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1.
An assignment of the near-infrared bands in the 600–800 nm spectral region observed in magnetic circular dichroism (MCD)
spectra of high-spin ferrous haemoproteins is presented. The assignment is based on a relative energy level scheme for iron
d-electrons, a comparison of predicted and measured temperature dependences of MCD intensity, a sign of MCD bands and a group
theoretical analysis of allowed transitions. The proposed assignment is consistent with the ∼15-nm red shift of the ∼760 nm
band on breakage of the Fe-His bond in deoxy-myoglobin at low pH, with low-temperature photolysis experiments available for
CO complexes of several haemoproteins. In accordance with the observations, the intensity of the MCD bands for proteins with
a sulphur anion of cysteine as proximal haemligand (cytochrome P450 and chloroperoxidase) is predicted to be diminished by
at least one order of magnitude compared to that for proteins with an imidazole of a histidine as a protein-derived haemligand
(i.e. myoglobin, haemoglobin and horseradish peroxidase).
Received: 4 February 1997 / Accepted: 1 May 1997 相似文献
2.
Vasily L. Morgunov 《Pramana》2007,69(6):1097-1100
A new calorimeter energy calibration method was developed for the proposed ILC detectors. The method uses the center-of-mass
energy of the accelerator as the reference. It has been shown that using the energy conservation law it is possible to make
ECAL and HCAL cross calibration to reach a good energy resolution for the simple calorimeter energy sum.
相似文献
3.
Vasily Dzhordzhadze 《Acta Physica Hungarica A》2006,25(2-4):451-459
The PHENIX detector at RHIC has been designed to study different signatures of the states of matter created in heavy-ion collisions, and to investigate the spin structure of the nucleon. The PHENIX detector measures muons in two muon spectrometers, located at forward rapidities (1.2 < |η| < 2.4) and hadrons, electrons and photons in the two central spectrometers at midrapidity (|η| <0.35). To make a next step in the PHENIX research program, it is necessary to extend the rapidity coverage beyond the limits set by the existing central spectrometer. The functionality of the PHENIX muon detectors can be extended with added capabilities to measure photonic and hadronic jets. Tungsten calorimeters with silicon pixel readout and fine transverse and longitudinal segmentation are proposed to attain this goal. The proposed calorimeters will be located in the forward directions on either side of the PHENIX interaction point. In this talk we report on the studies of the functionality of the proposed calorimeters: the detector energy resolution, the jet reconstruction capabilities and the characteristics of pion rejection. 相似文献
4.
A. V. Kravtsov 《Computational Mathematics and Mathematical Physics》2007,47(11):1875-1884
A linear problem of parametric oscillations of a low-viscous two-layer fluid in a closed vessel partially filled with a porous medium is studied. An asymptotic solution is constructed on the basis of combined application of boundary functions and averaging methods. Approximate formulas for boundaries of instability domains in the case of subharmonic and harmonic resonances are derived. 相似文献
5.
A. S. Peregudov L. N. Usatova E. I. Smyslova E. I. Fedin D. N. Kravtsov 《Russian Chemical Bulletin》1995,44(8):1513-1519
It has been shown by the19F NMR method that the relative polarities of nitrogenelement bonds in 2-(4-fluorophenyl)benzimidazole and its PhHg and PPh3Au derivatives increase in the order N-H19F NMR. It has been found that these reactions occur by a bimolecular associative mechanism and that the N-H bond is substantially less reactive than the N-Hg and N-Au bonds, which have identical reactivities within the limits of sensitivity of the method used.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1574–1580, August, 1995.This work was carried out with financial support from the Russian Foundation for Basic Research (Project No. 93-03-5528). 相似文献
6.
A microscopic theory of the Efetov supermatrix sigma-model type is constructed for the low-lying electron states in a mixed
superconductive-normal system with disorder. This technique is used for the study of the localized states in the core of a
vortex in a moderately clean superconductor with τ
−1≫ω
0∼Δ2/E
F
. At low energies ε≪ω
Th∼ (ω
0/τ)1/2, the energy level statistics is described by the “zero-dimensional” limit of this supermatrix theory, and the result for
the density of states is equivalent to that obtained within Altland-Zirnbauer random matrix model. Nonzero modes of the sigma
model increase the mean interlevel distance by the relative amount [2 ln (1/ω
0
τ)]−1.
Pis’ma Zh. éksp. Teor. Fiz. 68, No. 1, 78–83 (10 July 1998)
Published in English in the original Russian journal. Edited by Steve Torstveit. 相似文献
7.
O. Ya. Butkovskii Yu. A. Kravtsov E. D. Surovyatkina 《Journal of Experimental and Theoretical Physics》1998,86(1):206-212
The structure of the attraction zones of the final states associated with dynamical period doubling bifurcations is investigated.
It is found that on the “initial value—transition rate” plane the attraction zones of the two possible final states alternate
with each other and that a subdivision of the attraction regions occurs with a decrease in the transition rate. It is shown
that the boundaries of the attraction zones are smeared out because of the effect of noise and in this situation the fine
structure of the attraction zones is destroyed. As analytical and numerical calculations have shown, the critical value of
the noise variance, corresponding to the boundary between the dynamical (or predictable) and stochastic (or unpredictable)
modes, has a power-law dependence on the transition rate with a typical exponent value of one. The existence of “noise” invariants
is also observed: the integrated (over all initial values) probability of achieving the final state is invariant with respect
to the noise level.
Zh. éksp. Teor. Fiz. 113, 369–380 (January 1998) 相似文献
8.
9.
10.
Supramolecular isomerism in coordination compounds: nanoscale molecular hexagons and chains 总被引:1,自引:0,他引:1
Abourahma H Moulton B Kravtsov V Zaworotko MJ 《Journal of the American Chemical Society》2002,124(34):9990-9991
A nanoscale supramolecular hexagon, 1, and its supramolecular isomeric chain structure, 2, have been prepared from self-assembly of 5-NO2-bdc and Cu(II) cations. The hexagon is neutral and soluble and has outer and inner diameters of 3.1 and 0.8 nm, respectively. 相似文献