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The title compound of Cu(C14H9O3)2(C5H5N)2(C2H5OH)2(1) was synthesized via the hy- drothermal reaction of CuCl2·2H2O and 9-hydroxy-fluorene-9-carboxylic acid(HHF) with pyridine, and characterized by elemental analysis and infrared spectra. The crystal belongs to triclinic, space group P1 with a = 8.8302(12), b = 10.1625(14), c = 12.2708(17), α = 86.207(2), β = 69.562(2), γ = 64.932(2)o, V = 930.3(2) 3, Z = 1, Mr = 764.30, Dc = 1.364 g/cm3, F(000) = 399, S = 1.059 and μ(MoKα) = 0.644 mm-1. The final R = 0.0459 and wR = 0.1274 for 3414 observed reflections with I 2σ(I). The copper atom is six-coordinated by two oxygen atoms from two different 9-hydroxy-fluorene-9-carboxylate ligands, two pyridine nitrogen atoms and two ethanol oxygen atoms, forming a distorted octahedral coordination geometry. The extensive O–H···O hydrogen bonding connects the molecules to form a one-dimensional chain structure. Between adjacent one-dimensional chains, a two-dimensional layered structure was formed by fluorene ring π-π packing interaction. Between the layers, a three-dimensional structure was formed through the π-π packing interaction of the pyridine ring. Moreover, the thermal stability and photoluminescent property of the complex has been investigated. 相似文献
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中阶梯光栅是一种特殊的衍射光栅, 它以高的衍射级次和大的衍射角来工作, 具有高分辨率、全波闪耀等特性。已广泛应用于高端光谱仪器之中,极大地促进了航天航空、天文、医疗、军事、环境等尖端科技的发展。但是专业的刻划系统需要定制,价格昂贵。使用已成熟的超精密加工设备来加工中阶梯光栅,可以大大降低中阶梯光栅母版的制备成本。超精密单点金刚石车床制备中阶梯光栅时,系统直线度不好,存在较大的累积误差,导致中阶梯光栅衍射波前较差,达不到制备要求。为了减小超精密单点金刚石车床固有的直线度误差,对超精密单点金刚石车床进行了误差补偿。首先,以累积误差曲线为依据进行第一次补偿。实验结果表明,当补偿系数为0.75~0.85时,此时衍射波前的PV(峰谷值)值在约400 nm,一次直线度补偿效果到达极限。然后,以闪耀级的衍射波前曲线为依据进行第二次直线度补偿,二次补偿后的衍射波前PV值为约83 nm。补偿后的结果表明衍射波前得到大幅改善,有利于提高所制备光栅的质量,在光栅实际刻划中具有指导作用。 相似文献
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