排序方式: 共有12条查询结果,搜索用时 15 毫秒
1.
3.
4.
From Wide-Angle X-ray Scattering (WAXS) pattern of uniaxially orientated fibers, the crystal structure of Nylon-1010 was determined. The Nylon-1010 crystallizes in the triclinic system, with lattice dimensions: a=4.9A, b=5.4A, c=27.8, α=49 °, β=77 °,γ=63.5 °, the unit cell contains one monomeric unit and the space group is P. The degree of crystallinity of polymer was deter mined as about 60%, using Ruland's method.The structures of Nylon-1010 with different draw ratio have been investigated by using Small-Angle X-ray Scattering (SAXS). The results indicate that the draw ratio of samples has a significant effect on microstructure of Nylon-1010. The long period and thickness of amorphous layer obviously increase but the invariant, average lameUar and interphase zone show almost independent of draw ratio, long period increases because amorphous layer increases with draw ratio. The electron density fluctuation values increased with draw ratio, but inner surface O_s is drecreased. 相似文献
5.
6.
7.
热处理对尼龙1010结构影响研究 总被引:2,自引:0,他引:2
采用WAXD,SAXS方法研究了热处理对尼龙1010聚集态结构的影响.结果表明,在温度为175℃左右对样品进行退火处理可获得较完善的结晶.利用Wc.x~T关系曲线外推法得到尼龙1010样品的Tg大约为58℃.根据一维电子密度相关函数法求得了系列样品在所研究条件下的结晶片层厚,过渡层厚,长周期和结晶非晶相间的密度差.得到了不同退火条件尼龙1010样品的结晶相密度ρc. 相似文献
8.
Based on the X-ray scattering intensity theory and using the atomic scattering factorapproximate expression,the correction factors for three main crystalline peaks and an amorphouspeak of Nylon-1010 were calculated and the formula of degree of crystallinity of Nylon-1010 wasderived by graphic multipeak resolution method. The results calculated are compatible with the density measurement and calorimetry. 相似文献
9.
10.
The structural parameters of the aggregated state of polyamide (PA)-1010 annealedat various temperatures were computed by means of the desmearing intensity from SmallAngle X-ray Scattering (SAXS) measurements and by using the concept of the distance dis-tribution function. The results indicated that the structural parameters of the aggregatedstate were strongly dependent upon heat treatment conditions and the maximum valuesof the structural parameters were obtained for the samples annealed at T = 175℃. Theparticle size Z annealed at different temperature was ranged between 8.1--12.8nm, and thevalues of the distance distribution function P_(max)(Z) were obtained when Z = 4.0--6.8nm.Using one dimension electron density correlation function (1D EDCF) method long period(L) and thickness of the lamellar (d_0) were estimated and were found to increase with theincrease of the degree of crystallinity. 相似文献