moreover,compound 2 containing C(2)-H(2)…π(thiazole) interaction is more stable than 1.     

殊途同归 择优而行——以“一题多解”为例浅谈数学物理方法课程思政

数学物理方法课程是物理学专业和部分工科专业重要的基础课，在数学物理方法课程中融入课程思政，是新时期落实立德树人教育根本目标的必要之举。基于数学物理方法课程教学内容和知识体系的特点，该课程开展思政建设的重点在于提高学生的科学思维意识、辩证思维能力和创新能力。本文我们以教学内容中经典例题的“一题多解”为引，以“殊途同归择优而行”为切入点，浅谈在数学物理方法课程思政建设中的一些思考和教学实践。     

“格物致理、慎思笃行”——数学物理方法课程教学改革、创新与实践

山西大学数学物理方法课程团队在教学各环节尝试改革创新.教学理念创新以满足培养创新型拔尖人才的目标,教学内容改革以体现该课程“承上启下”的作用,教学内容重组创新以面向国家开展量子科技研究的重大需求,教学模式创新以实现“以学生为中心”,教学手段创新实现数学、物理相互融合,客观有效的教学评价以保障教学质量、提高教学效果,课程思政与教研融合,实现“春风化雨、润物无声”.