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排序方式: 共有71条查询结果,搜索用时 93 毫秒
1.
Haas P Hempstead M Jensen T Kagan H Kass R Behrends S Gentile T Guida JM Guida JA Morrow F Poling R Rosenfeld C Thorndike EH Tipton P Besson D Green J Namjoshi R Sannes F Skubic P Stone R Bortoletto D Chen A Goldberg M Horwitz N Jawahery A Lubrano P Moneti GC Trahern CG van Hecke H Csorna SE Garren L Mestayer MD Panvini RS Word GB Yi X Alam MS Bean A Ferguson T Avery P Bebek C Berkelman K Blucher E Cassel DG Copie T DeSalvo R DeWire JW Ehrlich R Galik RS Gilchriese MG Gittelman B Gray SW 《Physical review letters》1985,55(12):1248-1251
2.
Chemosensors for the marine toxin saxitoxin 总被引:1,自引:0,他引:1
Gawley RE Pinet S Cardona CM Datta PK Ren T Guida WC Nydick J Leblanc RM 《Journal of the American Chemical Society》2002,124(45):13448-13453
Eleven anthracylmethyl crown ethers have been synthesized and evaluated as fluorescence sensors for the marine toxin saxitoxin. Fluorescence enhancement data are consistent with a 1:1 binding complex for all crowns. The binding constants are in the range of 10(4) M(-)(1) in ammonium phosphate buffer (pH 7.1) in 80% ethanol solvent. Selectivity for sensing saxitoxin versus several organic analytes has been demonstrated for the first time. Possible modes of binding are presented, and relevance to saxitoxin monitoring programs are discussed. 相似文献
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4.
M. Guida 《Journal of Pure and Applied Algebra》2007,208(2):603-615
In this paper we compute the generators, the Hilbert function, and the Hilbert polynomial of the projective closure of affine lines which are parallel to the coordinate axes and pass through a lattice of points. We also consider the Cohen-Macaulay and seminormality property of their homogeneous coordinate ring. These lines are said to form a grid. 相似文献
5.
A theoretical investigation of friction-induced self-excited oscillations for systems with one degree of freedom is proposed.
The friction force is assumed as an odd function of the relative sliding velocity with a jump discontinuity at a value of
zero for the relative sliding velocity. The friction characteristic is approximated with a piecewise linear function, i.e.
straight line segments with a suitable slope. For the generic system belonging to the class in question, the stick-slip instability
region is located on a suitable dimensionless map.
Sommario Viene proposta un'indagine teorica sulle oscillazioni autoeccitate indotte dall'attrito per sistemi ad un grado di libertà. La forza d'attrito viene assunta come funzione dispari della velocità relativa tra le superfici accoppiate, con una discontinuità di prima specie in corrispondenza del valore nullo della velocità. La caratteristica d'attrito viene approssimata mediante una funzione lineare a tratti con segmenti di opportuna pendenza. Per il generico sistema appartenente alla classe in esame, si perviene all'individuazione, su opportuna mappa adimensionale, della regione di instabilità da stick-slip.相似文献
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8.
G. Chevrier J. M. Kiat J. Guida A. Navaza 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(7):i59-i62
Crystals of barium pentacyanonitrosylferrate trihydrate (barium nitroprusside trihydrate), Ba[Fe(CN)5(NO)]·3H2O, have been studied by neutron diffraction in order to examine the structural behaviour of the compound in the 20–120 K temperature range and to determine the structure at 105 K. The results show the existence of a new crystal phase of the compound at 80 K (with a duplicated a parameter), which still exists at 20 K. The crystal structure at 105 K shows a rearrangement of the water molecules, which results in an ordered structure with P1 symmetry. Two of the four independent nitroprusside cations are rotated by 4.5° around the [100] direction. 相似文献
9.
Susana H. Tarulli Oscar V. Quinzani Prof. Dr. Sandra D. Mandolesi Jorge A. Guida Gustavo A. Echeverría Oscar E. Piro Eduardo E. Castellano 《无机化学与普通化学杂志》2009,635(11):1604-1612
A series of palladium(II) thiosaccharinates with triphenylphosphane (PPh3), bis(diphenylphosphanyl)methane (dppm), and bis(diphenylphosphanyl)ethane (dppe) have been prepared and characterized. From mixtures of thiosaccharin, Htsac, and palladium(II) acetylacetonate, Pd(acac)2, the palladium(II) thiosaccharinate, Pd(tsac)2 (tsac: thiosaccharinate anion) ( 1 ) was prepared. The reaction of 1 with PPh3, dppm, and dppe leads to the mononuclear species Pd(tsac)2(PPh3)2 · MeCN ( 2 ), [Pd(tsac)2(dppm)] ( 3 ), Pd(tsac)2(dppm)2 ( 4 ), and [Pd(tsac)2(dppe)] · MeCN ( 5 ). Compounds 2 , 4 , and 5 have been prepared also by the reaction of Pd(acac)2 with the corresponding phosphane and Htsac. All the new complexes have been characterized by chemical analysis, UV/Vis, IR, and Raman spectroscopy. Some of them have been also characterized by NMR spectroscopy. The crystalline structures of complexes 3 , and 5 have been studied by X‐ray diffraction techniques. Complex 3 crystallizes in the monoclinic space group P21/n with a = 16.3537(2), b = 13.3981(3), c = 35.2277(7) Å, β = 91.284(1)°, and Z = 8 molecules per unit cell, and complex 5 in P21/n with a = 10.6445(8), b = 26.412(3), c = 15.781(2) Å, β = 107.996(7)°, and Z = 4. In compounds 3 and 5 , the palladium ions are in a distorted square planar environment. They are closely related, having two sulfur atoms of two thiosaccharinate anions, and two phosphorus atoms of one molecule of dppm or dppe, respectively, bonded to the PdII atom. The molecular structure of complex 3 is the first reported for a mononuclear PdII‐dppm‐thionate system. 相似文献
10.
1-取代-2-氨基苯并咪唑衍生物的理论计算及QSAR研究 总被引:1,自引:0,他引:1
在B3LYP/6-31+g(d)计算水平下, 通过运用密度泛函理论(DFT)量子化学方法, 对7种1-取代-2-氨基苯并咪唑衍生物的电子结构特征进行了研究, 获得了它们的电离能、亲合能、化学硬度、化学软度、化学势、电负性、亲电性、分配系数、折射率、极化率、分子体积和分子表面积等参数. 结果表明, 在2-氨基苯并咪唑衍生物的1位引入取代基团, 对化合物的电荷布居和结构性质都有较大的影响|关联了定量结构-活性关系(QSAR), 7种化合物的半数致死量LD50与极化率等有较好的相关性. 这些结果可为1-取代-2-氨基苯并咪唑衍生物的氧化代谢实验研究和毒性机理揭示等提供重要信息. 相似文献