基于氦离子化气相色谱法测定微量氧、氮的影响因素

探讨氦离子化气相色谱法测定样品中微量氧、氮含量的影响因素。采用控制变量法,对色谱柱温度、进样流量、进样管道环境及极化电压等因素对微量氧、氮测定结果的影响进行讨论和分析。结果表明,当色谱柱温度为25~45℃时,色谱柱对氧、氮吸附量最小;当进样流量不小于70 mL/min时,微量氧、氮测定结果受外界干扰最小;当极化电压为80~160 V时,氧、氮具有最佳的响应值;初次测定样品中微量氧、氮含量时,需使进样管道表面吸附的氧、氮处于饱和状态,以便获得理想的测定结果。讨论的结果可为氦离子化气相色谱法测定相关样品中微量氧、氮含量时提供技术参考。     

Excess 3H in the volcanic lakes: evidence for natural nuclear fusion

The excess ³H (tritium) have been observed in the volcanic lakes Nemrut (Turkey), Laacher (Germany) and Pavin (France). The ⁴He and ³He concentrations in Lakes Nemrut, Laacher, and Pavin were determined to be 25 and 190, 10 and 50, and 70 and 500 times larger than the atmospheric saturation value respectively. The isotopic ratio of the helium excess, ³He_ex/⁴He_ex, in Lakes Nemrut, Laacher and Pavin was (1.032±0.006)×10^－5, (7.42±0.03)×10^－6 and (9.09±0.01)×10^－6 respectively. The ³He/⁴He ratio of helium isotopes in the lake can help us to identify the origin of gas fluxes from the interior of the Earth. The ³He/⁴He ratios in the Lakes Nemrut, Laacher and Pavin clearly indicate that a large amount of helium isotopes were released to the lakes from mantle source. The excess ³H at the bottom of Lakes Nemrut, Laacher and Pavin have a good correlation with mantle ³He. We consider that the excess ³H might be also released from mantle source and both ³H and ³He might be produced by nuclear fusion (d-d reaction) in an environment rich in H atoms and (U+Th) at high temperature and high pressure condition in deep Earth.