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1.
Paritosh K Das 《Tetrahedron letters》1981,22(14):1307-1310
The rate constants for electron transfer reactions from several aromatic carbonyl triplets to paraquat dication leading to the formation of paraquat radical ion have been measured by nanosecond laser flash photolysis and are found to be in the range, 1 – 9 × 109 M?1 s?1. 相似文献
2.
Benzoyl peroxide has been used as a mild and efficient reagent for the preparation of benzoyl ester of oxime in moderate to good yields. 相似文献
3.
The oxidation of alkyl chlorides and bromides with dimethyl sulfoxide has been performed in the presence of sodium iodide. This method allows a convenient one-step procedure for the preparation of aldehydes from alkyl chlorides and bromides. 相似文献
4.
Abhijit Dutta Amit Kumar Pradhan Fei Qi Paritosh Mondal 《Monatshefte für Chemie / Chemical Monthly》2020,151(2):159-171
Quantum chemical study has been performed on finite-sized bi-metallic Rh3M alloys, M = Ag, Ir, Pd, Pt, Au, derived from magic cluster, Rh4. Bond length of C–O and N–O are noticed to be elongated in the presence of rhodium alloy clusters. CO2 and NO2 gases are found to be highly adsorbed on Rh3M clusters, which is confirmed by stretching frequency of C–O and N–O. DFT evaluated dipole moment and electronic charge redistribution suggests the sensing capability of CO2 and NO2 gases by Rh3M clusters which is further confirmed by the calculated HOMO–LUMO gap. Mixed rhodium alloy clusters supported on single-wall carbon nanotube (SWCNT) exhibits much higher ability to sense CO2 and NO2. On the other hand, SWCNT@Rh3M shows higher catalytic activity for the activation of CO2 and NO2 in comparison to bare Rh3M because of the higher electronic charge redistribution in the case of SWCNT@Rh3M. In case of SWCNT-supported gas adsorbed clusters, p electrons play a major role in bonding. 相似文献
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Bhattacharjee CR Goswami P Pramanik HA Paul PC Mondal P 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2011,78(5):1408-1415
Two new mixed-ligand iron(III) complexes, [Fe(L(n))(acac)(C(2)H(5)OH)] incorporating coordinated ethanol from the reaction solvent were accessed from the reaction of [Fe(acac)(3)] with [ONO] donor dibasic tridentate unsymmetrical Schiff base ligands derived from condensation of 2-hydroxy-1-napthaldehyde with 2-aminophenol (H(2)L(1)) or 2-aminobenzoic acid (H(2)L(2)). The thermal study (TGA-DTA) provided evidence for weakly bound ethanol which is readily substituted by neutral N-donor molecule imidazole, benzimidazole or pyridine to produce an array of newer complexes, [Fe(L(n))(acac)X] (n=1, 2; X=Im, Bim, Py). The compounds were characterized by elemental analyses, FT-IR, UV-vis, solution electrical conductivity, FAB mass, (1)H and (13)C NMR spectroscopy. Room temperature magnetic susceptibility measurements (μ(eff)~5.8 B.M.) are consistent with spin-free octahedral iron(III) complexes. Cyclic voltammetry of ethanol complexes revealed a quasi-reversible one electron redox response (ΔE(p)>100 mV) for the Fe(III)/Fe(II) couple. Low half wave redox potential (E(1/2)) values suggested easy redox susceptibility. The ground state geometries of the ethanol and imidazole complexes have been ascertained to be distorted octahedral by density functional theory using DMol3 program at BLYP/DNP level. 相似文献
7.
Paritosh Biswas 《Proceedings Mathematical Sciences》1976,83(5):167-174
Berger’s approximate equations extended to heated plates have been used to obtain the large deflection of a heated semi-circular plate with simply-supported edges under stationary temperature distribution. 相似文献
8.
Paritosh Verma 《Annalen der Physik》2024,536(2):2100600
This article presents the calculation of gravitational radiation from an oscillating rod in Brans–Dicke (BD) theory. Here only the selected formulae is shown and is applied to a toy problem without any rigorous derivation. First, the explicit expressions for the polarizations are calculated and then the power radiated away in gravitational waves (GWs) is obtained. This problem is motivated by the famous Eddington's spinning rod. 相似文献
9.
Paritosh Mokhasi 《Physica D: Nonlinear Phenomena》2008,237(24):3197-3213
In this paper, the problem of approximating velocity fields at future and past times based on information available at the current time is addressed. A novel method called “episodic POD” is described and developed that enables us to achieve our objective. Application of episodic POD to an ensemble of flow data results in a set of spatio-temporal eigenfunctions and a set of coefficients associated with the eigenfunctions. From these eigenfunctions, we develop two models called the “forward model” and “inverse model” that enable us to approximate the velocity fields at future and past times, based on information provided at the current time. A second set of models, the forward and inverse sequential models are also developed that enable the dynamic update of approximated velocity fields when new information is made available, making these models more adept at on-line estimation. The various properties associated with these models are described in detail, and four different examples are used to validate the models and show the different properties associated with episodic POD. It is shown through numerical validation, that the episodic POD model has a form that is dynamically consistent with the original system. It is also shown that episodic POD outperforms linear Kalman filters in the presence of noise. 相似文献
10.
Parmar Paritosh Rao Priyashi Sharma Abhilasha Shukla Arpit Rawal Rakesh M. Saraf Meenu Patel Baldev V. Goswami Dweipayan 《Molecular diversity》2022,26(1):389-407
Molecular Diversity - The latest global outbreak of 2019 respiratory coronavirus disease (COVID-19) is triggered by the inception of novel coronavirus SARS-CoV2. If recent events are of any... 相似文献