微波消解电感耦合等离子体质谱法测定桃中稀土元素及其分布

以市场销售的桃为实验材料,利用微波消解电感耦合等离子体质谱法(ICP-MS)同时测定桃中稀土元素的含量。样品经过硝酸-氢氟酸-双氧水微波消解,实现了桃中16种稀土元素的测定。各元素的检出限在0.004~0.020μg·g-1之间,方法精密度在0.78%~2.96%,回收率在95.0%~106.0%之间。比较了稀土元素在果皮和果肉中的分布。结果表明,稀土元素在果皮中的含量明显高于果肉。本法快速、准确,可用于桃等水果中稀土元素的测定。     

酸溶-碱提取-硫氰酸盐分光光度法测定岩石矿物中的钼含量

<正>钼在地壳中的质量分数约为3μg·g~(-1),自然界中已知的含钼矿物约有30余种~([1]),目前岩石矿物中钼的测定方法主要有重量法~([2])、容量法~([3])、分光光度法~([4-6])、原子吸收光谱法~([7-9])、电感耦合等离子体质谱法~([10-12])和电感耦合等离子体原子发射光谱法~([13-15])等。重量法和容量法操作繁琐,仅适用于钼     

啁啾相移光纤光栅分布式应变与应变点精确定位传感研究

利用啁啾相移光纤光栅狭缝的中心波长对应变点和应变量的波长敏感性,实现应变与应变点精确定位的传感.当啁啾光纤光栅上的某一位置产生微应变时,该应变点会产生相移,其频谱则会出现一个与之对应的狭缝,且狭缝的深度和中心波长与应变的大小和位置相关.当串接不同中心波长的啁啾光纤光栅后,即可实现一定范围内的分布式应变与应变点精确定位检测.本文通过V-I传输矩阵法建立了狭缝深度和中心波长关于应变量和应变位置的理论模型,分析结果表明理论上可以实现微米量级的精确定位.搭建了级联啁啾相移光纤光栅的分布式应变传感装置,实验获得的最大应变灵敏度为0.19 pm/με.该精确定位传感装置在先进制造、精密加工、航空航天、铁路系统等高新技术领域具有重要的应用前景.     

Spectral analysis of the UFBG-based acousto optical modulator in V–I transmission matrix formalism

In this study, the V-I transmission matrix formalism （V-I method） is proposed to analyze the spectrum characteristics of the uniform fiber Bragg grating （FBG）-based acousto--opfic modulators （UFBG-AOM）. The simulation results demon- strate that both the amplitude of the acoustically induced strain and the frequency of the acoustic wave （AW） have an effect on the spectrum. Additionally, the wavelength spacing between the primary reflectivity peak and the secondary reflectivity peak is proportional to the acoustic frequency with the ratio 0.1425 nm/MHz. Meanwhile, we compare the amount of calculation. For the FBG whose period is M, the calculation of the V-I method is 4 × （2M-l） in addition/subtraction, 8 × （2M - 1） in multiply/division and 2M in exponent arithmetic, which is almost a quarter of the multi-film method and transfer matrix （TM） method. The detailed analysis indicates that, compared with the conventional multi-film method and transfer matrix （TM） method, the V-I method is faster and less complex.     

Intensity detecting refractive index sensors with long-period fiber gratings written in STS structure

A refractive index intensity detecting sensor with long-period grating written in the single-mode–thin-core–single-mode fiber(STS) structure is proposed and optimized theoretically. The sensor is composed of two single-mode fibers connected by a section of long-period fiber grating fabricated on thin-core fiber. After optimization and benefitting from the phase matching point, the loss peak of the structure can reach 62.8 d B theoretically. The wavelength of the characteristic peak is fixed at the phase matching point, so intensity detection can be achieved. The sensitivity can reach 272.5 d B/RIU. The structural optimization in this Letter provides a reference for the fabrication of an easy-made all-fiber sensor without extra cladding.     

基于光纤叠栅的全光纤声光可调谐滤波器的特性分析

本文提出了一种基于光纤叠栅的全光纤声光可调谐滤波器, 与普通光纤布拉格光栅型全光纤声光可调谐滤波器相比, 该滤波器能够对光纤叠栅的两个中心波长进行同步调制. 理论分析了声波频率和声致应变幅度对基于光纤叠栅的全光纤声光可调谐滤波器的传输光谱的影响, 结果表明, 各阶次反射峰分别以两个主反射峰为中心呈对称关系, 且主反射峰与其所调制出的次反射峰之间的波长间隔与声波频率成正比, 而两个主反射峰所调制出的同阶次反射峰之间的波长间隔与声波频率无关; 声致应变幅度主要影响主反射峰及次反射峰的反射率的变化. 实验中, 分别测试声波频率为390 kHz和710 kHz的基于光纤叠栅的全光纤声光可调谐滤波器的传输光谱, 实验结果的变化趋势与仿真分析结果相一致.