The first total syntheses of (±)-Preussomerins K and L using 2-arylacetal anion technology |
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| Authors: | Ernesto Quesada |
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| Institution: | Department of Chemistry, University of York, Heslington, York, YO10 5DD, United Kingdom |
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| Abstract: | The first syntheses of newly isolated members of the Preussomerin family, Preussomerins K and L, are reported. Key steps include the functionalisation of a 2-arylacetal anion, one-pot Friedel-Crafts cyclisation-deprotection and reductive opening of epoxides. |
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| Keywords: | Total synthesis Natural products Preussomerins Arylacetal anion |
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