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1.
Mesoscopic modeling at the pore scale offers great promise in exploring the underlying structure transport performance of flow through porous media. The present work studies the fluid flow subjected to capillarity-induced resonance in porous media characterized by different porous structure and wettability. The effects of porosity and wettability on the displacement behavior of the fluid flow through porous media are discussed. The results are presented in the form of temporal evolution of percentage saturation and displacement of the fluid front through porous media. The present study reveals that the vibration in the form of acoustic excitation could be significant in the mobilization of fluid through the porous media. The dependence of displacement of the fluid on physicochemical parameters like wettability of the surface, frequency along with the porosity is analyzed. It was observed that the mean displacement of the fluid is more in the case of invading fluid with wetting phase where the driving force strength is not so dominant. 相似文献
2.
Self‐Assembly and Gelation of Poly(aryl ether) Dendrons Containing Hydrazide Units: Factors Controlling the Formation of Helical Structures 下载免费PDF全文
Partha Malakar Prof. Dr. Edamana Prasad 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(13):5093-5100
Self‐assembly of AB2 and AB3 type low molecular weight poly(aryl ether) dendrons that contain hydrazide units were used to investigate mechanistic aspects of helical structure formation during self‐assembly. The results suggest that there are three important aspects that control helical structure formation in such systems with acyl hydrazide/hydrazone linkage: i) J‐type aggregation, ii) the hydrogen‐bond donor/acceptor ability of the solvent, and iii) the dielectric constant of the solvent. The monomer units self‐assemble to form dimer structures through hydrogen‐bonding and further assembly of the hydrogen‐bonded dimers leads to macroscopic chirality in the present case. Dimer formation was confirmed by NMR spectroscopy and by mass spectrometry. The self‐assembly in the system was driven by hydrogen‐bonding and π–π stacking interactions. The morphology of the aggregates formed was examined by scanning electron microscopy, and the analysis suggests that aprotic solvent systems facilitate helical fibre formation, whereas introduction of protic solvents results in the formation of flat ribbons. This detailed mechanistic study suggests that the self‐assembly follows a nucleation–elongation model to form helical structures, rather than the isodesmic model. 相似文献
3.
4.
Examples are worked out using a new equation proposed in the previous paper to show that it has new physical predictions for mesoscopic systems. 相似文献
5.
We characterize all equivariant odd spectral triples for the quantum SU(2) group acting on its L
2-space and having a nontrivial Chern character. It is shown that the dimension of an equivariant spectral triple is at least three, and given any element of the K-homology group of SUq(2), there is an equivariant odd spectral triple of dimension 3 inducing that element. The method employed to get equivariant spectral triples in the quantum case is then used for classical SU(2), and we prove that for p < 4, there does not exist any equivariant spectral triple with nontrivial K-homology class and dimension p acting on the L
2-space.The first author would like to acknowledge support from the National Board of Higher Mathematics, India. 相似文献
6.
K. Dasgupta P. Barat A. Sarkar P. Mukherjee D. Sathiyamoorthy 《Applied Physics A: Materials Science & Processing》2007,87(4):721-726
The use of graphite as a moderator in a low temperature thermal nuclear reactor is restricted due to accumulation of energy
caused by displacement of atoms by neutrons and high energetic particles. Thermal transients may lead to a release of stored
energy that may raise the temperature of the fuel clad above the design limit. Disordered carbon is thought to be an alternative
choice for this purpose. Two types of disordered carbon composites, namely, CB (made up of 15 wt. % carbon black dispersed
in carbonized phenolic resin) and PAN (made up of 20 vol. % chopped polyacrylonitrile carbon fibre dispersed in carbonized
phenolic resin matrix) have been irradiated with 145 MeV Ne6+ ions at three fluence levels of 1.0×1013, 5.0×1013 and 1.5×1014 Ne6+/cm2, respectively. The XRD patterns revealed that both the samples remained disordered even after irradiation. The maximum release
of stored energy for CB was 212 J/g and that of PAN was 906 J/g. For CB, the release of stored energy was a first order reaction
with activation energy of 2.79 eV and a frequency factor of 3.72×1028 per second. 13% of the defects got annealed by heating up to 700 °C. PAN showed a third-order release rate with activation
energy of 1.69 eV and a frequency factor of 1.77×1014 per second. 56% of the total defects got annealed by heating it up to 700 °C. CB seems to be the better choice than PAN as
it showed less energy release with a slower rate.
PACS 61.80.Jh; 61.80.-x; 61.43Er; 61.43.-j; 68.43.Vx 相似文献
7.
The study of the angular distribution of slow particles during high energy hadron-nucleus interaction indicates that emission of slow particles takes place from a thermally non-equilibrated system. This evidence has come out from the presence of intermittency - a phenomenon that reveals a fractal structure and represents a self-similarity in the particle production process. Hence, this study highlights inadequacy of cascade-evaporation model and advocates the need of its refinement. 相似文献
8.
S. Sarkar A. D. Thakur C. V. Tomy G. Balakrishnan D. McK Paul S. Ramakrishnan A. K. Grover 《Pramana》2006,66(1):193-207
New experimental data are presented on the scan rate dependence of the magnetization hysteresis width ΔM(H) (∞ critical current densityJ
c(H)) in isothermalMH scans in a weakly pinned single crystal of Ca3Rh4Sn13, which displays second magnetization peak (SMP) anomaly as distinct from the peak effect (PE). We observe an interesting
modulation in the field dependence of a parameter which purports to measure the dynamical annealing of the disordered bundles
of vortices injected through the sample edges towards the destined equilibrium vortex state at a givenH. These data, in conjunction with the earlier observations made while studying the thermomagnetic history dependence inJ
c(H) in the tracing of the minor hysteresis loops, imply that the partially disordered state heals towards the more ordered state
between the peak field of the SMP anomaly and the onset field of the PE. The vortex phase diagram in the given crystal of
Ca3Rh4Sn13 has been updated in the context of the notion of the phase coexistence of the ordered and disordered regions between the
onset field of the SMP anomaly and the spinodal line located just prior to the irreversibility line. A multi-critical point
and a critical point in the (H,T) region of the Bragg glass phase have been marked in this phase diagram and the observed behavior is discussed in the light
of recent data on multi-critical point in the vortex phase diagram in a single crystal of Nb. 相似文献
9.
Pongaglabol [8-hydroxy-5-phenyl-furo[2,3-h]benzo(b)pyran-7-one] was synthesized and tested for antibacterial effects againstShigella dysenteriae, Salmonella typhi, Streptococcus β-haemolyticus andStaphylococcus aureus. The synthesized compounds were characterized using UV, IR and1H NMR spectral data 相似文献
10.
Studies on the thermal stability of FeCr2O4 in air show that surface oxidation preceeds bulk oxidation. Electrical resistivity and thermoelectric power measurements show that above 47 K, Fe2+ ions are oxidised by the oxygen adsorbed on the surface and above 523K diffusion of the ions into the bulk occur. DTA and TG show that the bulk oxidation starts above 673 K and the change from the defect spinel phase to the rhombohedral phase occurs during oxidation and is not a sharp transition.
The authors wish to thank DST for some financial help. 相似文献
Zusammenfassung Untersuchungen der thermischen Stabilität von FeCr2O4 in Luft zeigen, daß der Masseoxidation eine Oxidation an der Oberfläche vorangeht. Messungen des elektrischen Widerstandes und der thermo-elektromotorischen Kraft zeigen, daß die Fe2+-Ionen oberhalb 47 K durch den an der Oberfläche adsorbierten Sauerstoff oxidiert werden und daß oberhalb 523 K eine Diffusion der Ionen in das Innere abläuft. DTA- und TG- Untersuchungen zufolge setzt die Masseoxidation oberhalb 673 K ein und während der Oxidation verläuft ein unscharfer Übergang von der defekten Spinellphase in die rhomboedrische Phase.
The authors wish to thank DST for some financial help. 相似文献