Filter-radiometer-based realization of candela and establishment of photometric scale at UME

The luminous intensity unit of candela was realized based on filter-radiometer, which is traceable to detector-based primary standard electrical substitution cryogenic radiometer (ESCR). In that realization the traditional Osram Wi41/G-type incandescent lamp and filter-radiometer consisting of an aperture, a V(λ) filter and a silicon photodiode based trap detector were used as light source and detection element, respectively. Measurement techniques of effective aperture area, spectral transmittance of V(λ) filter and absolute responsivity of trap detector are also presented.     

New glyoxime derivatives and their transition metal complexes

Two new vic-dioxime ligands and their complexes with Co⁺², Ni⁺², Cu⁺², Cd⁺², and Zn⁺² ions were synthesized. Primer amines (3,4-methylenedioxaaniline and 4-methylbenzylamine) reacted with antichloroglyoxime to give 3,4-methylenedioxaphenylaminoglyoxime (H₂L¹) and N-(4-methylbenzyl)aminoglyoxime (H₂L²) ligands. Structures of the ligands and their complexes are proposed based on elemental analyses, IR, UV-Vis, and ¹H NMR spectra, magnetic susceptibility measurements, and thermogravimetric analyses (TGA). The article was submitted by the authors in English.     

Synthesis of N-(4′-Benzo[15-crown-5])biphenylaminoglyoxime and Its Complexes with Some Transition Metals

N-(4-Benzo[15-crown-5])biphenylaminoglyoxime (H₂L) and sodium chloride salt of N-(4-benzo[15-crown-5])biphenylaminoglyoxime (H₂L · NaCl) have been prepared from 4-biphenylchloroglyoxime, 4-aminobenzo[15-crown-5], and sodium bicarbonate and sodium chloride. Nickel(II), cobalt(II), and copper(II) complexes with H₂L and H₂L · NaCl have a metal–ligand ratio of 1 : 2 and the ligand coordinates through the two N atoms, as do most of the vic-dioximes. Their IR spectra and elemental analyses are given, together with ¹H NMR spectra of the ligands.     

A constructive approach to examination timetabling based on adaptive decomposition and ordering

In this study, we investigate an adaptive decomposition and ordering strategy that automatically divides examinations into difficult and easy sets for constructing an examination timetable. The examinations in the difficult set are considered to be hard to place and hence are listed before the ones in the easy set in the construction process. Moreover, the examinations within each set are ordered using different strategies based on graph colouring heuristics. Initially, the examinations are placed into the easy set. During the construction process, examinations that cannot be scheduled are identified as the ones causing infeasibility and are moved forward in the difficult set to ensure earlier assignment in subsequent attempts. On the other hand, the examinations that can be scheduled remain in the easy set. Within the easy set, a new subset called the boundary set is introduced to accommodate shuffling strategies to change the given ordering of examinations. The proposed approach, which incorporates different ordering and shuffling strategies, is explored on the Carter benchmark problems. The empirical results show that the performance of our algorithm is broadly comparable to existing constructive approaches.     

Split‐type octonion matrix

The split and hyperbolic (countercomplex) octonions are eight‐dimensional nonassociative algebras over the real numbers, which are in the form , where e_m's have different properties for them. The main purpose of this paper is to define the split‐type octonion and its matrix whose inputs are split‐type octonions and give some properties for them by using the real quaternions, split, and hyperbolic (countercomplex) octonions. On the other hand, to make some definitions, we present some operations on the split‐type octonions. Also, we show that every split‐type octonions can be represented by 2 × 2 real quaternion matrix and 4 × 4 complex number matrix. The information about the determinants of these matrix representations is also given. Besides, the main features of split‐type octonion matrix concept are given by using properties of  real quaternion matrices. Then, 8n × 8nreal matrix representations of split‐type octonion matrices are shown, and some algebraic structures are examined. Additionally, we introduce real quaternion adjoint matrices of split‐type octonion matrices. Moreover, necessary and sufficient conditions and definitions are given for split‐type octonion matrices to be special split‐type octonion matrices. We describe some special split‐type octonion matrices. Finally, oct‐determinant of split‐type octonion matrices is defined. Definitive and understandable examples of all definitions, theorems, and conclusions were given for a better understanding of all these concepts.     

Automated generation of constructive ordering heuristics for educational timetabling

Annals of Operations Research - Construction heuristics play an important role in solving combinatorial optimization problems. These heuristics are usually used to create an initial solution to the...     

Structural characterization of dodecyltrimethylammonium (DTMA) bromide modified sepiolite and its adsorption isotherm studies

In this study, dodecyltrimethylammonium (DTMA) bromide was used to modify natural sepiolite via an ion exchange reaction to form DTMA-sepiolite. Sepiolite and DTMA-sepiolite were then characterized by using Brunauer–Emmett–Teller (BET), elemental analysis, XRD, FT-IR, thermogravimetric (TG) and zeta potential analysis techniques. The BET surface area of sepiolite significantly decreased from 152.14 m² g^–1 to 88.63 m² g^–1, after the modification, due to the coverage of the pores of sepiolite. DTMA was located onto sepiolite according to the differential thermogravimetric (dTG) peaks of DTMA-sepiolite. XRD results confirmed the interaction between DTMA⁺ cations and sepiolite. FT-IR spectra indicated the existence of DTMA functional groups on sepiolite surface. After the characterization was accomplished, adsorption isotherm studies of naphthalene, which is the first member of the polycyclic aromatic hydrocarbons (PAHs), were carried out. The maximum adsorption capacity of DTMA-sepiolite for naphthalene was determined from Langmuir isotherm equation at pH 6 and 20 °C as 1.88 × 10^–4 mol g^?1 or 24.09 mg g^?1.     

Synthesis, characterization, thermal and optical properties of styrene derivatives having pendant p-substituted benzylic ether groups

The derivatives of styrene monomer, 4-chlorophenyl-4-vinylbenzyl ether (M1), 4-methoxyphenyl-4-vinylbenzyl ether (M2), 4-ethylphenyl-4-vinylbenzyl ether (M3) and 1-naphtylphenyl-4-vinylbenzyl ether (M4) were synthesized. The normal free radical polymerization of monomers in 1,4-dioxane were performed by using 2,2′-azobisisobutyronitrile as an initiator at 65 °C. The monomers and their homopolymers were characterized by FT-IR, NMR and elemental analyses measurements. The thermal stability of polymers was investigated by thermogravimetric and differential scanning calorimetric analysis. Thermal degradation activation energies of the polymers were calculated by the Ozawa and Kissinger methods. In addition, photo-stability tests of the polymers under near-UV irradiation were performed.     

Synergistic Effect of Lithium Perchlorate and Sodium Hydroxide in the Preparation of Electrochemically Treated Pencil Graphite Electrodes for Selective and Sensitive Bisphenol A Detection in Water Samples

In this study, pencil graphite electrodes were activated electrochemically in the presence of different supporting electrolytes and used for the selective and sensitive determination of bisphenol A (BPA) in water samples. Synergistic effects of both LiClO₄ and NaOH supporting electrolytes on the performance of the electrochemically treated pencil graphite electrode (ETPGE) were demonstrated in the oxidation of BPA. The electrochemical behavior of BPA on the ETPGE showed two irreversible oxidation peaks at 0.744 V and 0.877 V (vs. SCE). The detection limit was determined to be 3.1 nM. This single‐use electrode is a very promising candidate to overcome the passivation problems arising from the oxidation of BPA. The analytical application of the ETPGE was performed in tap and river water samples.     

Cryogenic radiometer based absolute spectral power responsivity calibration of integrating sphere radiometer to be used in power measurements at optical fiber communication wavelengths

This paper covers the absolute spectral power responsivity calibration of spectralon-coated Integrating Sphere Radiometer (ISR) equipped with 3 mm diameter InGaAs photodiode to be used as a transfer standard in fiber optic power measurements against Electrical Substitution Cryogenic Radiometer (ESCR) in Optics Laboratory of National Metrology Institute (TUBITAK UME) of Turkey. The initial uncertainty arising from the use of the Electrically Calibrated Pyroelectric Radiometer (ECPR) as a transfer standard in radiometric scale is 0.5% (k=2), which particularly comes from irregularity in the surface homogeneity of ECPR. In order to eliminate the ECPR step as well as its initial uncertainty contribution in fiber optic power measurements, the calibration application herein was carried out. Moreover power stabilization measurements of DFB laser sources at both 1309.1 nm and 1549.0 nm, the beam size determinations, and spectral analyses of these laser sources as well as spatial and angular dependence of spectral responsivities of the ISR were presented in this paper. The total expanded uncertainties were calculated as 0.283% and 0.315% in the determination of absolute spectral power responsivities of the ISR for 1309.1 nm and 1549.0 nm wavelengths respectively (k=2).