全文获取类型
收费全文 | 1190篇 |
免费 | 36篇 |
国内免费 | 7篇 |
专业分类
化学 | 856篇 |
晶体学 | 3篇 |
力学 | 21篇 |
数学 | 210篇 |
物理学 | 143篇 |
出版年
2023年 | 5篇 |
2022年 | 7篇 |
2021年 | 21篇 |
2020年 | 11篇 |
2019年 | 22篇 |
2018年 | 18篇 |
2017年 | 13篇 |
2016年 | 22篇 |
2015年 | 30篇 |
2014年 | 29篇 |
2013年 | 67篇 |
2012年 | 83篇 |
2011年 | 67篇 |
2010年 | 45篇 |
2009年 | 49篇 |
2008年 | 83篇 |
2007年 | 62篇 |
2006年 | 62篇 |
2005年 | 81篇 |
2004年 | 70篇 |
2003年 | 46篇 |
2002年 | 50篇 |
2001年 | 18篇 |
2000年 | 20篇 |
1999年 | 8篇 |
1998年 | 16篇 |
1997年 | 10篇 |
1996年 | 9篇 |
1995年 | 11篇 |
1994年 | 11篇 |
1992年 | 10篇 |
1991年 | 10篇 |
1990年 | 5篇 |
1989年 | 6篇 |
1988年 | 5篇 |
1987年 | 6篇 |
1986年 | 7篇 |
1985年 | 8篇 |
1984年 | 17篇 |
1983年 | 12篇 |
1982年 | 8篇 |
1981年 | 10篇 |
1980年 | 5篇 |
1979年 | 5篇 |
1978年 | 6篇 |
1977年 | 7篇 |
1974年 | 4篇 |
1973年 | 4篇 |
1915年 | 4篇 |
1913年 | 5篇 |
排序方式: 共有1233条查询结果,搜索用时 625 毫秒
1.
2.
Wen Zhang Hui Huang Yu Ding Margherita Gavagnin Ernesto Mollo Guido Cimino Yue‐Wei Guo 《Helvetica chimica acta》2006,89(4):813-820
Three new polyoxygenated steroids, muricesteroid ( 1 ), and menellsteroids A ( 2 ) and B ( 3 ), were isolated from two species of the South China Sea gorgonian Muricella flexuosa and Menella verrucosa Brundin , respectively. The structures of these new compounds were elucidated on the basis of extensive spectroscopic analysis, chemical methods and comparison with known related compounds. 相似文献
3.
Ernesto Quesada 《Tetrahedron letters》2004,45(25):4877-4881
The first syntheses of newly isolated members of the Preussomerin family, Preussomerins K and L, are reported. Key steps include the functionalisation of a 2-arylacetal anion, one-pot Friedel-Crafts cyclisation-deprotection and reductive opening of epoxides. 相似文献
4.
The linearized stability of charged thin shell wormholes under spherically symmetric perturbations is analyzed. It is shown that the presence of a large value of charge provides stabilization to the system, in the sense that the constraints onto the equation of state are less severe than for non-charged wormholes. 相似文献
5.
Summary We consider a one-dimensional linear wave equation with a small mean zero dissipative field and with the boundary condition imposed by the so-called Goursat problem. In order to observe the effect of the randomness on the solution we perform a space-time rescaling and we rewrite the problem in a diffusion approximation form for two parameter processes. We prove that the solution converges in distribution toward the solution of a two-parameter stochastic differential equation which we identify. The diffusion approximation results for oneparameter processes are well known and well understood. In fact, the solution of the one-parameter analog of the problem we consider here is immediate. Unfortunately, the situation is much more complicated for two-parameter processes and we believe that our result is the first one of its kind.Partially supported by ONR N00014-91-J-1010 相似文献
6.
7.
8.
Enrique Bendito ngeles Carmona Andr s M. Encinas 《Applied Numerical Mathematics》2004,50(3-4):343-370
Our aim is to set the foundations of a discrete vectorial calculus on uniform n-dimensional grids, that can be easily reformulated on general irregular grids. As a key tool we first introduce the notion of tangent space to any grid node. Then we define the concepts of vector field, field of matrices and inner products on the space of grid functions and on the space of vector fields, mimicking the continuous setting. This allows us to obtain the discrete analogous of the basic first order differential operators, gradient and divergence, whose composition define the fundamental second order difference operator. As an application, we show that all difference schemes, with constant coefficients, for first and second order differential operators with constant coefficients can be seen as difference operators of the form
for suitable choices of q,
and
. In addition, we characterize special properties of the difference scheme, such as consistency, symmetry and positivity in terms of q,
and
. 相似文献
9.
Angel L. Esteban Maria P. Galache Francisco Mora Ernesto Diez Jesus San Fabian 《Journal of computational chemistry》1989,10(7):887-895
An equation is formulated on the basis of theoretical INDO/FPT calculations which describes the angular dependence of the propanic long-range coupling constant 4JMeH in substituted HCCCH3 fragments. This equation is a truncated Fourier series in the torsion angle ?, HCCMe, which takes into account the dependence of the Fourier coefficients on the bond angle θ, CCMe. The substituent effects are assumed to be additive. Some parameters in the equation may be obtained from the 4JMeH couplings in propane and neopentane derivatives. The calculated effect upon 4JMeH of changes in the bond angle θ is significant and it seems to be in part the cause of some effects which have been attributed to conformational dependence. 相似文献
10.